全文获取类型
收费全文 | 25219篇 |
免费 | 175篇 |
国内免费 | 139篇 |
专业分类
安全科学 | 399篇 |
废物处理 | 1412篇 |
环保管理 | 3046篇 |
综合类 | 3498篇 |
基础理论 | 7352篇 |
环境理论 | 5篇 |
污染及防治 | 5814篇 |
评价与监测 | 2045篇 |
社会与环境 | 1863篇 |
灾害及防治 | 99篇 |
出版年
2022年 | 138篇 |
2021年 | 118篇 |
2020年 | 110篇 |
2019年 | 117篇 |
2018年 | 1626篇 |
2017年 | 1558篇 |
2016年 | 1489篇 |
2015年 | 411篇 |
2014年 | 494篇 |
2013年 | 1272篇 |
2012年 | 950篇 |
2011年 | 1996篇 |
2010年 | 1271篇 |
2009年 | 1160篇 |
2008年 | 1524篇 |
2007年 | 1891篇 |
2006年 | 617篇 |
2005年 | 554篇 |
2004年 | 566篇 |
2003年 | 583篇 |
2002年 | 600篇 |
2001年 | 671篇 |
2000年 | 486篇 |
1999年 | 263篇 |
1998年 | 185篇 |
1997年 | 207篇 |
1996年 | 208篇 |
1995年 | 245篇 |
1994年 | 237篇 |
1993年 | 185篇 |
1992年 | 202篇 |
1991年 | 185篇 |
1990年 | 208篇 |
1989年 | 191篇 |
1988年 | 155篇 |
1987年 | 164篇 |
1986年 | 154篇 |
1985年 | 158篇 |
1984年 | 162篇 |
1983年 | 152篇 |
1982年 | 126篇 |
1981年 | 120篇 |
1980年 | 117篇 |
1979年 | 126篇 |
1978年 | 101篇 |
1977年 | 116篇 |
1975年 | 89篇 |
1974年 | 88篇 |
1973年 | 96篇 |
1972年 | 86篇 |
排序方式: 共有10000条查询结果,搜索用时 171 毫秒
991.
Starch-based composite films have been proposed as food packaging. In this context, the study of non-conventional starch sources (sagu, Canna edulis Kerr) has worldwide special attention, because these materials can impart different properties as carbohydrate polymers. A thorough study of the matrices used (sagu starch and flour) was carried out. In the same way, thermoplastic starch (TPS)/PCL blend and thermoplastic flour (TFS)/PCL blend were obtained by melt mixing followed by compression moulding containing glycerol as plasticizer. In this study, chemical composition of the matrices and their properties were related with the properties of the developed films. Moisture content, water solubility, X-ray diffraction, thermogravimetric analysis and mechanical and microstructural properties were evaluated in the films. Taking into account the results, the sagu flour has great potential as starchy source for food packaging applications. However, concretely the flour had lower compatibility with the PCL compared to the starch/PCL blend. 相似文献
992.
993.
Andrzej Pukacz Mariusz Pełechaty Marcin Frankowski 《Environmental science and pollution research international》2016,23(22):22433-22442
The month-to-month variability of biomass and CaCO3 precipitation by dense charophyte beds was studied in a shallow Chara-lake at two depths, 1 and 3 m. Charophyte dry weights (d.w.), the percentage contribution of calcium carbonate to the dry weight and the precipitation of CaCO3 per 1 m2 were analysed from May to October 2011. Physical-chemical parameters of water were also measured for the same sample locations. The mean dry weight and calcium carbonate precipitation were significantly higher at 1 m than at 3 m. The highest measured charophyte dry weight (exceeding 2000 g m?2) was noted at 1 m depth in September, and the highest CaCO3 content in the d.w. (exceeding 80 % of d.w.) was observed at 3 m depth in August. The highest CaCO3 precipitation per 1 m2 exceeded 1695 g at 1 m depth in August. Significant differences in photosynthetically active radiation (PAR) were found between 1 and 3 m depths; there were no significant differences between depths for other water properties. At both sampling depths, there were distinct correlations between the d.w., CaCO3 content and precipitation and water properties. In addition to PAR, the water temperature and magnesium and calcium ion concentrations were among the most significant determinants of CaCO3 content and d.w. The results show that light availability seems to be the major factor in determining charophyte biomass in a typical, undisturbed Chara-lake. The study results are discussed in light of the role of charophyte vegetation in whole ecosystem functioning, with a particular focus on sedimentary processes and the biogeochemical cycle within the littoral zone. 相似文献
994.
995.
Leila Mehrparvar Siyamak Safapour Mousa Sadeghi-Kiakhani Kamaladin Gharanjig 《Environmental Chemistry Letters》2016,14(4):533-539
The classical use of synthetic dyes is causing issues of environmental pollution and heath risk. As a consequence natural dyes are gaining interest, but the use of natural dyes still includes toxic reagents such as metals as mordants and acids to enhance color and yield. Therefore, we designed a new chitosan-polypropylene imine dendrimer hybrid at 0–2000 mg/L to treat wool before dyeing with cochineal. We compared dye exhaustion, color depth, color characteristics, and color fastness of the new process with dyed pristine and metal mordanted wool. Results show that wool pretreatment improved dye exhaustion from 48 to 88 %, shifted saturation point toward lower dye concentration from 3000 to 1000 mg/L, and improved color depth from 13.68 for pristine wool and 15.17 for metal mordanted wool to 23.89 for the new process. 相似文献
996.
