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991.
Elaine S. Carvalho Rubén J. Sánchez Maria I. B. Tavares álano C. Lam?nica 《Journal of Polymers and the Environment》2010,18(4):661-667
The chemical modification of Acrylamidomethyl Cellulose Acetate Propionate (AMCAP) was carried out by radical addition of
acrylic acid. The structural modification was confirmed with the aid of FTIR, MS and NMR techniques. Thermal properties of
hydrophilic cellulose derivative (AMCAP–H2O2) such as glass transition (Tg 153 °C) and thermal stability (372.7 °C) were determined by DSC and TGA techniques, respectively. These thermal properties
confirmed the introduction of carboxylic groups into AMCAP structure, which causes an impact in their properties. The AMCAP–H2O2 shows minor contact angle compared to AMCAP, giving a more hydrophilic characteristic, due to acrylic acid addition into
the side chains of AMCAP polymer. 相似文献
992.
Andrés Pérez-parada Joaquín González Lucía Pareja Lucía Geis-Asteggiante Marcos Colazzo Silvina Niell 《Journal of environmental science and health. Part. B》2013,48(8):796-803
In order to evaluate the extraction of pesticide residues that are transferred to the brew during mate drinking process of P.U.1 yerba mate leaves (Ilex paraguariensis), a special device to simulate the way in which mate is drunk in Uruguay was developed. The transfer to the brew of 12 organophosphates, 5 synthethic pyrethroids and one organochlorine pesticide from spiked samples was studied. The relationship between the transfer data thus obtained and physicochemical properties like water solubility (Ws), octanol-water coefficient (Kow) and Henry's constant (H) was evaluated. The extractability of the pesticide residues from yerba mate can be correlated with log Ws and log Kow. These transfer values allowed the calculation of ARLs (acceptable residue level) for the pesticides following Food and Agriculture Organization (FAO), World Health Organizaion (WHO) guidelines. These results can help the future establishment of maximum residue levels (MRLs) 相似文献
993.
L. M. Simon K. László M. Kotormán A. Vértesi K. Bagi J. Nemcsók 《Journal of environmental science and health. Part. B》2013,48(5):819-828
Abstract The effects of pyrethroid pesticides (deltamethrin, permethrin and cypermethrin) and an organophosphate ester (methidation) on the activities of carp trypsin, α‐chymotrypsin, carboxypeptidase A and lipase were studied. The enzymes were isolated from the gastrointestinal tract and the effects of the pesticides were investigated during incubation for 5 min. The activity of trypsin was influenced only slightly by the presence of deltamethrin and methidation, whereas permethrin and cypermethrin caused significant inhibition. The pyrethroid pesticides at lower concentrations resulted in a slight activation of α‐chymotrypsin. Methidation inhibited the α‐chymotrypsin activity by about 20%. These pesticides modified the lipase activity to a lesser extent; the highest inhibition was measured with cypermethrin. The carboxypeptidase A activity was inhibited by both pyrethroid pesticides and methidation. The results suggest that these pesticides might interact with the active conformation of the studied hydrolytic enzymes, resulting in changes in their activities. 相似文献
994.
Wagner G. Moravia Míriam C.S. Amaral Liséte C. Lange 《Waste management (New York, N.Y.)》2013,33(1):89-101
A high content of refractory organic matter, ammonia and toxic compounds is characteristic of landfill leachate. Advanced oxidative processes (AOPs) are an attractive alternative for landfill leachate treatment. However, when applied as a unique process treatment, they do not provide a complete solution for the effluent treatment. Combining AOP with a membrane separation process (MSP) presents a number of benefits and provides an adequate solution for this problem. With this in mind, the present work aims to evaluate, using a bench scale, leachate treatability through AOP by Fenton’s reagent (AOP/Fenton) combined with microfiltration (MF) and nanofiltration (NF). A high efficient removal of COD (63%), true color (76%) and humic substances (50%) was observed during AOP/Fenton under optimized conditions (1.7 g H2O2/g CODraw leachate; FeSO4·7H2O:H2O2 = 1:5.3; pH = 3.8; reaction conditions = 115 rpm/28 min). According to the evaluated parameters, MSP presented an efficient complementary treatment, in which the integrity of the stages was sufficient for reaching regulatory levels in the effluent (Deliberação Normativa Conjunta COPAM/CERH-MG No. 1, May 5, 2008). 相似文献
995.
