Investigating the environmental Kuznets Curve and the role of green energy: Emerging and developed markets

In this study, the validity of the Environmental Kuznets Curve (EKC) hypothesis and the effect of green energy sources to decrease CO₂ emissions are examined for emerging and developed markets from 1990 to 2011 using a pooled mean group (PMG) estimator. Empirical findings of this study suggest that the EKC hypothesis is not confirmed by emerging markets; meanwhile, it is strongly supported by developed markets. The long-run elasticity results of per capita data may also imply a divergence between emerging markets and developed markets regarding CO₂ emissions. On the other hand, the findings of this study indicate that renewable energy sources will play an important role in reducing CO₂ emissions for both panel groups in the long run.     

Atmospheric concentrations and phase partitioning of polybrominated diphenyl ethers (PBDEs) in Izmir, Turkey

Atmospheric concentrations of 7 PBDE congeners (BDE-28, -47, -99, -100, -153, -154 and -209) were determined at four sites (i.e. Suburban, Urban 1, Urban 2, Industrial) in Izmir, Turkey and their gas/particle partitioning was investigated. Total PBDE ( summation operator(7)PBDE) concentrations ranged between 11 (Urban 1) and 149pgm(-3) (Industrial) in summer, while in winter, they ranged from 6 (Suburban) to 81pgm(-3) (Industrial). BDE-209 was the dominant congener at all sites, followed by BDE-99 and -47. Investigation of source profiles indicated that the air samples were dominated by congeners of the penta and deca-technical BDE mixtures. The measured PBDE particle fractions were compared to the predictions of the K(OA) (octanol-air partition coefficient)-based equilibrium partitioning model and to the dynamic uptake model developed by others for passive samplers, which was adapted to model gas-particle partitioning in this study. For BDE-28, good agreement was observed between the experimental particle fractions and those predicted by the equilibrium partitioning model. However, this model overestimated the particle fractions of other congeners. The predictions of the dynamic uptake model supported the hypothesis that the unexpectedly high partitioning of BDEs (except BDE-28) to the gas-phase is due to their departure from equilibrium partitioning. When congeners with very large octanol-air partition coefficients (i.e. BDE-100, -99, -154, -153, and -209) are emitted from their sources in the gas-phase, they may remain in that phase for several months before reaching equilibrium with atmospheric particles. This may also have important implications for the transport of atmospheric PBDEs. For example, in addition to particle-bound transport, the gas-phase transport of highly brominated congeners (i.e. BDE-209) may also be important.     

Ambient concentrations and source apportionment of PCBs and trace elements around an industrial area in Izmir, Turkey

Atmospheric concentrations of polychlorinated biphenyls (PCBs) and trace elements were measured at two sites (Industrial and Urban) located around the Aliaga industrial region, Izmir, Turkey. Average sigma 36PCB concentrations were 3136+/-824 and 1371+/-642 pg m(-3) for summer and winter periods, respectively in the Industrial site and they were 314+/-129 and 847+/-610 pg m(-3) in the Urban site. The elemental content showed that the PM(10) measured at the Industrial site was dominated by terrestrial elements and trace elements emitted by the iron-steel plants (Fe, Zn and Pb). The elemental profile at the Urban site was typical for Aegean Region that was dominated by terrestrial elements (Ca, Al, Mg) and sea salt (Na). Sources of particle-phase PCBs and trace elements were identified using factor analysis (FA) and were apportioned by chemical mass balance (CMB) model. FA suggested that the steel industry, fuel oil combustion, or the nearby vinyl chloride process in the petrochemical plant, and soil were significant PCB sources. CMB results showed that at the Industrial site, the contribution of steel industry and soil to particle-phase PCBs were 71% and 22%, respectively, while at the Urban site, the contributions were 33% and 49%, respectively. Steel industry was also the dominant contributor for trace elements around the site. Fugacity calculations in air and soil showed that the soil acts as a secondary source to the atmosphere for low molecular weight PCBs especially in summer and as a sink for the higher molecular weight ones.     

