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981.
982.
983.
Guangke Li Fen Hou Zhen Guo Gaoyi Yao Nan Sang 《Waste management (New York, N.Y.)》2011,31(11):2203-2207
To investigate the feasibility of using aged municipal solid waste as farmland soil, it is essential to study its nutritive compositions for plant growth. Previous studies have demonstrated that the properties of different particle-size aged refuse are very different, therefore, the present study was conducted to evaluate the adequacy of three elements (N, P, K) and the fractionation of inorganic P in the aged refuse with a particle-size distribution of 900 to 300, 300 to 150, 150 to 105, 105 to 90 and 90 to 0 μm. The results indicate that (1) total quantities of N, P, K were much larger than that in the general soil and the quantities of available N, P and K were also adequate; (2) total content of P was sufficient, but the ratio of available-P to total P was not high enough; (3) with the decrease of particle size, the contents of these elements presented different trends. The results implicate that total contents of N, P and K were enough for the aged refuse being exploited as cultivated soil, and different gradation of aged refuse could be added to improve poor soils. It provides scientific evidence for utilizing different particle-size aged refuse comprehensively. 相似文献
984.
Sorption of apolar and polar organic contaminants by waste tire rubber and its chars in single- and bi-solute systems 总被引:1,自引:0,他引:1
Lian F Huang F Chen W Xing B Zhu L 《Environmental pollution (Barking, Essex : 1987)》2011,159(4):850-857
Single- and bi-solute sorption of organic compounds [1,3-dichlorbenzene (DCB), 1,3-dinitrobenzene (DNB) and 2,4-dichlorophenol (DCP)] on ground tire rubber and its chars was studied. The chars were prepared by pyrolyzing tire rubber at different temperatures (200-800 °C). Their surface area, aromaticity and hydrophobicity increase greatly with pyrolytic temperature, and the polymeric phase is partly converted into a condensed phase. The sorption of DNB and DCP increases with pyrolytic temperature and is characterized by a transition from a partition dominant to an adsorption dominant process. However, the sorption of DCB linearly decreases with the pyrolytic temperature. The enhanced adsorption of DNB and DCP on carbonized phase is primarily attributed to nonhydrophobic interactions such as π-π electron-donor-acceptor interactions and/or H bonding. The higher partition of DCB to polymeric phase is attributed to its high hydrophobicity. Competitive sorption between DCB and DCP on the tire chars is highly dependent on dissociation of the latter. 相似文献
985.
Simultaneous adsorption and degradation of γ-HCH by nZVI/Cu bimetallic nanoparticles with activated carbon support 总被引:1,自引:0,他引:1
Chun Chang Fei Lian Lingyan Zhu 《Environmental pollution (Barking, Essex : 1987)》2011,159(10):2507-2514
Cu amended zero valent iron bimetallic nanoparticles were synthesized by doping Cu on the surface of iron. They were incorporated with granular activated carbon (AC) to prepare supported particles (AC-Fe0-Cu), which were used to remove γ-HCH. Cu on the surface of iron enhanced the dechlorination activity of Fe0. The dechlorination rate constant (kobs) increased with the Cu loading on the surface of iron and the maximum was achieved with 6.073% Cu. AC as a support was effective for increasing the dispersion of the nanoparticles and avoiding the agglomeration of the metallic nanoparticles. The simultaneous adsorption of γ-HCH on AC accelerated the degradation rate of γ-HCH by the bimetals. After reaction for 165 min, around 99% of γ-HCH was removed by the solids of AC-Fe0-Cu. In addition, AC could adsorb the degradation products. The degradation of γ-HCH was mainly through dehydrochlorination and dichloroelmination based on the intermediate products detected by GC/MS. 相似文献
986.
In this paper, elimination of two types of organophosphorus pesticides (OPPs), chlorpyrifos and diazinon spiked in aqueous solution by ultrasonic irradiation was investigated. Results showed that chlorpyrifos and diazinon could be effectively and rapidly degraded by ultrasonic irradiation, and the degradation of both pesticides was strongly influenced by ultrasonic power, temperature and pH value. Furthermore, two and seven products for the degradation of chlorpyrifos and diazinon formed during ultrasonic irradiation have been identified by gas chromatography-mass spectrometry, respectively. The hydrolysis, oxidation, hydroxylation, dehydration and decarboxylation were deduced to contribute to the degradation reaction and the degradation pathway for each pesticide under ultrasonic irradiation was proposed. Finally, the toxicity evaluation indicated that the toxicity decreased for diazinon solution after ultrasonic irradiation, but it increased for chlorpyrifos solution. The detoxification of OPPs by ultrasonic irradiation was discriminative. 相似文献
987.
Occurrence and partition of perfluorinated compounds in water and sediment from Liao River and Taihu Lake, China 总被引:14,自引:0,他引:14
The concentrations of four perfluorinated sulfonate acids (PFSAs) and 10 perfluorinated carboxylate acids (PFCAs) were measured in water and sediment samples from Liao River and Taihu Lake, China. In the water samples from Taihu Lake, PFOA and PFOS were the most detected perfluorinated compounds (PFCs); in Liao River, PFHxS was the predominant PFC followed by PFOA, while PFOS was only detected in two of the samples. This suggests that different PFC products are used in the two regions. PFOS and PFOA in both watersheds are at similar level as in the rivers of Japan, but significantly lower than in Great Lakes. The contributions of PFOS and long chain PFCAs in sediments were much higher than in water samples of both watersheds, indicating preferential partition of these PFCs in sediment. The concentrations of PFOS and PFOA were three orders of magnitude of lower than that of polycyclic aromatic hydrocarbons in the same sediments. The average sediment-water partition coefficients (log Koc) of PFHxS, PFOS and PFOA were determined to be 2.16, 2.88 and 2.28 respectively. 相似文献
988.
Release of hexachlorocyclohexanes from historically and freshly contaminated soils in China: implications for fate and regulation 总被引:1,自引:0,他引:1
Duan L Zhang N Wang Y Zhang C Zhu L Chen W 《Environmental pollution (Barking, Essex : 1987)》2008,156(3):753-759
Hexachlorocyclohexanes (HCHs) were produced and used in large quantity worldwide and are common soil pollutants. In this study, desorption of α-HCH and γ-HCH from two soil samples collected from a historical pesticide plant in Tianjin, China, was examined. As a comparison, desorption of freshly sorbed γ-HCH was examined, using five typical Chinese soils. Strong resistant desorption was observed for both historically contaminated and freshly contaminated soils, and desorption results were well modeled with a biphasic desorption isotherm. The unique thermodynamic characteristics associated with the desorption-resistant fraction indicated that physical constraint within soil organic matrices was likely the predominant mechanism controlling resistant desorption. Resistant desorption could have significant effects on fate and exposure of HCHs in soil environment. More accurate biphasic desorption models that take into account of the resistant desorption can be used to facilitate regulating, management and remediation of HCH-contaminated sites. 相似文献
989.
四川汶川8.0级地震间接经济损失评估方法 总被引:8,自引:5,他引:3
国内生产总值(GDP)是衡量该地区经济总量和经济发展水平的重要指标.灾区内各评估子区震害程度、企业服务业恢复生产营业时间以及地震对企业服务业生产营业影响时间与地震间接经济损失有直接的关系.在研究了国内外有关地震间接经济损失评估研究成果的基础上,根据现场灾害调查结果,结合灾区实际,提出利用灾区各市(县)国内生产总值GDP(第二、三产业)数据、各评估子区震害系数、企业服务业生产营业恢复时间以及地震对企业服务业生产营业影响时间,进行地震灾害间接经济损失评估方法. 相似文献
990.