Pablo Souza-Alonso Alejandra Guisande Luís González 《Journal of environmental science and health. Part. B》2013,48(3):184-189
Triclopyr is a commonly used herbicide in the control of woody plants and can exhibit toxic effects to soil microorganisms. However, the impact on soils invaded by plant exotics has not yet been addressed. Here, we present the results of an 18-month field study conducted to evaluate the impact of triclopyr on the structure of fungal and bacterial communities in soils invaded by Acacia dealbata Link, through the use of denature gradient gel electrophoresis. After triclopyr application, analyses of bacterial fingerprints suggested a change in the structure of the soil bacterial community, whereas the structure of the soil fungal community remained unaltered. Bacterial density and F:B ratio values changed across the year but were not altered due to herbicide spraying. On the contrary, fungal diversity was increased in plots sprayed with triclopyr 5 months after the first application. Richness and diversity (H´) of both bacteria and fungi were not modified after triclopyr application. 相似文献
996.
997.
Eduardo J. Picco Héctor R. Fernández Diego C. Díaz David Manuel I. San Andrés Juan C. Boggio Casilda Rodríguez 《Journal of environmental science and health. Part. B》2013,48(5):405-409
The aim of this work was to study the pharmacokinetic behavior and the inhibitory effect of acetylcholinesterase (AChE) and butyrylcholinesterase (BChE) activities of chlorpyrifos (CPF) in steer cattle after pour-on administration. Determination of cholinesterase activity in plasma and erythrocyte was carried out according to Ellman kinetic method. CPF was analyzed by gas chromatography. AChE was the predominant form of cholinesterase analyzed, with low levels of BChE in plasma. Following the treatment with CPF, the maximum inhibitory effect on AChE or BChE were 50.88 ± 11.57 and 42.66 ± 12.01%, respectively. The chlorpyrifos plasma concentrations observed were low and they presented a high variability. Chlorpyrifos peak plasma concentration (10.42 ± 4.76 μ g/L) was reached at 8.42 ± 13.97 h. The pesticide was not detected in plasma after 48 h post treatment. The values of area under the curve (AUC) were 118.48 ± 87.46 μ g· h/L and mean resistance time (MRT) were 13.38 ± 10.41 h. The pour-on exposure to the organophosphate chlorpyrifos significantly reduced AChE and BChE activity in steer cattle and the recovery was not reached on 50 days post-treatment. 相似文献
998.
Maria A. L. Milhome Lucélia K. de Lima Crisiana de A. Nobre Francisco de A. F. Lima Ronaldo F. do Nascimento 《Journal of environmental science and health. Part. B》2013,48(12):786-792
AbstractThis study investigates the oxidation of trifluralin residues during ozonation in aqueous and food matrices (tomato). Domestic ozonation equipment with average production of 23.9?mg O3 L?1 h?1 was used in the tests. Modern chromatographic systems (SPME-GC-IT/MS/MS and QuEChERS-GC-IT/MS/MS) were applied for extraction and detection of trifluralin residue in fortified samples of ultrapure water, tap water, superficial water and tomato fruit. The samples were submitted to the ozonation process during 0, 5, 10 and 20?min. Treatment at 5?min was able to degrade 71.5% of herbicide trifluralin in surface water. The removal (%) in ultrapure water reached 83.4% after 20?min of ozonation. The degradation of trifluralin in fortified tomato samples (0.025–0.1?mg kg?1) were conducted with ozonation at 20?min, and it ranged from 84.4 to 92.7%. After treatment, levels of trifluralin in tomato remained within the established MRLs to EU, USEPA and ANVISA (Brazil). The data provided evidence that ozone is effective for removing trace trifluralin from water and foods. 相似文献
999.
1000.
Ongoing eutrophication is changing the Baltic Sea ecosystem. Aquaculture causes relatively small-scale nutrient emissions,
but local environmental impact may be considerable. We used substance flow analysis (SFA) to identify and quantify the most
significant flows and stocks of nitrogen (N) and phosphorus (P) related to rainbow trout aquaculture in Finland. In 2004–2007,
the input of nutrients to the system in the form of fish feed was 829 t N year−1 and 115 t P year−1. Around one-fifth of these nutrients ended up as food for human consumption. Of the primary input, 70% ended up in the Baltic
Sea, directly from aquaculture and indirectly through waste management. The nutrient cycle could be closed partially by using
local fish instead of imported fish in rainbow trout feed, thus reducing the net load of N and P to a fraction. 相似文献