Characterization of Volatile Organic Compounds (VOCs) and Their Sources in the Air of Izmir, Turkey

Air samples were collected in Izmir, Turkey at two (suburban and urban) sites during three sampling programs in 2002 and 2004 to determine the ambient concentrations of several monoaromatic, chlorinated and oxygenated volatile organic compounds (VOCs). Samples were analyzed for 60 VOCs using gas chromatography/mass spectrometry and 28 compounds were detected in most samples. On the average, urban air VOC concentrations were about four times higher than those measured at the suburban site. Toluene (40.6%) was the most abundant compound in suburban site and was followed by benzene (7.4%), o,m-xylene (6.5%), and 1,2-dichloroethane (5.1%). In urban site, toluene (30.5%), p-xylene (14.9%), o,m-xylene (11.4%), and ethyl benzene (7.2%) were the dominating compounds in summer. In winter, toluene (31.1%), benzene (23.9%), 1,2-dichloroethane (9.5%), and o,m-xylene (8.2%) were the most abundant compounds. Receptor modeling (positive matrix factorization) has been performed to estimate the contribution of specific source types to ambient concentrations. Six source factors (gasoline vehicle exhaust, diesel vehicle exhaust+residential heating, paint production/application, degreasing, dry cleaning, and an undefined source) were extracted from the samples collected in the urban site. Three source factors (gasoline vehicle exhaust, diesel vehicle exhaust, and paint production/application) were identified for the suburban site.     

Evaluation of vegetable based cutting fluids with extreme pressure and cutting parameters in turning of AISI 304L by Taguchi method

Many problems such as health and environment issues are identified with the use of cutting fluids (CFs). There has been a high demand for developing new environmentally friendly CFs such as vegetable based cutting fluids (VBCFs) to reduce these harmful effects. In this study, performances of six CFs, four different VBCFs from sunflower and canola oils with different ratios of extreme pressure (EP) additives, and two commercial types of CFs (semi-synthetic and mineral) are evaluated for reducing of surface roughness, and cutting and feed forces during turning of AISI 304L austenitic stainless steel with carbide insert tool. Taguchi’s mixed level parameter design (L₁₈) is used for the experimental design. Cutting fluid, spindle speed, feed rate and depth of cut are considered as machining parameters. Regression analyses are applied to predict surface roughness, and cutting and feed forces. ANOVA is used to determine effects of the machining parameters and CFs on surface roughness, cutting and feed forces. In turning of AISI 304L, effects of feed rate and depth of cut are found to be more effective than CFs and spindle speed on reducing forces and improving the surface finish. Performances of VBCFs and commercial CFs are also compared and results generally show that sunflower and canola based CFs perform better than the others.     

Unsustainable urban development for Zonguldak metropolitan area (NW Turkey)

Since Turkey is located on a region that is prone to the risks of natural disasters like earthquake, flooding, and avalanche; a majority of the residential areas are facing these risks at various levels. Before determination of these risks, taking action in order to decrease the vulnerability levels of the residential areas will help keep the damage at the minimum level in case of a disaster. Urban planning decisions which are made in accordance with vulnerability studies aiming to determine natural disaster risks will not only help prevent loss of life but also help decrease negative social and economic effects of disasters. The Zonguldak city has been chosen as a case study area since Zonguldak metropolitan area has endured almost all kinds of threats that a city can face. In this study disaster-producing factors in the area are primarily considered which can be named as topography, destruction of forest lands, geological and karstic structure, mining activities, and misuse of the land, and later risk assessment is conducted with geographic information system (GIS). It has been assessed that more than half of the buildings within the study area were constructed in areas not suitable for housing. It is concluded that there is a need for urgent urban development plan for the city.     

Income inequality and CO2 emissions: nonlinear evidence from Turkey

The income inequality-economy link has been argued by researchers a long time. But the impact of income inequality on environmental pollution is a new investigation topic for developing countries. Turkey is well known as an emerging economy which has a high level of income inequality and CO₂ emissions. Therefore, this paper concentrates on the income inequality-CO₂ emissions link in Turkish economy by applying a nonlinear analysis. This paper integrates economic growth and financial development to the CO₂ emissions specification over the period of 1987–2019. We employ the nonlinear autoregressive distributed lag approach to explore the long-run nonlinear linkages between the series. Our findings reveal an asymmetric cointegration among variables. Positive and negative income inequality shocks positively affect CO₂ emissions implying that positive and negative shocks of income inequality enhance CO₂ emissions in the long run. Negative economic growth shocks decrease CO₂ emissions, while positive shocks to financial development increase CO₂ emissions in the long run. We provide important policy suggestions that might be useful to the policymakers to decrease CO₂ emissions in Turkey.