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91.
本文报道了以7碘8羟基喹啉5磺酸作荧光增强剂的Zn、Al激光时间分辨荧光测定方法。方法检出限分别为25μg/L和10μg/L。用牛肝粉标准品(NBS1577a)进行了验证  相似文献   
92.
The global cycles of man-produced pollutants entering the natural environment are reflected in changes of pollutant cycles, even in background regions.The system of mathematical balance simulation models of inorganic pollutant distribution and circulation (some heavy metals and pesticides included in the priority list for integrated background monitoring) has been developed for the Lake Baikal drainage basin. The system consists of the following units: (1) inventory and classification of regional sources of pollutants entering the atmosphere, natural waters and soils; (2) computation of the global atmospheric transfer and depositions; (3) regional spreading with atmospheric fluxes and deposition onto the underlying surfaces; (4) transport with waterflows feeding Lake Baikal; (5) transport with the lake currents and balance in the lake.The models developed have enabled improvement of existing programmes and systems of observations, in particular to substantiate the large-scale snow sampling and analysis network, and to develop the programme of integrated surveys of the state of Lake Baikal. Since 1981 these actions have been included in the operational network observations within the Lake Baikal Monitoring System.  相似文献   
93.
For detailed reconstructions of atmospheric metal deposition using peat cores from bogs, a comprehensive protocol for working with peat cores is proposed. The first step is to locate and determine suitable sampling sites in accordance with the principal goal of the study, the period of time of interest and the precision required. Using the state of the art procedures and field equipment, peat cores are collected in such a way as to provide high quality records for paleoenvironmental study. Pertinent field observations gathered during the fieldwork are recorded in a field report. Cores are kept frozen at -18 degree C until they can be prepared in the laboratory. Frozen peat cores are precisely cut into 1 cm slices using a stainless steel band saw with stainless steel blades. The outside edges of each slice are removed using a titanium knife to avoid any possible contamination which might have occurred during the sampling and handling stage. Each slice is split, with one-half kept frozen for future studies (archived), and the other half further subdivided for physical, chemical, and mineralogical analyses. Physical parameters such as ash and water contents, the bulk density and the degree of decomposition of the peat are determined using established methods. A subsample is dried overnight at 105 degree C in a drying oven and milled in a centrifugal mill with titanium sieve. Prior to any expensive and time consuming chemical procedures and analyses, the resulting powdered samples, after manual homogenisation, are measured for more than twenty-two major and trace elements using non-destructive X-Ray fluorescence (XRF) methods. This approach provides lots of valuable geochemical data which documents the natural geochemical processes which occur in the peat profiles and their possible effect on the trace metal profiles. The development, evaluation and use of peat cores from bogs as archives of high-resolution records of atmospheric deposition of mineral dust and trace elements have led to the development of many analytical procedures which now permit the measurement of a wide range of elements in peat samples such as lead and lead isotope ratios, mercury, arsenic, antimony, silver, molybdenum, thorium, uranium, rare earth elements. Radiometric methods (the carbon bomb pulse of (14)C, (210)Pb and conventional (14)C dating) are combined to allow reliable age-depth models to be reconstructed for each peat profile.  相似文献   
94.
乌鲁木齐市餐饮业油烟污染的调查及防治初探   总被引:1,自引:0,他引:1  
通过对乌鲁木齐市20家餐饮业油烟污染的调查分析,结果表明,乌鲁木齐市餐饮业油烟污染严重,并提出了防治措施。  相似文献   
95.
深圳市几种空气污染物浓度日变化特征分析   总被引:2,自引:0,他引:2  
通过对深圳市2002年8月至2003年8月五种空气污染物浓度日变化特征、相互关系及不同天气条件下的变化,与人们活动的关系等进行分析,试图找出深圳空气污染的主要成因及变化规律,为环境规划决策提供科学依据。  相似文献   
96.
