Assessment of physicochemical parameters and metal distribution in bog peat of the western segment of the North European part of Russia (Arkhangelsk region)

This article is devoted to the study of physicochemical parameters and the assessment of the accumulation and distribution of metals in peat deposits from the North European part of Russia (Arkhangelsk region). Peat profiles were selected both in the area with a high anthropogenic load and in a bog remote from industrial pollution. The determination of metals was carried out by using the methods X-ray fluorescence analysis and atomic absorption spectroscopy. It was determined that the studied bogs can be attributed to the low ash type, and the recorded pH and mineralisation values make it possible to attribute these deposits to the acid-oxidising facies of oligotrophic peatlands, characteristic of taiga landscapes. Assessment of metal accumulation showed a high content of titanium, chromium, lead, nickel, vanadium, cobalt, aluminium, silicon, and copper in peat, mainly caused by the burning of fossil fuels and industrial production, as well as the burning of urban and industrial waste. The peat profiles are characterised by significant fluctuations in the content of elements in different horizons. Studies have shown the need to monitor the content of metals in peatlands from the Arkhangelsk region to assess atmospheric pollution from industrial emissions, both at the moment and in the past.

     

Thiourea leaching of gold from processed municipal solid waste incineration residues

Incineration is one of the key technologies in disposal of municipal waste, which produces municipal solid waste incineration (MSWI) residues with high valuable metal contents. The recycling strategy for the MSWI residues is typically focused on the recovery of scrap metals yielding processed municipal solid waste incineration residues (PIR) as the main byproduct. However, the PIR still contains valuable metals, particularly gold, which cannot be extracted by conventional methods. Here, we evaluated the feasibility of using the 0.5–2.0 mm grain size fraction of PIR containing 28.82 ± 1.62 mg/kg of gold as raw material for a two-stage extraction process. In the first stage the alkalic fine-grained PIR was acidified with a solution of 20% (v/v) of HCl-containing flue gas cleaning liquid that is obtained by the municipal waste incineration plant itself as a waste product. In the second stage we leached the acidified fine-grained PIR by thiourea with Fe³⁺ as an oxidant. Application of the thiourea-Fe³⁺ leaching system resulted in recovery of 16.4 ± 1.56 mg/kg of gold from the fine-grained PIR within 6 h of incubation. Due to high gold market prices, upscaling of the suggested technology can represent a suitable strategy for gold recovery from PIR and other MSWI residues.

     

Intelligent Databases Assist Transparent and Sound Economic Valuation of Ecosystem Services

Assessment and economic valuation of services provided by ecosystems to humans has become a crucial phase in environmental management and policy-making. As primary valuation studies are out of the reach of many institutions, secondary valuation or benefit transfer, where the results of previous studies are transferred to the geographical, environmental, social, and economic context of interest, is becoming increasingly common. This has brought to light the importance of environmental valuation databases, which provide reliable valuation data to inform secondary valuation with enough detail to enable the transfer of values across contexts. This paper describes the role of next-generation, intelligent databases (IDBs) in assisting the activity of valuation. Such databases employ artificial intelligence to inform the transfer of values across contexts, enforcing comparability of values and allowing users to generate custom valuation portfolios that synthesize previous studies and provide aggregated value estimates to use as a base for secondary valuation. After a general introduction, we introduce the Ecosystem Services Database, the first IDB for environmental valuation to be made available to the public, describe its functionalities and the lessons learned from its usage, and outline the remaining needs and expected future developments in the field.     

Pesticide exposure and lung cancer mortality in Leningrad province in Russia

This study was carried out to examine the association between pesticide exposure and lung cancer mortality. We conducted an autopsy based case-control study in Leningrad Province in Russia. A total of 540 lung cancer cases and 582 controls were identified among subjects who had died in the hospitals of the Leningrad province between 1993 and 1998. Using work history records, we assessed exposure to pesticide at the level of industry and job title. Unconditional logistic regression was used to calculate adjusted odds ratio for pesticide exposure and lung cancer mortality. There was no association between ever exposure to pesticide and lung cancer mortality overall (odds ratio=1.06, 95% confidence interval=0.82-1.36) and in both men (odds ratio=1.11, 95% confidence interval=0.84-1.46) and women (odds ratio=0.74, 95% confidence interval=0.37-1.46). We observed no statistically significant odds ratio by duration of pesticide exposure, intensity of pesticide exposure, and cumulative pesticide exposures with lung cancer mortality in both smokers and nonsmokers. Odds ratio also did not differ when the analysis was restricted to individuals who had exposure data with high confidence scores. Our findings suggest no associations between pesticide exposures and mortality of lung cancer in the population of the Leningrad province in Russia that deserves further evaluation.     

