Algal biomass valorization for biofuel production and carbon sequestration: a review

The world is experiencing an energy crisis and environmental issues due to the depletion of fossil fuels and the continuous increase in carbon dioxide concentrations. Microalgal biofuels are produced using sunlight, water, and simple salt minerals. Their high growth rate, photosynthesis, and carbon dioxide sequestration capacity make them one of the most important biorefinery platforms. Furthermore, microalgae's ability to alter their metabolism in response to environmental stresses to produce relatively high levels of high-value compounds makes them a promising alternative to fossil fuels. As a result, microalgae can significantly contribute to long-term solutions to critical global issues such as the energy crisis and climate change. The environmental benefits of algal biofuel have been demonstrated by significant reductions in carbon dioxide, nitrogen oxide, and sulfur oxide emissions. Microalgae-derived biomass has the potential to generate a wide range of commercially important high-value compounds, novel materials, and feedstock for a variety of industries, including cosmetics, food, and feed. This review evaluates the potential of using microalgal biomass to produce a variety of bioenergy carriers, including biodiesel from stored lipids, alcohols from reserved carbohydrate fermentation, and hydrogen, syngas, methane, biochar and bio-oils via anaerobic digestion, pyrolysis, and gasification. Furthermore, the potential use of microalgal biomass in carbon sequestration routes as an atmospheric carbon removal approach is being evaluated. The cost of algal biofuel production is primarily determined by culturing (77%), harvesting (12%), and lipid extraction (7.9%). As a result, the choice of microalgal species and cultivation mode (autotrophic, heterotrophic, and mixotrophic) are important factors in controlling biomass and bioenergy production, as well as fuel properties. The simultaneous production of microalgal biomass in agricultural, municipal, or industrial wastewater is a low-cost option that could significantly reduce economic and environmental costs while also providing a valuable remediation service. Microalgae have also been proposed as a viable candidate for carbon dioxide capture from the atmosphere or an industrial point source. Microalgae can sequester 1.3 kg of carbon dioxide to produce 1 kg of biomass. Using potent microalgal strains in efficient design bioreactors for carbon dioxide sequestration is thus a challenge. Microalgae can theoretically use up to 9% of light energy to capture and convert 513 tons of carbon dioxide into 280 tons of dry biomass per hectare per year in open and closed cultures. Using an integrated microalgal bio-refinery to recover high-value-added products could reduce waste and create efficient biomass processing into bioenergy. To design an efficient atmospheric carbon removal system, algal biomass cultivation should be coupled with thermochemical technologies, such as pyrolysis.

     

Methanol fuel production,utilization, and techno-economy: a review

Environmental Chemistry Letters - Climate change and the unsustainability of fossil fuels are calling for cleaner energies such as methanol as a fuel. Methanol is one of the simplest molecules for...     

Immune responses,DNA damage and ultrastructural alterations of gills in the marine mussel Lithophaga lithophaga exposed to CuO nanoparticles

Environmental Science and Pollution Research - Nanoparticle (NP) pollution is a worldwide problem. Copper oxide nanoparticles (CuO NPs) are one of the most used NPs in a variety of applications,...     

Experimental study on fresh,mechanical properties and embodied carbon of concrete blended with sugarcane bagasse ash,metakaolin, and millet husk ash as ternary cementitious material

Environmental Science and Pollution Research - In recent years, the research direction is shifted toward introducing new supplementary cementitious materials (SCM) in lieu of in place of Portland...     

Effect of alkalinity on the performance of a simulated landfill bioreactor digesting organic solid wastes

This study investigated the effects of alkalinity on the anaerobic treatment of the organic solid wastes collected from the kitchen of Engineering Faculty in Dokuz Eylul University, Izmir, Turkey and the leachate characteristics treated in three simulated landfill anaerobic bioreactors. All of the reactors were operated with leachate recirculation. One reactor was operated without alkalinity addition. The second reactor was operated by the addition of 3 g l-1 d-1 of NaHCO3 alkalinity to the leachate and the third reactor was operated by the addition of 6 g l-1 d-1 NaHCO3 alkalinity to the leachate. After 65 d of anaerobic incubation, it was observed that the chemical oxygen demand (COD), volatile fatty acids (VFA) concentrations, and biochemical oxygen demand to chemical oxygen demand (BOD5/COD) ratios in the leachate samples produced from the alkalinity added reactors were lower than the control reactor while the pH values were higher than the control reactor. The COD values were measured as 18900, 3800 and 2900 mg l-1 while the VFA concentrations were 6900, 1400 and 1290 mg l-1, respectively, in the leachate samples of the control, and reactors containing 3 g l-1 NaHCO3 and 6 g l-1 NaHCO3 after 65 d of anaerobic incubation. The total nitrogen (TN), total phosphorus (TP) and ammonium nitrogen (NH4-N) concentrations in organic solid waste (OSW) significantly reduced in the reactor containing 6 g l-1 NaHCO3 by d 65. The values of pH were 6.54, 7.19 and 7.31, after 65 d of anaerobic incubation, respectively, in the aforementioned reactors results in neutral environmental conditions in alkalinity added reactors. Methane percentage of the control, reactors containing 3 g l-1 NaHCO3 and 6 g l-1 NaHCO3 were 37%, 64% and 65%, respectively, after 65 d of incubation. BOD5/COD ratios of 0.27 and 0.25 were achieved in the 3 and 6 g l-1 NaHCO3 containing reactors, indicating a better OSW stabilization. Alkalinity addition reduced the waste quantity, the organic content of the solid waste and the biodegradation time.     