研究了烟草中六六六及滴滴涕异构体含量的气相色谱分析方法.样品以石油醚 丙酮在索氏提取器中提取,提取液以浓硫酸净化.采用DB-5弹性石英毛细管柱分离样品,GC-ECD检测农药六六六、滴滴涕的残留量.方法的线性范围为2.27×10-13~7.66×10-11g;最小检测量为1.3×10-8~3.0×10-7 μg,加标平均回收率为95.3%~103.3%,RSD为2.8%~4.5%.  相似文献   
97.
A novel approach to the problem of estimating climate impact on social systems is suggested. This approach is based on a risk concept, where the notion of critical events is introduced and the probability of such events is estimated. The estimation considers both the inherent stochasticity of climatic processes and the artificial stochasticity of climate predictions due to scientific uncertainties. The method is worked out in some detail for the regional problem of crop production and the risks associated with global climate change, and illustrated by a case study (Kursk region of the FSU). In order to get local climatic characteristics (weather), a so-called statistical weather generator is used. One interesting finding is that the 3% risk level remains constant up to 1.0–1.1°C rise of mean seasonal temperature, if the variance does not change. On the other hand, the risk grows rapidly with increasing variance (even if the mean temperature rises very slowly). The risk approach is able to separate two problems: (i) assessment of global change impact, and (ii) decision making. The main task for the scientific community is to provide the politicians with different options; the choice of admissible (from the social point of view) critical events and the corresponding risk levels is the business of decision makers.  相似文献   
98.
构建了经济发展与生态环境评价指标体系,选用耦合协调度模型计算2010—2019年安徽省不同区域经济发展与生态环境的耦合协调度,并采用灰色关联度法计算评价指标与耦合协调度的关联系数。研究结果表明:全省经济发展与生态环境的耦合协调度整体呈改善趋势,耦合协调度集中分布在0.393~0.765,基本处于良好协调或低水平协调阶段。全省不同区域的生态环境指数均大于经济发展指数。省会城市、沿江江南地区耦合协调度高于江淮之间和淮河以北地区。工业"三废"排放量、环境质量、环境污染治理力度是影响经济发展与生态环境耦合协调度的重要因素,建议通过改善这些方面进一步提升经济与环境的耦合协调度水平。  相似文献   
99.
连续5天腹腔注射同一剂量(1/5LD50)的合成洗涤剂,取小鼠骨髓细胞测定嗜多染色红细胞的微核率,研究表明,3种合成洗涤剂(加大香洗衣粉,洁牌餐具洗涤剂,恩威高级餐具洗洁精)使小鼠微核率有所增高,但恩威,洁牌餐具洗涤剂与对照无显著性差异。  相似文献   
100.
16 priority polycyclic aromatic hydrocarbons (PAHs) were determined in water samples from the Jinsha River (Panzhihua part), Southwest China. Total dissolved PAH concentrations varied from 21.89 microg l(-1) to 382.8 microg l(-1). It was found that the concentration of PAHs decreased along the flow direction due to the higher density distribution of coal chemical industry in the upstream of our study rivers. The pollution levels in our study area are significantly higher than previously reported values in other waters both in China and other countries. The predominance of benzo[k]fluoranthene and indeno[1,2,3-cd]pyrene was clearly observed in all water samples. On average these two compounds accounted for 98.3% of the total dissolved PAH concentration in water. The results showed the positive correlations among total dissolved PAHs, benzo[k]fluoranthene and indeno[1,2,3-cd]pyrene, which suggested that these two predominant PAHs have similar source and environmental behaviors in our study area. When compared with the survey results of organic micropollutants two decades ago, it was found that hydrocarbon pollution both predominated and even increased with the development of coal chemical industry in this area during the past 20 years. The results therefore provide important information on the current contamination status of a key industrial city in China, and points to the need for urgent action to investigate the relationship between the PAH composition and concentration in water from the Jinsha River and the wastewater discharge from coal chemical industry, and to identify the source, transport pathway and fate of PAHs in the area. It should then be necessary to adopt appropriate and instant measures to control the pollution around this area.  相似文献   
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