津河水系的修复对天津城市生态环境的影响

针对天津城市生态环境特点和背方城市大气污染现状,探讨了津河水系的修复对改善城市环境质量,丰富城市景观以及修复城市生态环境的重要意义。     

Gangba sheep in the Tibetan plateau: Validating their unique meat quality and grazing factor analysis

Gangba sheep are known for having typical sensory characteristics attributed to free range conditions and grazing on wild plants. The genuine Gangba mutton was selected as the experimental group, and the commercial Tibetan mutton was selected as the control group, the nutritive composition of basic chemical components, amino acids and fatty acids in mutton were investigated to correlate its unique meat quality and eating satisfaction. The results showed that fatty acids were significantly higher (P<0.05) in Gangba mutton than in commercial mutton, and the higher content of flavoring amino acids (glutamic acid and aspartame) were primarily responsible for the taste attributes umami of meat juices. Moreover, the trace elements analysis in mutton and grazing factors (forage, water source and soil) were conducted, to explain the source of essential trace elements in mutton. The concentrations of essential trace elements show that the Gangba mutton was a valuable source for highly available Cu and Zn in human nutrition, and well managed with few detected of toxicity metal. The concentrations of essential trace elements in mutton are closely related to the trace elements in environmental grazing factors. In conclusion, the congenital grazing conditions (a highly mineralized water resource, natural forages and clean soils) were shown to contribute to the unique meat characteristics of Gangba sheep.     

Modelling of the fate of selected endocrine disruptors in a municipal wastewater treatment plant in South East Queensland, Australia

The aim of this study was to develop a fugacity-based analysis of the fate of selected industrial compounds (alkylphenols and phthalates) with endocrine disrupting properties in a conventional activated sludge wastewater treatment plant (WWTP A) in South East Queensland, Australia. Using mass balance principles, a fugacity model was developed for correlating and predicting the steady-state-phase concentrations, the process stream fluxes, and the fate of four phthalates and four alkylphenols in WWTP A. Input data are the compound's physicochemical properties, measured concentrations and the plant's operating design and parameters. The relative amounts of chemicals that are likely to be volatilized, sorbed to sludge, biotransformed, and discharge in the effluent water was determined. Since it was difficult to predict biotransformation, measured concentrations were used to calibrate the model in terms of biotransformation rate constant. Results obtained by applying the model for the eight compounds showed <40% differences between most of the estimated and measured data from WWTP A. All eight compounds that were modelled in this study had high removal efficacy from WWTP A. Apart from benzyl butyl phthalate and bisphenol A, the majority is removed via biotransformation followed by a lesser proportion removed with the primary sludge. Fugacity analysis provides useful insight into compound fate in a WWTP and with further calibration and validation the model should be useful for correlative and predictive purposes.     

Adsorption and redox reactions of heavy metals on synthesized Mn oxide minerals

Several Mn oxide minerals commonly occurring in soils were synthesized by modified or optimized methods. The morphologies, structures, compositions and surface properties of the synthesized Mn oxide minerals were characterized. Adsorption and redox reactions of heavy metals on these minerals in relation to the mineral structures and surface properties were also investigated. The synthesized birnessite, todorokite, cryptomelane, and hausmannite were single-phased minerals and had the typical morphologies from analyses of XRD and TEM/ED. The PZCs of the synthesized birnessite, todorokite and cryptomelane were 1.75, 3.50 and 2.10, respectively. The magnitude order of their surface variable negative charge was: birnessite> or =cryptomelane>todorokite. The hausmannite had a much higher PZC than others with the least surface variable negative charge. Birnessite exhibited the largest adsorption capacity on heavy metals Pb(2+), Cu(2+), Co(2+), Cd(2+) and Zn(2+), while hausmannite the smallest one. Birnessite, cryptomelane and todorokite showed the greatest adsorption capacity on Pb(2+) among the tested heavy metals. Hydration tendency (pK(1)) of the heavy metals and the surface variable charge of the Mn minerals had significant impacts on the adsorption. The ability in Cr(III) oxidation and concomitant release of Mn(2+) varied greatly depending on the structure, composition, surface properties and crystallinity of the minerals. The maximum amounts of Cr(III) oxidized by the Mn oxide minerals in order were (mmol/kg): birnessite (1330.0)>cryptomelane (422.6)>todorokite (59.7)>hausmannite (36.6).     