Comparison of old and new municipal solid waste management systems in Denizli, Turkey

Rapid economic growth, increasing population and change in living standards contribute to increasing the generation rate of municipal solid waste (MSW) in Denizli city, like other Turkish cities. The improper and poor MSW management system (old system) in Denizli caused environmental problems originating from the uncontrolled release of methane and leachate. In addition, the disposal of recyclable materials in unsanitary landfills is responsible for the consumption and destruction of natural sources. This paper presents a general overview of old and new MSW management practices in Denizli. Detailed data on MSW management practices including collection, transportation, disposal and recycling have been presented. The amount of solid waste generated in Denizli over the last decade has increased steadily over the years, from 108,500 tons in 1995 to 179,495 tons in 2006. The average MSW generation rate was found to be 1.23kg/day per capita. The major constituent of MSW in Denizli is food waste, but the percentage of recyclable waste has increased significantly recently. Except for metal wastes, the percentages of recyclable waste materials in Denizli are higher than in all neighborhood cities. The objective of this study is to compare the old and new MSW management systems in Denizli city. The MSW management system has been changed entirely last five years. A dumpsite was closed and a sanitary landfill with a composting facility was constructed. In addition, source separated collection has been carried out since 2002. The quantity of recyclable waste collected increased from 195 to 1549 tons. The amount of recyclable waste will continue to be increased by expanding the source separation collection system to all the districts of the city and preventing scavenging. Thus, revenue from recyclable waste ($7227 in 2006) is expected to increase. In addition, the capacity of the composting facility will be increased. Most importantly, information to increase public participation and awareness in municipal recovery programs has to be provided.     

Rice straw for energy and value-added products in China: a review

Environmental Chemistry Letters - The rise of global waste and the decline of fossil fuels are calling for recycling waste into energy and materials. For example, rice straw, a by-product of rice...     

Biochemical properties of some Salvia L. species

Antioxidant capacity, total phenol and mineral contents of aerial parts of sage belonging to some Salvia species were established. The lowest and highest antioxidant values of Salvia dichroantha Stapf and Salvia heldreichiana Boiss. ex Benth. extracts were found as 73.855 and 80.207 mg GAE/g, respectively. While the highest total phenol was established in Salvia tomentosa Mil. (13.316 mg GAE/100 ml), the lowest level was found in Salvia halophila Hedge (6.168 mg GAE/100 ml). While K contents of plants changed between 14,518 and 24,171 mg/kg, Ca contents ranged between 12,402 and 18,553 mg/kg. P and Mg contents were found low compared with K and P values of plants. Mg content was changed between 2,118 and 2,914 mg/kg; the mean was calculated as 2,496 mg/kg. P contents of plants were determined between 1,385 to 1,910 mg/kg. As a microelement, Fe was found at the highest level. Fe contents of plants were found between 179 and 782 mg/kg.     

The value of indigenous knowledge in climate change mitigation and adaptation strategies in the African Sahel

Past global efforts at dealing with the problem of global warming concentrated on mitigation, with the aim of reducing and possibly stabilizing greenhouse gas (GHG) concentrations in the atmosphere. With the slow progress in achieving this, adaptation was viewed as a viable option to reduce the vulnerability to the anticipated negative impacts of global warming. It is increasingly realized that mitigation and adaptation should not be pursued independent of each other but as complements. This has resulted in the recent calls for the integration of adaptation into mitigation strategies. However, integrating mitigation and adaptation into climate change concerns is not a completely new idea in the African Sahel. The region is characterized by severe and frequent droughts with records dating back into centuries. The local populations in this region, through their indigenous knowledge systems, have developed and implemented extensive mitigation and adaptation strategies that have enabled them reduce their vulnerability to past climate variability and change, which exceed those predicted by models of future climate change. However, this knowledge is rarely taken into consideration in the design and implementation of modern mitigation and adaptation strategies. This paper highlights some indigenous mitigation and adaptation strategies that have been practiced in the Sahel, and the benefits of integrating indigenous knowledge into formal climate change mitigation and adaptation strategies. Incorporating indigenous knowledge can add value to the development of sustainable climate change mitigation and adaptation strategies that are rich in local content, and planned in conjunction with local people.