An investigation of engine and fuel system performance in a diesel engine operating on waste cooking oil

Waste cooking oil (WCO) was experimentally examined to determine whether it can be used as an alternative fuel in a 3-cylinder, 4-stroke, direct injection, 48 kW power tractor engine. The test engine was operated under full load conditions using diesel fuel and waste vegetable oil from the 2400 to 1100 rpm and performance values were recorded. Tests were performed in two stages to evaluate the effect of the waste oils on the engine life cycle. When the test engine was operated with diesel fuel and waste cooking oil; engine torque decreased between at ratio of 0.09 % and 3% according to the engine speed. While no significant difference occurs in the diesel fuel tests at the end of 100 hours of operation, an important reduction was observed in the engine torque of the WCO engine between 4.21% and 14.48% according to the engine speed, and an increase in average smoke opacity ratio was also observed. In accordance with the results obtained from the studies, it was determined that the engine performance values of waste cooking oil show similar properties with diesel fuel, but in long-term usage, performance losses increased. In the SEM analysis performed on the fuel system, there were dark deposits at the nozzle tip and stem. According to an EDX analysis at the nozzle tips, the detected elements point to engine oil ash in the combustion chamber and show coking products (C and O). The other elements (Na, S, Ca, P, Cl, and K) point to used WCO.     

The Sustainability of Subsistence Hunting in the Neotropics

Hunting is an important component of native subsistence strategies in Amazonia. It is also a serious threat to biodiversity in some areas. We present data on the faunal harvests of two native Neotropical subsistence hunting peoples, Machiguenga bow-hunters and Piro shotgun hunters of Peru. The rate of annual harvest per square kilometer of catchment is estimated and compared to rates of sustainable harvest calculated by Robinson and Redford (1991). We used indicators of prey abundance to test for the depletion of species that hunters killed in numbers greater than what the model predicts to be sustainable. As predicted, we found the strongest evidence for local depletion of the large primates at the Piro site. The woolly monkey ( Lagothrix lagothricha) harvest at the Machiguenga village and the deer ( Mazama americana) and collared peccary (Tayassu tajacu) harvests at both sites were not predicted to be unsustainable and we found no evidence for depletion. Machiguenga bow hunters killed spider monkeys (Ateles paniscus) in quantities that were slightly above what the model predicted to be sustainable, yet we found no evidence for depletion. Differential species vulnerability, catchment size, and consumer population size could be important factors in determining sustainability.     

Linking river, floodplain, and vadose zone hydrology to improve restoration of a coastal river affected by saltwater intrusion

Floodplain forests provide unique ecological structure and function, which are often degraded or lost when watershed hydrology is modified. Restoration of damaged ecosystems requires an understanding of surface water, groundwater, and vadose (unsaturated) zone hydrology in the floodplain. Soil moisture and porewater salinity are of particular importance for seed germination and seedling survival in systems affected by saltwater intrusion but are difficult to monitor and often overlooked. This study contributes to the understanding of floodplain hydrology in one of the last bald cypress [Taxodium distichum (L.) Rich.] floodplain swamps in southeast Florida. We investigated soil moisture and porewater salinity dynamics in the floodplain of the Loxahatchee River, where reduced freshwater flow has led to saltwater intrusion and a transition to salt-tolerant, mangrove-dominated communities. Twenty-four dielectric probes measuring soil moisture and porewater salinity every 30 min were installed along two transects-one in an upstream, freshwater location and one in a downstream tidal area. Complemented by surface water, groundwater, and meteorological data, these unique 4-yr datasets quantified the spatial variability and temporal dynamics of vadose zone hydrology. Results showed that soil moisture can be closely predicted based on river stage and topographic elevation (overall Nash-Sutcliffe coefficient of efficiency = 0.83). Porewater salinity rarely exceeded tolerance thresholds (0.3125 S m(-1)) for bald cypress upstream but did so in some downstream areas. This provided an explanation for observed vegetation changes that both surface water and groundwater salinity failed to explain. The results offer a methodological and analytical framework for floodplain monitoring in locations where restoration success depends on vadose zone hydrology and provide relationships for evaluating proposed restoration and management scenarios for the Loxahatchee River.     

Organic Compounds in Urban Atmospheres: A Review of Distribution,Collection and Analysis

An attempt has been made to summarize the present state of knowledge concerning the occurrence, sampling, and analytical procedures for organic components in the atmosphere. This review places special emphasis on classification strategy and draws attention to classes of compounds which may be potentially toxic. Methods currently used for collection and analyses are briefly described and evaluated.     

