The effect of EDDS and citrate on the uptake of lead in hydroponically grown Matthiola flavida

Root and shoot lead concentrations and the impact of chelating agents on these were investigated in two populations of the novel metallophyte Matthiola flavida. Plants were exposed in hydroponics to Pb(NO₃)₂, supplied alone, or in combination with citric acid, or EDDS. When supplied at concentrations expected to bind about 95% of the Pb in a solution containing 1-μM Pb (1000 μM citrate or 3.1 μM EDDS, respectively), the root and shoot Pb concentrations were dramatically lowered, in comparison with a 1-μM free ionic Pb control exposure. A 1-mM EDDS + 1-μM Pb treatment decreased the plants’ Pb concentrations further, even to undetectable levels in one population. At 100 μM Pb in a 1-mM EDDS-amended solution the Pb concentration increased strongly in shoots, but barely in roots, in comparison with the 1-μM Pb + 1-mM EDDS treatment, without causing toxicity symptoms. Further increments of the Pb concentration in the 1-mM EDDS-amended solution, i.e. to 800 and 990 μM, caused Pb hyperaccumulation, both in roots and in shoots, associated with a complete arrest of root growth and foliar necrosis. M. flavida seemed to be devoid of constitutive mechanisms for uptake of Pb-citrate or Pb-EDDS complexes. Hyperaccumulation of Pb-EDDS occurred only at high exposure levels. Pb-EDDS was toxic, but is much less so than free Pb. Free EDDS did not seem to be toxic at the concentrations tested.     

Physical development trend and green space destruction in developing cities: a GIS approach

Green spaces considered natural remnants in urban environments play a key role in promoting environmental quality and forming a sustainable city. Nowadays, development of urban spaces has taken a hasty growth. In the meanwhile, the natural green spaces are severely damaged. The current study aims at investigating the trend of changes in green space of Tabriz City, the second large industrial city in Iran, on the basis of landscape ecology principles. In order to prepare the land-cover maps, Landsat TM and IRS LISS-III of the years 1989 and 2006 were applied. Alongside, landscape percentage metrics, the largest patch index, number of patches, patch density, edge density, total edge, class area and landscape shape index were also used to analyse the changes. Metric analysis of the landscape within the studied years revealed that a large part of the region has enjoyed a rapid growth (equivalent to 64.5 %) in constructions. As the obtained results showed, the smallest landscape percentage (3.9 %) in the study area is belonged to the municipal green space, while the largest landscape percentage (66 %) is allocated to the barren land. This shows that the constructions have not balanced with creation of new green spaces, and the lack of green space per capita continues to be felt.     

Environmental protection stability of river bed and banks using convex, concave, and linear bed sills

River bed scourings are a major environmental problem for fish and aquatic habitat resources. In this study, to prevent river bed and banks from scouring, different types of bed sills including convex, concave and linear patterns were installed in a movable channel bed in a laboratory flume. The bed sills were tested with nine different arrangements and under different flow conditions. To find the most effective bed sill pattern, the scouring depth was measured downstream of the bed sill for a long experimental duration. The scour depth was measured at the middle and at the end of each experimental test for different ratios of the arch radius to the channel width $(r/\emph{w})$ . The experimental results indicated that the convex pattern with $r/\emph{w}=0.35$ produced minimum bed scouring depth at the center line whereas the concave pattern with $r/\emph{w}=0.23$ produced the minimum scour depth at the wall banks. Therefore, the convex pattern was the most effective configuration for prevention of scouring at the center line of the river while the concave pattern was very effective to prevent scouring at the river banks. These findings can be suggested to be used in practical applications.     

Petroleum pollution in mangrove forests sediments from Qeshm Island and Khamir Port—Persian Gulf, Iran

The concentrations of total polycyclic aromatic hydrocarbons (?PAHs) and 22 individual PAH compounds in 42 surface sediments collected from the mangrove forest of Qeshm Island and Khamir Port (Persian Gulf) were analyzed. ?PAHs concentrations ranged from 259 to 5,376 ng?g^?1 dry weight with mean and median values of 1,585 and 1,146 ng?g^?1, respectively. The mangrove sediments had higher percentages of lower molecular weight PAHs and the PAH profiles were dominated by naphthalene. Ratio values of specific PAH compounds were calculated to evaluate the possible source of PAH contamination. This ratios suggesting that the mangrove sediments have a petrogenic input of PAHs. Sediment quality guidelines were conducted to assess the toxicity of PAH compounds. The levels of total PAHs at all of stations except one station, namely Q₆, were below the effects range low. Also, concentrations of naphthalene in some stations exceeded the effects range median.     

Ultrasound-assistant preparation of Cu-SAPO-34 nanocatalyst for selective catalytic reduction of NO by NH3

The influence of the various preparation methods of Cu-SAPO-34 nanocatalysts on the selective catalytic reduction of NO with NH₃ under excess oxygen was studied. Cu-SAPO-34 nanocatalysts were prepared by using four techniques: conventional impregnation (IM), ultrasound-enhanced impregnation (UIM), conventional deposition precipitation (DP) using NaOH and homogeneous deposition precipitation (HDP) using urea. These catalysts were characterized in detail by various techniques such as N₂-sorption, XRD, TEM, H₂-TPR, NH₃-TPD and XPS to understand the catalyst structure, the nature and the dispersed state of the copper species, and the acid sites for NH₃ adsorption. All of the nanocatalysts showed high activities for NO removal. However, the activities were different and followed the sequence of Cu-SAPO-34 (UIM) > Cu-SAPO-34 (HDP) > Cu-SAPO-34 (IM) > Cu-SAPO-34 (DP). Based on the obtained results, it was concluded that the NO conversion on Cu-SAPO-34 nanocatalysts was mainly related to the high reducibility of the isolated Cu^2 + ions and CuO species, the number of the acid sites and the dispersion of CuO species on SAPO-34.     

Application and evaluation of kriging and cokriging methods on groundwater depth mapping

Groundwater and water resources management play a key role in conserving the sustainable conditions in arid and semi-arid regions. Applying some techniques that can reveal the critical and hot conditions of water resources seem necessary. In this study, kriging and cokriging methods were evaluated for mapping the groundwater depth across a plain in which has experienced different climatic conditions (dry, wet, and normal) and consequently high variations in groundwater depth in a 12 year led in maximum, minimum, and mean depths. During this period groundwater depth has considerable fluctuations. Results obtained from geostatistical analysis showed that groundwater depth varies spatially in different climatic conditions. Furthermore, the calculated RMSE showed that cokriging approach was more accurate than kriging in mapping the groundwater depth though there was not a distinct difference. As a whole, kriging underestimated the real groundwater depth for dry, wet, and normal conditions by 5.5, 2.2, and 5.3%, while cokriging underestimations were 3.3, 2, and 2.2%, respectively; which showed the unbiasedness in estimations. Results implied that in the study area farming and cultivation in dry conditions needs more attention due to higher variability in groundwater depth in short distances compared to the other climate conditions. It is believed that geostatistical approaches are reliable tools for water resources managers and water authorities to allocate groundwater resources in different environmental conditions.