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91.
Prediction for thermodynamic function of dioxins for gas phase using semi-empirical molecular orbital method with PM3 Hamiltonian 总被引:1,自引:0,他引:1
In this investigation, respective thermodynamic parameters of heats of formation, standard entropy and specific heat capacity at constant pressure for PCDDs, PCDFs, Co-PCB and PCBs as well as polychlorinated-benzenes and polychlorinated-phenols have been evaluated by quantum chemical calculation using a semi-empirical molecular orbital method with the PM3 Hamiltonian and statistical thermodynamic correlation. 相似文献
92.
Dr. Naomichi Matsumoto Nakamichi Saito Naoki Harada Kiyoji Tanaka Norio Niikawa 《黑龙江环境通报》1995,15(7):675-677
DNA-based prenatal carrier detection of group A xeroderma pigmentosum (XP-A) is reported. Chorionic villus sampling was done at the tenth gestational week in a pregnant woman whose first child suffers from XP-A. Genomic DNAs from the villi, proband, and parents were PCR (polymerase chain reaction)-amplified using three sets of primers, because the PCR and a subsequent enzyme digestion with HphI, AlwNI, or MseI may detect the three most frequent mutations of the XP-A complementing gene (XPAC) in Japanese XP-A patients. The results showed that the proband is a homozygote and that the parents and fetus are heterozygotes for a base substitution at the 3′ acceptor site of intron 3 of XPAC, indicating that the fetus is a healthy carrier of XP-A. This is the first case of prenatal carrier detection of the disorder. 相似文献
93.
The need for quality control of the complex micro-structure has been growing due to increased production of parts with complex 3D micro-scale features. However, wide use of 3D metrology of miniature parts is difficult due to the lack of cost-effective and precise probing system at the micro-scale. This paper introduces a new probing system using a wire-based probe and acoustic emission (AE)-based sensing method. The design of the probing system allows the size of the probe to be varied relatively easily. Repeatability of less than 1 μm has been achieved with the proposed probing system. 相似文献
94.
M. Koroki S. Saito H. Hashimoto T. Yamada Masakazu Aoyama 《Environmental Chemistry Letters》2010,8(1):59-61
We prepared a carbonaceous sorbent for Cr(VI) from the culm of Sasa
kurilensis by dehydration with concentrated H2SO4. The removal of Cr(VI) by the sorbent was highly solution pH dependent and mainly governed by physicochemical sorption. The
equilibrium data fit well in the Langmuir isotherm model and indicate the endothermic nature of the Cr(VI) sorption. The desorption
experiments suggest that the Cr(VI) sorption is generally irreversible, owing to strong interaction of HCrO4− with the active sites of the sorbent. 相似文献
95.
Various elements and inorganic ions in rice straw and ash samples were analyzed by using inductively coupled plasma atomic emission spectrometry (ICP‐AES) and ion chromatography (IC). Five major elements: Mg, Mn, Al, Ca, and Fe and eight minor and trace elements: Cr, Cu, Ti, Zn, La, Sr, Ba, and Hg were detected in these samples, at more than ppm‐level. In ash samples the trace elements such as Y, As, V, Se, and Sc were also identified. The concentrations of SO4, PO4, Cl, Na, and K ions in these samples were higher than those of other ions measured. These elements and inorganic ion concentrations were approximately one order of magnitude higher in the ash than in the straw samples. Gas chromatography/mass spectrometry (GC/MS) and library search showed the presence of fatty‐, carboxylic‐ and nicotinic acids, and their derivatives in small quantities in the straw samples. 相似文献
96.
Yutaka Saito Anthony R. Chittenden Kotaro Mori Katsura Ito Atsushi Yamauchi 《Behavioral ecology and sociobiology》2008,63(1):33-42
The number of nests containing egg masses a female makes over her lifetime and the pattern of scattering nests vary among
species in a genus of nest-weaving spider mites (Stigmaeopsis). We hypothesized that the scattered nests of small nest builders have a previously overlooked indirect effect in that the
void nests created after predation take on a new role as hindering devices that effectively decrease predator searching efficiency.
First, we demonstrated that the experimental design used in this study is a good reflection of the nest distribution pattern
of Stigmaeopsis takahashii (an intermediate-sized nest builder) in the field. Using this species as a model, we tested how different nest-scattering
patterns affect the predator to examine how scattering may indirectly provide an anti-predation strategy by increasing a predators
searching time. Next, we observed how artificially arranged void nests disturb predatory behavior in both starved and fully
fed predator females and showed that void nests have a strong hindering effect on predators. Thus, we concluded that the nesting
behavior of this mite species not only has anti-predator effects but must also have a stabilizing effect on predator–prey
interaction systems at the population level. 相似文献
97.
98.
99.
Miyajima K Itabashi G Koshida T Tamari K Takahashi D Arakawa T Kudo H Saito H Yano K Shiba K Mitsubayashi K 《Environmental monitoring and assessment》2011,182(1-4):233-241
Immunoassay methods are generally used for measuring of allergenic substances. However, they need special facilities, skilled handling, and time-consuming procedure. In this work, a fiber-optic immunoassay system which could measure allergen by fluorescent intensities of immune complexes formed by allergens and fluorescently labeled antibodies was established. Immune complexes absorbed on the optical fiber probe surface, and excitation light was injected into the probe, then evanescent field is created in the proximity of the probe. The fluorophores were excited by the evanescent light, and fluorescence was detected by a photo diode. The target allergen detected by our system was Der f1 derived from Dermatophagoides farinae that is one of the house dust mite and major source of inhaled allergens. The fluorophore used labeling on detecting antibody was cyanine 5. The system enabled to detect and quantitatively determine of Der f1. The measurement range was from 0.24 to 250?ng/ml, and the result competes with ELISA. The measurement time was 16?min/sample. The immunoassay system was applied to measurement of Der f1 from actual dust samples. Calculated values of Der f1 showed good correlations between the fiber-optic fluoroimmunoassay and ELISA. 相似文献
100.
Sou Matsunaga Michihiro Mochida Takuya Saito Kimitaka Kawamura 《Atmospheric environment (Oxford, England : 1994)》2002,36(39-40)
Isoprene (2-methyl-1,3-butadiene) was measured on board of R/V Mirai for eight air samples and 14 seawater samples collected in the western North Pacific during ACE-Asia campaign (from 18 to 26 May 2001). The measurements were conducted in situ using a cryo-focus/gas chromatography/mass spectrometry (Cryo/GC/MS). Concentrations of isoprene ranged from 7.2 to 110 parts-per-trillion (pptv) in the marine air, and ranged from below 12 to 94 pmol l−1 in the seawater. Based on these results, sea-to-air fluxes of isoprene were calculated to be 184 and 300 nmol m−2 day−1 for two samples, and the upper limits of the fluxes were also calculated to be from 32 to 300 nmol m−2 day−1. Atmospheric isoprene concentrations cannot be explained only by the flux from the seawater. Thus, the concentrations of isoprene in the marine air in western North Pacific should be significantly affected by terrestrial vegetational emission and subsequent long-range atmospheric transport of isoprene. 相似文献