三元复合驱采出水中悬浮固体的控制方法

采用向三元复合驱采出水中加入水质稳定剂的方法有效降低采出水中悬浮固体的质量浓度。实验结果表明,将100 g采出水依次经滤纸和孔径为0.45μm的醋酸纤维素膜过滤后,加入1.0 g WSBL-3型水质稳定剂,混合均匀后置于80℃的水浴中静置4 h,取出后再置于40℃的水浴中静置5 min,由此可将采出水中的悬浮固体质量浓度由107 mg/L降至2 mg/L。     

Evaluation on the toxicity of ionic liquid mixture with antagonism and synergism to Vibrio qinghaiensis sp.-Q67

Ionic liquids (ILs) are a fascinating group of new chemicals with the potential to replace the classical volatile organic solvents, stimulating many applications in chemical industry. In case ILs are released to the environment, possible combined toxicity should be taken into account and it is, however, often neglected up to now. In this paper, therefore, the concentration-response curves (CRCs) of four groups of IL mixtures with various mixture ratios to Vibrio qinghaiensis sp.-Q67 were determined using the microplate toxicity analysis and were compared to the CRCs predicted by an additive reference model, the concentration addition (CA) or independent action (IA), to identify the toxicity interaction. It is showed that most of the IL mixture rays displayed the classical addition while the remaining rays exhibited antagonism or synergism. Moreover, it is found that the pEC₅₀ values of the mixture rays exhibiting antagonism or synergism are well correlated with the mixture ratio of a certain IL therein.     

Characteristics and assessment of phthalate esters in urban dusts in Guangzhou city, China

Phthalate esters (PAEs) were examined in indoor and outdoor dust samples from the subtropical city of Guangzhou, China. The ∑(16)PAEs concentrations ranged from 121 to 3,223 μg g(-1) dust, with the median concentration of 840 μg g(-1) dust. Significantly higher concentrations of PAEs in dust samples were found in offices where electrical and electronic devices, carpet pads, and office furniture were widely used. Of the 16 PAEs, diisobutyl phthalate (DiBP), di-n-butyl phthalate (DnBP), and di(2-ethylhexyl) phthalate (DEHP) dominated the PAEs in indoor and outdoor dust samples, and accounted for >96.8% and >93.1% of the ∑(16)PAEs concentrations, respectively. The median daily inhalation exposure of ∑(16)PAEs were 3.53 and 0.247 μg kg(-1) body weight day(-1), and at the 95(th) percentile were 7.62 and 0.530 μg kg(-1) body weight day(-1), up on the measured concentrations and estimated dust ingestion rates, respectively, for toddles and adults. The ubiquitous distribution of PAEs as noted in this study suggests the need for detailed assessment of PAEs concentrations using more sites and to further investigate the factors influencing PAEs exposure in China.     

不同粒径泥沙理化特性对磷吸附过程的影响

以北京大兴南海子湖表层沉积物为研究对象,测试分析了0.147～0.246 mm(细砂)、0.074～0.147 mm(极细砂)、0.0385～0.0740 mm(粉粒)和<0.0385 mm(粉粒粘粒混合物)4种粒径泥沙对磷的吸附行为,并采用相关分析及逐步回归分析探讨不同粒径沉积物中有机质(OM)、Fe、Al、Ca、Mn和TP含量对磷吸附过程的影响。结果表明,二级动力学方程和Langmuir模型能较好地描述南海子不同粒径泥沙的吸附动力学及等温吸附过程(R2>0.90)。粒径对单位质量泥沙吸附磷量具有明显影响,粉粒粘粒混合物>粉粒>细砂>极细砂。总体上,泥沙有机质(OM)、TP、Fe、Al、Ca和Mn含量随粒径的减小而增大,且粘粒对其影响较大。不同粒径泥沙(OM)、Fe、Al、Ca和Mn含量之间存在极显著正相关关系(P<0.01),且均对单位质量泥沙最大吸附量(Xm)和饱和吸附量(Cse)具有正效应,其中Al含量对该参数的影响更为显著。这说明泥沙对磷的吸附行为可能受到粒径和化学成分的共同影响。     

浅论环境影响评价在油田环境管理中的作用

新疆地区的环境较为敏感,油气田开发对环境的影响较大,围绕着油气田开发所开展的各项活动必须严格执行环境影响评价。文章介绍油气田开发环境影响特点,环境影响评价工作中存在的问题。加强油田环境管理的措施为:实施战略和区域环境影响评价,在可行性研究报告审查前提出环境保护建议,在设计阶段严格执行环评中提出的环境保护措施,严格执行HSE环境管理体系,建立和完善回顾性环境影响评价制度,制定新疆油田建设项目环境保护管理方面的规定。     

Determination of antibiotics in sewage from hospitals, nursery and slaughter house, wastewater treatment plant and source water in Chongqing region of Three Gorge Reservoir in China

