发酵法溶剂生产工艺的流程模拟与参数优化

对发酵法溶剂生产的精馏工艺流程采用化工流程模拟软件PROII进行了模拟。将复杂的流程分为醪塔子系统、丁塔子系统和乙丙子系统,采用液体活度系数模型NRTL和非理想物系的CHEMDIST算法,利用Distillation模块、Simple HX模块、Flash模块和Mixer模块分别进行模拟。流程模拟结果与实际运行结果吻合良好。在此基础上,以减少塔釜废液中溶剂含量为优化目标,利用中心组合设计(CCD)与PROII流程模拟相结合,对醪塔的部分操作参数进行了优化。优化后可使废液中溶媒含量减少至0.008%,远低于原工艺数据。     

废聚苯乙烯塑料共焦化过程的生命周期评价

随着我国废塑料资源化利用技术的不断发展,其资源化过程中的环境问题也日益显现。以生命周期评价为研究方法,对废聚苯乙烯共焦化过程的环境影响进行评价。研究结果表明:废聚苯乙烯共焦化过程对酸化、烟尘和粉尘、全球变暖3类环境问题的影响较大,分别占了总影响的34.0%、27.5%和23.3%。从共焦化过程的3个阶段来看,入炉炼焦阶段的环境影响最大,其次是混合颗粒制备阶段和PS颗粒制备阶段,对炼焦阶段环境污染的控制是废塑料共焦化技术发展的关键。     

纳米铂微粒电极催化氧化有机污染物的研究

采用电化学阴极还原-阳极氧化方法制备了纳米铂微粒电极.电极表面的微观结构表征表明,铂微粒在三维网状的氧化钛膜孔道中呈均匀、高度分散状态,且粒径细小,铂微粒充分裸露,使得纳米铂微粒电极活性点多,电催化性能高.采用循环伏安法研究了铂微粒电极对有机小分子代表性物质甲醇的电催化氧化行为.结果表明,在酸性、中性和碱性介质中纳米铂微粒电极对甲醇的电催化氧化性能均明显优于光滑铂片电极,甲醇在纳米铂微粒电极上产生的氧化电流密度比光滑铂片电极高100倍以上.2种铂电极催化氧化降解甲醇、苯酚和甲基橙3种有机物时,纳米铂微粒电极的平均氧化电流效率是光滑铂片电极的数倍,这进一步表明纳米铂微粒电极对有机污染物具有良好的催化氧化降解能力.     

Growth and phosphate uptake kinetics of Microcystis aeruginosa under various environmental conditions

Growth and uptake of exogenous phosphate by Microcystis aeruginosa in batch culture under different temperature, photoperiod, and turbulence were studied by the method of phosphate isotope tracer. Relatively high temperature, long photoperiod and strong turbulence increased the cell density of M. aeruginosa in these batch cultures. The initial rapid uptake of phosphate by M. aeruginosa was independent of the temperature, photoperiod, and turbulence. Similarly, maximum exogenous phosphate uptake was not related to these environmental factors. However, elevated temperature and turbulence shortened the time, required to obtain maximum P accumulation. The growth of M. aeruginosa could alleviate the phosphorous leakage. Total amounts of exogenous phosphate uptake to M. aeruginosa and the phosphorus leakage of M. aeruginosa were significantly influenced by the growth state of M. aeruginosa closely correlated with the environmental factors. The maximum volume of exogenous phosphate uptake to M. aeruginosa was 46% of added exogenous phosphate in water with 16 hours of photoperiod. Thus, total amounts of exogenous phosphate uptake to M. aeruginosa were more strongly affected by the photoperiod length than temperature and turbulence.     

乙醛对鱼类毒性的实验研究

介绍了实验室乙醛对鲢鱼幼鱼的急性毒性。试验结果表明，乙醛对鲢鱼幼鱼的急性毒性４８ｈＬＣ５０为１４６１８ｍｇ／Ｌ，其安全浓度为１４６２ｍｇ／Ｌ。     

陶粒复合垂直流人工湿地对污水季节性处理效果的试验研究

研究了四种陶粒组合、一种石灰石碎石5套复合垂直流人工湿地在不同季节处理生活污水的运行效果。结果表明:陶粒组合人工湿地系统对COD、TP、NH3-N的去除效果均优于石灰石碎石湿地;复合垂直流人工湿地对COD的去除效果在冬季有所下降,但仍保持在50%以上;湿地系统对TP去除率受季节性变化影响不显著,但随着复合垂直流人工湿地系统的运行,基质层对TP的吸附逐渐饱和,去除效率缓慢下降;1号~5号人工湿地对氨氮的去除率分别从秋季42.0%、55.1%、61.1%、49.9%、50.2%下降至冬季21.9%、31.0%、36.5%、28.5%、29.2%,春、夏季处理效率开始回升,并保持稳定的状态。     

警惕来自外太空的灾害

<正>强烈的太阳风暴并非地震与海啸等自然灾害的主要诱因,但它对航天、通信、电力等人类的高科技活动却会造成严重影响。美国国家科学院和美国宇航局2010年初郑重预警了2012—2014年太阳风暴将带来的影响。科学家们担忧,太阳的这一次猛然"苏醒",也     

地铁隧道不同排烟风速对火灾烟气控制的模拟分析

以某地铁隧道过江段为研究对象,基于CFD数值模拟方法,采用大涡模拟火灾分析软件FDS对相同纵向风速条件下,排烟道内不同排烟风速对地铁列车火灾烟气控制效果的影响进行模拟对比分析,分析结果可为设计单位对在排烟风机的选取提供一定的参考。模拟分析的结果表明,当纵向风速设定为1m/s时,排烟风道内排烟风速为5m/s即能达到较好的地铁列车火灾烟气控制效果。     

The influence of heterogeneous environmental regulation on the green development of the mining industry: empirical analysis based on the system GMM and dynamic panel data model

The intensity of environmental regulation (ERI) affects the short-term effect of the level of green mining (GML), and which structure determines the long-term mechanism. Based on the panel data from 2001 to 2015, with the dynamic panel model and system GMM estimation method were employed to test the influence of heterogeneous environmental regulation on green mining and its transmission mechanism. The results show that, there is a “U” type nonlinear relationship between the ERI and GML. The direct effect of command-control-based (CAC) and the market incentive-based (MBI) environmental regulation on green development of mining shows the characteristics of inhibition and promotion. There is a “U” type of indirectly moderating effect between technological innovation and the energy consumption structure on the GML. The technological innovation promotes the green development of the mining industry only after pass the inflection point of MBI, while the CAC plays a significant guiding role in upgrading of the energy consumption structure. There is an inhibition and promotion effect of MBI on the GML in the southeast coastal area, and the CAC is not significantly. Meanwhile, both of the ERI shows no positive effects in the central and western inland region.     

Year-round film mulching system with monitored fertilization management improve grain yield and water and nitrogen use efficiencies of winter wheat in the dryland of the Loess Plateau,China

Environmental Science and Pollution Research - Year-round film mulching in winter wheat field facilitates rainwater storage in summer fallow period and reduces water evaporation in growing reason,...