南亚热带丘陵土壤水分循环及其有效性的研究──Ⅴ.丘陵土壤蒸散量的估算

根据系统实测资料,利用根层土壤水的变化量,按水量平衡公式反算求得观测年、季及旱月的土壤蒸散量.以三年平均及旱年土壤吸入水量减去蒸散量的结果显示,两个观测试区0～100cm土层蒸散量大于吸入水量;若以月平均计,则每月蒸散量大于土壤吸入水量3．84～8．60mm,土壤水的吸入略小于消耗,一年内土壤水量接近平衡．     

坡地赤红壤物理退化及其机理研究──Ⅱ.土壤水分性能退化特征

探讨了坡地赤红壤水分性能退化的特征、结果表明,与地带性自然植被下坡地赤红壤比较,次生植被或人工植被下坡地赤红壤水分性能变劣：表现在导水性降低,2h饱和渗水量明显减少,自然赤红壤比耕型赤红壤的减幅大;持水能力下降,在同样吸力下,土壤持水量较少;供水能力下降,在同样吸力段,表土释放的水量较少;亚表土在低吸力段释放水量较少。     

战略环境影响评价(SEA)在中国的开展—区域环境评价(REA)

实践和研究表明 :传统的环境影响评价 (EIA) ,即在项目层次上开展的EIA ,不尽完美。而包含有战略环境影响评价的新一代EIA体系将很好的弥补项目EIA的不足 ,并且将可持续发展的思想真正贯彻到实际中去。中国在开展环境影响评价方面 ,也逐渐注重两个层次上EIA的开展 ,特别是结合当前发展的新特点 ,开展了区域环境影响评价。文章论证了区域环境评价 ,无论从层次上 ,还是从评价的对象、内容上都是属于战略环境影响的形式。并基于这个观点 ,介绍了区域环评在中国的开展及今后发展应注意的一些问题。     

Risk assessment and validation of farmland abandonment based on time series change detection

Environmental Science and Pollution Research - Farmland abandonment, a widespread phenomenon during land-use transition, leads to a cycling or vanishing evolution of farmland resources. As...     

The health consequences of greenhouse gas emissions: a potential pathway

Environmental Geochemistry and Health - Excessive greenhouse gas emissions might be the major culprit for environmental degradation, which have direct and indirect adverse impacts in various ways....     

内分泌干扰物对核受体二聚化影响的研究进展

环境内分泌干扰物(endocrine disrupting chemicals,EDCs)可模仿或拮抗天然激素与核受体结合,干扰核受体的同源或异源二聚,进而通过共调节因子的招募调控转录活性,最终引起内分泌干扰效应.目前研究主要针对EDCs与核受体的结合过程,忽视了其对核受体二聚化过程的影响,而该过程的阻断可直接导致转录失活.EDCs对于不同核受体二聚化的影响不同,只有激动剂EDCs能够促进雄激素受体(androgen receptor,AR)的同源二聚化,而雌激素受体(estrogen receptor,ER)在与具有激动或拮抗活性的EDCs结合后都可诱导ER二聚体的形成,但二聚化类型不同.通过检索ToxCast和Tox21数据库发现多达227种EDCs可以诱导ER二聚化,相比于ERα-ERα同源二聚体(6.09％ ～7.38％的活性率),EDCs更易诱导ERα-ERβ异源二聚体(11.25％ ～12.22％的活性率)和ERβ-ERβ同源二聚体(10.02％ ～11.69％的活性率).EDCs也能够差异性诱导其他核受体如维生素D受体(vitamin D receptor,VDR)与维甲酸X受体(retinoid X receptor,RXR)形成的异源二聚体,不同类型的二聚体对于研究EDCs转录活性的生理学相关性具有重要意义.基于经济合作与发展组织(Organization for Economic Co-operation and Development,OECD)报告的参考化学品研究发现,相比于配受体结合活性,二聚活性与转录活性之间有着更好的相关关系.本文从EDCs介导的核受体二聚化转录机制、二聚化与转录活性间的关系以及二聚化研究方法三方面,总结EDCs对核受体二聚化的影响,以期为深入理解EDCs的分子作用机制,推进化合物的内分泌干扰风险评估提供参考.