Sewage samples from 4 hospitals, 1 nursery, 1 slaughter house, 1 wastewater treatment plant and 5 source water samples of Chongqing region of Three Gorge Reservoir were analyzed for macrolide, lincosamide, trimethoprim, fluorouinolone, sulfonamide and tetracycline antibiotics by online solid-phase extraction and liquid chromatography-tandem mass spectrometry. Results showed that the concentration of ofloxacin (OFX) in hospital was the highest among all water environments ranged from 1.660 μg/L to 4.240 μg/L and norfloxacin (NOR, 0.136-1.620 μg/L), ciproflaxacin (CIP, ranged from 0.011 μg/L to 0.136 μg/L), trimethoprim (TMP, 0.061-0.174 μg/L) were commonly detected. Removal range of antibiotics in the wastewater treatment plant was 18-100% and the removal ratio of tylosin, oxytetracycline and tetracycline were 100%. Relatively higher removal efficiencies were observed for tylosin (TYL), oxytetracycline (OXY) and tetracycline (TET)(100%), while lower removal efficiencies were observed for Trimethoprim (TMP, 1%), Epi-iso-chlorotetracycline (EICIC, 18%) and Erythromycin-H₂O (ERY-H₂O, 24%). Antibiotics were removed more efficiently in primary treatment compared with those in secondary treatment.     

超疏水沸石咪唑酯骨架材料ZIF-90的制备及其气体吸附性能

以自制沸石咪唑酯骨架材料ZIF-90为原料,自制2,3,4,5,6-五氟苄胺为修饰剂,通过后修饰法制备了超疏水ZIF-90,采用SEM、XRD、FTIR等技术对其进行了表征,并进行了气体吸附性能测试。表征结果显示:制备的超疏水ZIF-90晶体结构和形貌良好;水接触角高达152.1°;修饰剂分子与ZIF-90晶体上的自由醛基成功发生缩胺反应。气体吸附实验结果表明:当相对压力小于0.02时,超疏水ZIF-90的CO_2吸附量较ZIF-90明显增大,CO_2/N_2和CO_2/CH_4的理想吸附选择系数由修饰前的15.76和4.88分别提升至33.28和17.13;超疏水ZIF-90具有优异的憎水性能。     

膜吸收法净化低浓度甲醛和氨气简

基于膜吸收技术自制双层平板式膜吸收器，搭建净化低浓度甲醛和氨气污染模拟系统，考察不同膜结构参数、进气流量、吸收剂流量等因素对其净化效果的影响。结果表明，聚偏氟乙烯PVDF对低浓度甲醛和氨气的净化效率高于聚四氟乙烯PTFE。对同一材质膜，随着膜孔隙率的增大，甲醛和氨气的净化率呈上升趋势。随着进气流量的增加，甲醛和氨气的净化效率降低；而吸收剂流量对其净化效率影响不大。对于所有实验条件，平均膜孔径为0.22 μm的PVDF 4^#在进气流量u_g=120 L/h时，甲醛和氨气的净化效率最高，分别达94.7%和96.3%。     

稀有鮈鲫作为水生模式生物的研究及探讨

我国本土水生生物稀有鮈鲫(Gobiocypris rarus Ye et Fu,1983年)是一种优良的试验用鱼，具备成为模式生物必要条件。本文总结了稀有鮈鲫生物生态学研究情况，分析了稀有鮈鲫在多个应用领域与模式生物斑马鱼、青鳉存在的不足和差距，同时借鉴发达国家推动模式生物的实践经验，提出了针对性建议。     

Development Potentials and Policy Options of Biomass in China

Biomass, one of the most important renewable energies, is playing and will continue to play an important role in the future energy structure of the world. This article aims to analyze the position and role, assess the resource availability, discuss the geographic distribution, market scale and industry development, and present the policy options of biomass in China. The resource availability and geographical distribution of biomass byproducts are assessed in terms of crop residues, manure, forest and wood biomass byproducts, municipal waste and wastewater. The position of biomass use for power generation is just next to hydropower among types of renewable energy in China. The potential quantity of all biomass byproducts energy in 2004 is 3511 Mtce (Mtce is the abbreviation of million tons of coal equivalents and 1 Mtce is equal to10⁶ tce.), while the acquirable quantity is 460 Mtce. Biomass energy plays a critical role in rural regions of China. The geographical distribution and quantity of biomass byproducts resources depends mainly on the relationship between ecological zones and climate conditions. Our estimation shows that the total quantity of crop residues, manure, forest and wood biomass byproducts, municipal waste and wastewater resources are 728, 3926, 2175, 155 and 48240 Mt (million tons), respectively. Crop residues come mainly from the provinces of Henan, Shandong, Heilongjiang, Jilin and Sichuan. All manure is mainly located in the provinces of Henan, Shandong, Sichuan, Hebei and Hunan. Forest and wood biomass byproducts are mainly produced in the provinces or autonomous regions of Tibet, Sichuan, Yunnan, Heilongjiang and Inner Mongolia, while most of municipal waste mainly comes from Guangdong, Shandong, Heilongjiang, Hubei and Jiangsu. Most of wastewater is largely discharged from advanced provinces like Guangdong, Jiangsu, Zhejiang, Shandong and Henan. Biomass byproducts’ energy distribution also varies from province to province in China. Based on the analysis of the market scale and industry development, the article argues that China’s biomass energy industry is still at a very early stage of development and that Feed-in Tariffs (FIT) might be the best policy option for China to promote its development of biomass energy. A successful enforcement of FIT in China needs some policy combination of special capital subsidies, R&D funding, tax incentives and pricing.