Integrated hydrologic–economic decision support system for groundwater use confronting climate change uncertainties in the Tunuyán River basin,Argentina

This study presents an integrated hydrologic–economic model as decision support system for groundwater use and incorporates uncertainties of climate change. The model was developed with the Vensim software (Ventana Systems) for system dynamic simulations. The software permitted the integration of economic variables along with hydrologic variables, in a unified format with the aim of evaluating the economic impacts of climate change on arid environments. To test the model, we applied it in one of the upper Tunuyán River sub-basin, located in the Mendoza Province (Argentina), where irrigation comes from groundwater. The model defines the best mix of crops and the total land use required to maximize the total river sub-basin monetary income, considering as a limit the amount of water that does not exceed the natural annual aquifer recharge. To estimate the impacts of climatic changes, four scenarios were compared: the business as usual (with the number of existing wells) in a dry year with a temperature increase of 4 °C; the business as usual in a wet year with an increase in temperature of 1.1 °C; an efficient use of wells in a dry year and a temperature increase of 4 °C and an efficient use of wells in a wet year with a temperature increase of 1.1 °C. Outputs calculated by the model were: land use per crop, total sub-basin net benefit, total sub-basin water extraction, water extraction limit depending on river discharge and total number of wells required to irrigate the entire area. Preliminary results showed that the number of existing wells exceeded the optimized number of wells required to sustainably irrigate the entire river sub-basin. Results indicated that in an average river discharge year, if wells were efficiently used, further rural development would be possible, until the limit of 350 million m³ of water extraction per year was reached (650 million m³ for a wet year and 180 million m³ for a dry year). The unified format and the low cost of the software license make the model a useful tool for Water Resources Management Institutions, particularly in developing countries.     

Spatial variability of precipitation in Spain

The spatial variability of annual and seasonal precipitation in the conterminous land of Spain has been evaluated by using correlation decay distance analysis (CDD). The CDD analysis essentially explores how the correlation between neighbouring stations varies according to distance. We analysed CDD independently for the decades 1956–1965, 1966–1975, 1976–1985, 1986–1995, and 1996–2005 using only those stations with no missing values for each decade. To this end, 972, 1,174, 1,242, 773 and 695 complete series were used for each decade, respectively. In particular, for each station and decade, we calculated the threshold distance at which the common variance between target (i) and neighbour series is higher than 50 % (r ²  = 0.5) to evaluate whether current density of the climate data set captures the spatial variability of precipitation within the study area. Results indicate that, at an annual scale, neighbouring stations with 50 % of common variance are restricted on average to about 105 km, but this distance can vary from 28 to 251 km within the study area. The lowest variability is located to the SW and in winter, while the higher spatial variability is found to the north, in the Cantabrian area, and to the east, in the Mediterranean and Pyrenees, during summer. Our results suggest that current density of climate stations (those operating in 2005) is good enough to study precipitation variability at an annual scale for winter, spring and autumn, but not enough for summer.     

Aboveground biomass and carbon stock are related with soil humidity in a mangrove at the Piraquê-Açu River,Southeastern Brazil

In Brazil, few studies have been conducted about the assimilation of carbon and biomass accumulation in mangroves despite its great role as a carbon sink. In this sense, this study aimed to estimate the aboveground biomass (AGB) and carbon stocked by mangrove species in a stretch along the Piraquê-Açu River in southeastern Brazil, and to verify their relation with some soil parameters. For such, the height and diameter of all trees inside six plots of 100 m² were measured and used to quantify AGB through an allometric equation, and soil samples were collected to calculate granulometry, humidity, time of infiltration and permeability. Multiple regressions were used to identify relations between AGB and soil parameters. A total of 296 trees were found in the area and the AGB and carbon assimilated were 2.92 t ha^?1 and 1.46 t ha^?1, respectively. Laguncularia racemosa was the most abundant species and contributed with 61% of these values. Only a positive relation between AGB/carbon of L. racemosa and soil humidity was found, probably due to the substrate characteristics which contain a large concentration of silt/clay, and may store more water and do not yet provide firmness to the roots. By comparison, this mangrove had a low amount of AGB and carbon stocked and has yet to develop structurally. Along with other ecological functions and its associated ecosystem services such as supplying food for the local community, these features highlight the importance to conserve the studied mangrove and the interlinked coastal ecosystems.     

