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21.
A series of highly-hydrophobic MIL-53-Al (MIL = Materials of Institut Lavoisier) frameworks synthesized via decoration of the Al-OH groups by alkyl phosphonic acid were developed as adsorbents for removing acetone from humid gas streams. The newly prepared materials were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), scanning electron microscope (SEM), N2 adsorption-desorption and thermogravimetric analysis (TGA). Their adsorption behaviors toward acetone vapor under dry and wet conditions were studied subsequently. Results showed that alkyl phosphonic acid was successfully grafted into MIL-53-Al skeleton through coordinating interaction with Al3+ generating [email protected]x (x = 12, 14, 18). The [email protected]x exhibited similar crystal structure and thermal stability to parent MIL-53-Al. Furthermore, the modified materials showed significantly enhanced hydrophobicity. The water vapor uptake of [email protected]14 decreased by 72.55% at 75% relative humidity (RH). Dynamic adsorption experiments demonstrated that water vapor had almost no effect on the acetone adsorption performance of [email protected]14. Under the condition of 90% RH, the acetone adsorption capacity of [email protected]14 was 102.98% higher than that of MIL-53-Al. Notably, [email protected]14 presented excellent adsorption reversibility and regeneration performance in 10 adsorption-desorption cycles. Taken together, the strategy of metal-OH group modification is an attractive way to improve the acetone adsorption performance over metal-organic frameworks (MOFs) under humid conditions. Besides, [email protected]14 would be deemed as a promising candidate for capturing acetone in high moisture environment. 相似文献
22.
环境保护与公众参与--绿色中国第九届论坛在京隆重召开 总被引:1,自引:0,他引:1
以“环境保护与公众参与”为主题的第九届“绿色中国论坛”,于12月3日在北京昆仑饭店隆重召开,这是2005中国环境文化节的重头戏。全国人大副委员长许嘉璐、全国政协副主席陈奎元.中宣部副部长胡振民.全国政协人资环委副主任温克刚等领导同志。来自清华大学.中国政法大学等著名高校的知名专家学者和企业家代表.文化界代表。以及全国70多家环保组织负责人应邀到会。国家环保总局副局长潘岳主持了论坛开幕式。并致开幕词。潘岳副局长还邀请中宣部副部长欧阳坚为本次论坛致词。本刊精编了论坛上的精彩发言,在此与读者共同分享。[编者按] 相似文献
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区域(城市)水体中主要有机毒物的筛选 总被引:1,自引:0,他引:1
本研究发展了区域(或城市)水体中主要有毒化学品的筛选方法。 在城市下游采集大体积水样,用CH_2Cl_2洗脱,再用有机溶剂萃取,用硅胶柱把有机物分成许多馏分,馏分最终变为水溶液。每个馏分中有机物浓度比原水大1000倍。用这种馏分水溶液进行溞的急性毒性试验和Ames试验。只对毒性大的馏分进行色谱/质谱/数据系统的鉴定和定量分析,然后根据各个化合物的急性毒性、降解难易和“三致”物质的资料及原水样中有机物的浓度资料,就可筛选出一个区域(城市)水体中的主要有毒化学品。 相似文献
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Salomao O. Bandeira Rui Paula e Silva Jose Paula Adriano Macia Lars Hernroth Almeida T. Guissamulo Domingos Z.Bergman 《Ambio-人类环境杂志》2002,31(7):606-609
本文概述了莫桑比克包括渔业在内的海洋生物学研究的发展情况.莫桑比克的海岸线约为3000km,海洋的生物资源在莫桑比克的社会中起着重要的作用,主要是作为人们的蛋白质来源以及收入和出口创汇的来源. 相似文献
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The peroxynitrite/porphyrin biomimetic system was established to investigate the effects of peroxynitrite on benzo[a]pyrene (B[a]P) metabolism. Three model systems consisting of different iron porphyrins were compared, and the results showed that the peroxynitrite/T(p-Cl)PPFeCl system was the highest catalytic efficiency in the metabolism of B[a]P. We analyzed the B[a]P metabolites produced from this system by RP-HPLC method and firstly identified the formation of nitrobenzo[a]pyrenes which are the special metabolites of B[a]P induced by peroxynitrite. 相似文献
29.
Liu Rui Zhou Qixing Zhang Lanying Guo Hao 《Frontiers of Environmental Science & Engineering in China》2007,1(1):114-119
To make a comprehensive assessment on monosodium glutamate (MSG) wastewater pollution, a pollution exposure experiment was
carried out on the seed germination and root elongation of wheat, Chinese cabbage and tomato by using the wastewater discharged
from different processing phases of MSG production. The results showed that there were significantly positive linear relationships
between the inhibitory rates of wheat seed germination and root elongation and the CODcr of the mother liquor scraps. The toxicity of MSG wastewater to the test crops was in the order of tomato > Chinese cabbage
> wheat, indicating that tomato was the most sensitive to the wastewater, and could be considered as an ideal toxic bioindicator.
The half-effect concentrations (IC50) based on the seed germination and root elongation of the test crops exposed to the wastewater discharged from various processing
phases of MSG production was 22.0–32 432 and 17.3–3320 mg/L, respectively.
Translated from Chinese Journal of Applied Ecology, 2006, 17(7): 1286–1290 [译自: 应用生态学报] 相似文献
30.
介绍了臭氧氧化、活性炭吸附去除MIB、GEOSMIN时的主要影响因素,分析了各因素对去除率的影响程度及原因。还介绍了臭氧、PAC去除痕量异味物质的机理。 相似文献