Patrick T.I. Lam Edwin H.W. Chan C.S. Poon C.K. Chau K.P. Chun 《Journal of environmental management》2010,91(3):654-661
Green specifications constitute one of the important elements in green construction. New sustainability requirements and changing priorities in construction management have spurred the emerging green specifications to a faster pace of development. A cross-sectional survey has been conducted in Hong Kong in 2007 to identify principal factors leading to the success of preparing green specifications. Based on extensive construction management literature, 20 variables concerning sustainable construction were summarized. Using the Mann–Whitney U-test, the subtle differences between stakeholders in specifying construction work have been detected even with the high consistency of the responses among the groups. Moreover, five independent factors for successful specification of green construction have been categorized by factor analysis. They are related to (1) green technology and techniques, (2) reliability and quality of specification, (3) leadership and responsibility, (4) stakeholder involvement, and (5) guide and benchmarking systems. Whilst the first and fourth factors are generally more important, different stakeholder groups have different emphases. The results of the survey have been validated against established principles. 相似文献
997.
Mehmet Sinan Bilgili Gamze Varank Elif Sekman Selin Top Didem Özçimen Remziye Yazıcı 《Environmental Modeling and Assessment》2012,17(3):289-300
Since phenols and phenolic compounds in many industrial wastewaters are toxic organic contaminants for humans and aquatic
life, to remove these compounds via the most efficient way is very important for environmental remediation treatment. In this
context, almost all of the isotherm models (Freundlich, Langmuir, Temkin, Redlich–Peterson, Sips, and Khan) for adsorption
in the literature were applied to explain the adsorption mechanism of 4-chlorophenol on activated carbon in this study. Also
theoretical modeling data were obtained using model equations; interpolation and analysis of variance were made to compare
data by using statistics software. In addition, the thermodynamic and kinetic studies for adsorption mechanism were included
in the article. The adsorption of 4-chlorophenol on activated carbon fits well to the pseudo-first-order kinetic model than
the pseudo-second-order, intraparticular diffusion and Bangham models. It is also indicated that 4-chlorophenol adsorption
by granular activated carbon would be attributed to a type of transition between physical and chemical adsorption rather than
a pure physical or chemical adsorption process. As a result, an environmental remediation problem and the adsorption mechanism
on activated carbon that can be regarded as a solution to this problem are described and explained using the mathematical
models and calculations in this study. 相似文献
998.
International environmental agreements (IEAs) can coordinate abatement of transboundary pollutants. This paper investigates
how heterogeneous countries facing a stock pollutant might structure such an agreement. In particular, we examine how an IEA
might be implemented with a set of monetary transfers. The focus is on transfers that are time invariant, linear in emissions,
and consistent with budget balance. There is a range of such schemes that would induce efficient emissions. We provide a simple
and intuitive characterization of these penalties and describe how specific proposals might be chosen in order to facilitate
compliance and implementation. Our proposals are illustrated with a simple example. We show that heterogeneity reduces the
scope for penalty schemes to jointly satisfy desirable properties. 相似文献
999.
Han I Mihalic JN Ramos-Bonilla JP Rule AM Polyak LM Peng RD Geyh AS Breysse PN 《Journal of the Air & Waste Management Association (1995)》2012,62(7):773-782
The main objectives of this study are to (1) characterize chemical constituents of particulate matter (PM) and (2) compare overall differences in PM collected from eight US. counties. This project was undertaken as a part of a larger research program conducted by the Johns Hopkins Particulate Matter Research Center (JHPMRC). The goal of the JHPMRC is to explore the relationship between health effects and exposure to ambient PM of differing composition. The JHPMRC collected weekly filter-based ambient fine particle samples from eight US. counties between January 2008 and January 2010. Each sampling effort consisted of a 5-6-week sampling period. Filters were analyzed for 25 metals using inductively coupled plasma mass spectrometry (ICP-MS). Overall compositional differences were ranked by principal component analysis (PCA). The results showed that weekly concentrations of each element varied 3-40 times between the eight counties. PCA showed that the first five principal components explained 85% of the total variance. The authors found significant overall compositional differences in PM as the average of standardized principal component scores differed between the counties. These findings demonstrate PCA is a useful tool to identify the differences in PM compositional mixtures by county. These differences will be helpful for epidemiological and toxicological studies to help explain why health risks associated with PM exposure are different in locations with similar mass concentrations of PM. 相似文献
1000.
Altaf H. Basta Houssni El-Saied Jerrold E. Winandy Ronald Sabo 《Journal of Polymers and the Environment》2011,19(2):405-412
Investigations have continued for production high performance agro-based composites using environmentally acceptable approaches.
This study examines the role of adding amide-containing biopolymers during synthesis of urea–formaldehyde (UF) on properties
of adhesive produced, especially its adhesion potential. The environmental performance of UF-resin synthesized in the presence
of modified amide-containing biopolymer was evaluated by evaluating the free-HCHO of both adhesive (during processing) and
of the eventual engineered composite product. Also, the benefits of this synthesis-modified adhesive in enhancing the bondability
of sugar-cane fibers used in engineered composite panels was evaluated and compared to using UF-resin. The results obtained
show that, static bending of the produced composites varied from 27.7 to 33.13 N/mm2 of modulus of rupture (MOR) and from 2860 to 3374 N/mm2 of Modulus of Elasticity (MOE); while for internal bond (IB) it’s varied from 0.64 to 0.866 N/mm2. Based on the ANSI and EN Standards modified UF-based agro composites produced meet the performance requirements for high
grade particleboards with respect to static bending strength. These agro-based composite also tested out as having free-HCHO
values of ~13 mg/100 g board. 相似文献