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101.
以68台燃油锅炉(≤10~MW)NOx排放实测数据为基础,通过统计分析方法,研究了NOx的排放特征;通过对比分析,探讨了我国燃油锅炉NOx排放控制与管理现状,讨论了进一步加强我国燃油锅炉NOx排放管理控制的可能性与可行性,并提出了相应的管理控制建议。结果表明,NOx平均排放浓度为318.2mg/m^3,基于燃料消耗量的平均排放因子为4.4kg/t,基于燃料发热量的平均排放因子为102.8ng/J,基于燃料氮含量的平均排放因子为2.1mg/mg;建议采取分阶段控制的方式,逐步提高NOx排放限制,从而实现控源减排目标。 相似文献
102.
Yayan Xu Jinming Song Liqin Duan Xuegang Li Huamao Yuan Ning Li Peng Zhang Ying Zhang Sisi Xu Mo Zhang Xiaodan Wu Xuebo Yin 《Environmental monitoring and assessment》2012,184(12):7275-7292
Surface sediment samples were collected at 27 stations of Bohai Bay, North China. Sequential extractions were carried out in this study. REE were leached out from four labile fractions: Exchangeable (L1), bound to carbonates (L2), bound to Fe–Mn oxides (L3), bound to organic matter (L4), and the remainder was residual (R5). The total contents of REE fluctuate slightly in Bohai Bay, and are mainly concentrated in the middle region, showing relatively higher levels in the north than that in the south of Bohai Bay. Percentages of L1, L2, L3, L4, and R5 for REE suggest that the residual fraction accounts for the major component of REE, whereas Fe–Mn oxides also play important roles in combining labile REE. As the REE complex is not stabilized, the competition of complex could induce dissociation of the complex and redistribution of the REE in various environments. According to REE patterns and Y/Ho ratios of samples, REE are not anthropogenic or oceanic sources but riverine input, whereas suitable environment varieties can slightly affect the patterns and fractionations of REE. As powerful tracers for the variable of environment, higher anomaly of Eu and Ce in southern regions indicates a greater reduction in the condition of surface sediment in the south than that in the north of Bohai Bay. 相似文献
103.
研究了KBrO3对二茂铁(Fc)非均相Fenton效能的影响,深入考察了KBrO3对体系中Fc溶解、H2O2分解和羟基自由基(·OH)生成的影响。结果表明,KBrO3的加入对不同反应阶段Fc/Fenton体系的效能均有明显的促进作用,初始阶段主要是由于KBrO3对·OH产生的促进作用所致,后期主要是由于KBrO3促进了体系中Fc的溶解,使得体系中溶解态的Fc催化的均相Fenton反应的比例增加,体系中H2O2的分解加快,·OH的表观生成率增加,进而促进了反应的进行。无KBrO3添加,pH=4,MB初始浓度为10 mg/L,Fc的量为1.6×10-3mol/L,[H2O2]/[MB]=3.14时,45 min时,MB的剩余率为9.1%,105 min时为0。当KBrO3的用量为3×10-4mol/L时,反应45 min后MB的去除率即可达到100%。随着KBrO3浓度的增加,其对Fc/Fenton效能的促进作用增强。 相似文献
104.
以白碳黑、硅灰、硅藻土和硅胶筛选硅质原料,并与钙质原料电石渣制备了水化硅酸钙。借助XRF、BET、FTIR等表征手段,通过多次重复除磷实验,研究了硅质原料特性对水化硅酸钙回收磷性能的影响。结果表明,白碳黑具有极高的反应活性,因此可作为制备具有磷回收特性的水化硅酸钙的硅质原料。结合XRD等表征发现,白碳黑的有效利用率是影响水化硅酸钙回收磷性能的关键,该利用率取决于白碳黑与电石渣的摩尔配比以及水热反应温度。当电石渣与白碳黑的摩尔比为1.6:1,反应温度为170℃时,白碳黑具有最佳的利用效率。该条件制备的水化硅酸钙可作为晶种,在其表面结晶形成羟基磷灰石,从而达到磷回收的目的,磷回收后固体物质中的磷含量为19.05%。 相似文献
105.