Forensic Evaluation of Metals (Cr,Cu, Pb,Zn), Isotopes (δ13C and δ15N), and C:N Ratios in Freshwater Sediment

A forensic approach was used to evaluate sediments from Portão Stream, including analysis of metals, carbon (C) and nitrogen (N) stable isotopes, and C:N ratios. Samples collected at various points located along the stream were tested in order to investigate a possible illegal leachate input. The studied stream is heavily impacted by sewage and industrial discharges from two cities along its course. Among the metals analyzed, chromium (Cr) was noticeably the main pollutant, showing the highest levels, above regulatory limits, downstream from some potential sources of effluents enriched with this metal. Isotope analyses revealed a general trend of depletion in the heavier isotope along the stream for C and N. The exception was one point near a hazardous waste landfill, where relatively more enriched δ¹³C and δ¹⁵N values were found. The isotope and metal analysis results indicated that this site was affected by a particular source, demonstrating the combination of these parameters could be used for the discrimination of sources in a heavily polluted stream. Nevertheless, further investigations are necessary to provide a comprehensive evaluation of the biogeochemical processes involved in the incorporation of leachate in sediments to use this analysis as evidence for the illegal leachate discharge.     

Polyfunctional Plants for Industrial Waste Disposal—Part II: Economics and Model Evaluation

ABSTRACT

This is the second part of a two-part paper dealing with the preliminary design and costing of polyfunctional waste treatment plants. In this article, we present some criteria for estimating capital investment and annual operating costs of polyfunctional plants for industrial waste treatment. The process and equipment design methods presented in Part I of this article, together with the economic approach proposed here, allow for complete technical/economic analyses. The overall mathematical model appears to be a useful tool in economic feasibility studies. The accuracy of the developed computer mathematical model has been demonstrated, referring to actual cost data from the literature.     

Risk assessment of trihalomethanes from tap water in Fortaleza, Brazil

The cancer risks (CR) by oral ingestion, dermal absorption, and inhalation exposure of trihalomethanes (THM) from tap water of ten districts in Fortaleza, Brazil were estimated. The mean levels of THM compounds were obtained in Fortaleza tap water as follow: 63.9 microg L(-1) for chloroform (CHCl(3)), 40.0 microg L(-1) for bromodichloromethane (CHBrCl(2)), and 15.6 microg L(-1) for dibromochloromethane (CHBr(2)Cl). Bromoform (CHBr(3)) was not detected. The mean CR for THMs in tap water is 3.96 x 10(-4). The results indicate that Fortaleza residents have a higher CR by inhalation than dermal absorption and oral ingestion. The CR for CHCl(3) contributes with 68% as compared with the total CR, followed by CHBrCl(2) (21%), and CHBr(2)Cl (11%). The hazard index (HI) is about ten times lower than unity, not indicating non-cancer effects.     

Environmental analysis of a construction and demolition waste recycling plant in Portugal – Part I: Energy consumption and CO2 emissions

This work is a part of a wider study involving the economic and environmental implications of managing construction and demolition waste (CDW), focused on the operation of a large scale CDW recycling plant. This plant, to be operated in the Lisbon Metropolitan Area (including the Setúbal peninsula), is analysed for a 60 year period, using primary energy consumption and CO₂eq emission impact factors as environmental impact performance indicators.Simplified estimation methods are used to calculate industrial equipment incorporated, and the operation and transport related impacts. Material recycling – sorted materials sent to other industries, to act as input – is taken into account by discounting the impacts related to industrial processes no longer needed.This first part focuses on calculating the selected impact factors for a base case scenario (with a 350 tonnes/h installed capacity), while a sensitivity analysis is provided in part two. Overall, a 60 year global primary energy consumption of 71.4 thousand toe (tonne of oil equivalent) and a total CO₂eq emission of 135.4 thousand tonnes are expected. Under this operating regime, around 563 thousand toe and 1465 thousand tonnes CO₂eq could be prevented by replacing raw materials in several construction materials industries (e.g.: ferrous and non-ferrous metals, plastics, paper and cardboard).     

Cost-Effectiveness Analysis of Waste Gas Treatment Plants for the Glass Industry

ABSTRACT

Cost-effectiveness of different plant solutions for glass furnace waste gas cleaning is compared in the present paper. Plant arrangements based on electrostatic precipi-tator or fabric filter dust collectors and wet, semi-dry, or dry processes for acid gas removal have been considered. A critical survey of each solution's advantages and disadvantages has been presented, taking into account both effectiveness and costs resulting from each available system. Finally, a quantitative assessment has been provided with reference to a case study involving actual float glass production lines at SIV plants located in northern and central Italy.     

Appraisal of water matrix on the removal of fungicide residues by heterogeneous photocatalytic treatment using UV-LED lamp as light source

Environmental Science and Pollution Research - In this study, the photocatalytic degradation of four fungicides, myclobutanil, penconazole and difenoconazole (triazole compounds) and boscalid...