Assessment of relative accuracy in the determination of organic matter concentrations in aquatic systems

Accurate determinations of total (TOC), dissolved (DOC) and particulate (POC) organic carbon concentrations are critical for understanding the geochemical, environmental, and ecological roles of aquatic organic matter. Of particular significance for the drinking water industry, TOC measurements are the basis for compliance with US EPA regulations. The results of an interlaboratory comparison designed to identify problems associated with the determination of organic matter concentrations in drinking water supplies are presented. The study involved 31 laboratories and a variety of commercially available analytical instruments. All participating laboratories performed well on samples of potassium hydrogen phthalate (KHP), a compound commonly used as a standard in carbon analysis. However, problems associated with the oxidation of difficult to oxidize compounds, such as dodecylbenzene sulfonic acid and caffeine, were noted. Humic substances posed fewer problems for analysts. Particulate organic matter (POM) in the form of polystyrene beads, freeze-dried bacteria and pulverized leaf material were the most difficult for all analysts, with a wide range of performances reported. The POM results indicate that the methods surveyed in this study are inappropriate for the accurate determination of POC and TOC concentration. Finally, several analysts had difficulty in efficiently separating inorganic carbon from KHP solutions, thereby biasing DOC results.     

Monitoring dissolved organic carbon in surface and drinking waters

The presence of natural organic matter (NOM) strongly impacts drinking water treatment, water quality, and water behavior during distribution. Dissolved organic carbon (DOC) concentrations were determined daily over a 22 month period in river water before and after conventional drinking water treatment using an on-line total organic carbon (TOC) analyzer. Quantitative and qualitative variations in organic matter were related to precipitation and runoff, seasons and operating conditions. Following a rainfall event, DOC levels could increase by 3.5 fold over baseflow concentrations, while color, UV absorbance values and turbidity increased by a factor of 8, 12 and 300, respectively. Treated water DOC levels were closely related to the source water quality, with an average organic matter removal of 42% after treatment.     

Assessment of different carbon and salinity level on growth kinetics,lipid, and starch composition of Chlorella vulgaris SAG 211-12

ABSTRACT

The quality of microalgal biofuel depends on the fatty acid (FA) distribution. A high ratio of saturated fatty acids (SFAs) favors better biofuel characteristics. Palmitic acid (C16:0) and stearic acid (C18:0) are essential FAs for required biodiesel quality. In this study, combined effects of growth medium concentrations of NaCl, glucose and glycerol on cell composition and FA profile of the Chlorella vulgaris SAG 211–12 were investigated. A central composite design (CCD) based design of experiments (DoE) was used for experimental setup. According to experimental results, the maximum mass fraction for palmitic acid (C16:0), 40.67% of total fatty acids, was obtained in the medium supplemented with 0.9% (w/v) NaCl, 0.3% (w/v) glucose, and 0.3% (w/v) glycerol, whereas stearic acid (C18:0) percentage reached the highest value of 22.16% of total fatty acids in the presence of 2.5% NaCl, 0.6% glucose, and 0.6% glycerol. According to the same set of designed experiments, best starch content was found as 22.08% of dry cell weight in a medium containing 2.0% NaCl, 0.3% glucose, and 0.3% glycerol. C16:0 mass fraction as a function of three medium ingredient concentrations was modeled using a Kriging model. Optimum concentrations of NaCl, glucose and glycerol to reach maximum C16:0 fraction were predicted as 0.5, 1, and 1%, respectively.     

Patterns of substance use among Hurricane Katrina evacuees in Houston,Texas

This paper focuses on changing patterns of substance use among low income, African American drug users evacuated from New Orleans, Louisiana, during Hurricane Katrina of August 2005. It examines the relationship between increases and decreases in alcohol and tobacco (AT) use and illicit drug (ID) use after Katrina and pre‐disaster and within‐disaster factors. Data from structured interviews with 200 Katrina evacuees currently living in Houston were collected 8–14 months after the disaster. Multivariate analysis revealed that rises in AT use were positively associated with education. Females and younger evacuees were more likely to have increased AT use. ID use increase was positively associated with resource loss and leaving the city before Katrina. Decreases in AT and ID use were found to be associated with disaster‐related exposure. The paper discusses the specific consequences of disasters on disadvantaged minority substance users and the importance of developing public health disaster policies that target this population.