本文以旅游景区的经营模式为研究核心,从现有国内外旅游景区组织结构分析入手,构建了适合我国国情和旅游景区可持续发展要求的两种经营模式:一种是国有国营的次国家公园模式,另一种是完全企业化经营,并且提出了两种模式运作的保障条件。 相似文献
106.
107.
Adverse effects of manufactured nickel oxide nanoparticles on the microalgae Chlorellavulgaris were determined by algal growth-inhibition test and morphological observation via transmission electron microscopy (TEM). Results showed that the NiO nanoparticles had severe impacts on the algae, with 72 h EC(50) values of 32.28 mg NiOL(-1). Under the stress of NiO nanoparticles, C. vulgaris cells showed plasmolysis, cytomembrane breakage and thylakoids disorder. NiO nanoparticles aggregated and deposited in algal culture media. The presence of algal cells accelerated aggregation of nanoparticles. Moreover, about 0.14% ionic Ni was released when NiO NPs were added into seawater. The attachment of aggregates to algal cell surface and the presence of released ionic Ni were likely responsible for the toxic effects. Interestingly, some NiO nanoparticles were reduced to zero valence nickel as determined by X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) analysis. The maximum ratios of nickel reduction was achieved at 72 h of exposure, in accordance with the time-course of changes in soluble protein content of treated C. vulgaris, implying that some proteins of algae are involved in the process. Our results indicate that the toxicity and bioavailability of NiO nanoparticles to marine algae are reduced by aggregation and reduction of NiO. Thus, marine algae have the potential for usage in nano-pollution bio-remediation in aquatic system. 相似文献
108.
109.
风险管理标准化述评 总被引:6,自引:0,他引:6
针对近年来三个重要的风险管理国际标准化文件:Guide 73:2002,澳大利亚的风险管理标准AS/NZS 4360:2004和ISO/CD 31000,以及国际减灾理事会的白皮书,评述了国际标准化文件在风险管理过程环节的基本条款和管理框架.Guide 73指引了风险管理领域最基础的术语,对全球的风险管理制定出通用的语言.它强调对于安全领域,风险管理把焦点放在危害的预防和减轻;AS/NZS 4360明确地确定了相关风险管理的定义,解释了风险管理的程序,重点强调要控制风险产生的后果;ISO/CD 31000聚合了大约26个国家的知识和经验,关注组织建立风险管理流程和不断地进行审评的重要性;IRGC强调群体感知是风险管理的前提,只有当群体认知到可能存在风险时,才会有利于用自己的判断经验去进行风险识别、划分和评价风险,进行风险评估.最后述评了中国风险管理标准化的工作以及在国际风险管理标准化中的贡献. 相似文献
110.
Wen-Xiu Liu Wei He Ning Qin Xiang-Zhen Kong Qi-Shuang He Hui-Ling Ouyang Fu-Liu Xu 《Environmental science and pollution research international》2013,20(4):2033-2045
The levels of organochlorine pesticides (OCPs) in the water, suspended solids, and sediments from Lake Chaohu during the high water level period were measured by a solid-phase extraction gas chromatograph–electron capture detector. The spatial distributions of the three phases and the water/suspended solids and sediment/water partition coefficients were analyzed. The results showed the following: (1) The mean contents of OCPs in the water, suspended solids, and sediments were 132.4?±?432.1 ng/L, 188.1?±?286.7 ng/g dry weight (dw), and 13.7?±?9.8 ng/g dw, respectively. The dominant OCP components were isodrin (85.1 %) for the water, DDTs (64.4 %) for the suspended solids, and both isodrin (48.5 %) and DDTs (31.8 %) for the sediments. (2) β-HCH was the primary isomer of HCHs in the water and sediments, and the proportions were 61.7 and 41.3 %; γ-HCH was the primary isomer in the suspended solids, accounting for 49.3 %; p,p′-DDT was the dominant content of DDTs in the water and suspended solids, whereas p,p′-DDD was the main metabolite of DDTs in the sediments. (3) The concentrations of contaminants in the water from the western lake were greater than those from the eastern lake, but the concentrations in the suspended solids from the western lake were less than those from the eastern lake. (4) There was no significant correlation between the water–suspended solids partition coefficient K d and the n-octanol–water partition coefficient K ow, and between the sediment–water organic-C weighted sorption coefficients K oc and K ow. 相似文献