Status and trends of circumpolar peregrine falcon and gyrfalcon populations

Ambio - The peregrine falcon (Falco peregrinus) and the gyrfalcon (Falco rusticolus) are top avian predators of Arctic ecosystems. Although existing monitoring efforts are well established for both...     

Biodegradation of Poly-ε-caprolactones and Poly-<Emphasis Type="SmallCaps">l</Emphasis>-lactides by Fungi

This work assessed biodegradation, by Aspergillus, Fusarium, Penicillium and Parengyodontium fungi, of four samples of poly-ε-caprolactone (PCL), three samples of poly-l-lactide (PLA) and one sample of poly-d,l-lactide (DL-PLA) produced by ring-opening polymerization initiated by aluminium complexes of corresponding lactones. Mesophilic fungal strains actively biodegrading PCL (F. solani) and PLA (Parengyodontium album and A. calidoustus) were selected. The rate of degradation by the selected fungi was found to depend on the physicochemical and mechanical properties of the polymers (molecular weight, polydispersity, crystallinity). The most degradable poly-ε-caprolactone sample was shown to have the lowest molecular weight; the most biodegradable polylactide DL-PLA had the lowest crystallinity. Mass spectral analysis of biodegraded polymer residues showed PCL to be degraded more intensively than PLA. It is established that in the case of Parengyodontium album the colonization of the films of polypropylene composites with DL-PLA is observed, which will undoubtedly contribute to their further destruction under the influence of abiotic factors in the environment.     

Patterns of soil contamination,erosion and river loading of metals in a gold mining region of northern Mongolia

Mining has become one of the main causes of increased heavy metal loading of river systems throughout the world. There is however an evident gap between assessments of soil contamination and metal release at the mined sites and estimates of river pollution. The present work focuses on Zaamar Goldfield, which is one of the largest placer gold mines in the world, located along the Tuul River, Mongolia, which ultimately drains into Lake Baikal, Russia. It combines field observations in the river basin with soil erosion modelling and aims at quantifying the contribution from natural erosion of metal-rich soil to observed increases in mass flows of metals along the Tuul River. Results show that the sediment delivery from the mining area to the Tuul River is considerably higher than the possible contribution from natural soil erosion. This is primarily due to excessive mining-related water use creating turbid wastewaters, disturbed filtering functions of deposition areas (natural sediment traps) close to the river and disturbances from infrastructures such as roads. Furthermore, relative to background levels, soils within Zaamar Goldfield contained elevated concentrations of As, Sr, Mn,V, Ni, Cu and Cr. The enhanced soil loss caused by mining-related activities can also explain observed, considerable increases in mass flows of metals in the Tuul River. The present example from Tuul River may provide useful new insights regarding the erosion and geomorphic evolution of mined areas, as well as the associated delivery of metals into stream networks.

     

The Selenga River delta: a geochemical barrier protecting Lake Baikal waters

Regional Environmental Change - The protection of Lake Baikal and the planning of water management measures in the Selenga River Basin require a comprehensive understanding of the current state and...     

A small change in the design of a slit bioaerosol impactor significantly improves its collection characteristics

While several methods are available for bioaerosol monitoring, impaction remains the most common one, particularly for collecting fungal spores. Earlier studies have shown that the collection efficiency of many conventional single-stage bioaerosol impactors falls below 50% for spores with an aerodynamic diameter between 1.7 and 2.5 microm because their cut-off size is 2.5 microm or greater. The cut-off size reduction is primarily done by substantially increasing the sampling flow rate or decreasing the impaction jet size, W, to a fraction of a millimetre, with both measures often impractical to implement. Some success has recently been reported on the utilization of an ultra-low jet-to-plate distance, S (S/W < 0.1), in circular impactors. This paper describes a laboratory evaluation and some field testing of two single-stage, single-nozzle, slit bioaerosol impactors, Allergenco-D and Air-O-Cell, which feature the same jet dimensions and flow rate but have some design configuration differences that were initially thought to be of low significance. The collection efficiency and the spore deposit characteristics were determined in the laboratory using real-time aerosol spectrometry and different microscopic enumeration methods as the test impactors were challenged with the non-biological polydisperse NaCl aerosol and the aerosolized fungal spores of Cladosporium cladosporioides, Aspergillus versicolor, and Penicillium melinii. The tests showed that a relatively small reduction in the jet-to-plate distance of a single-stage, single-nozzle impactor with a tapered inlet nozzle, combined with adding a straight section of sufficient length, can significantly decrease the cut-off size to the level that is sufficient to efficiently collect spores of all fungal species. Furthermore, it appears that the slit jet design may improve the application of partial spore counting methodologies with respect to those applied to circular deposits. Data from a demonstration field study, conducted with the two samplers in environments containing a variety of fungal species, supported the laboratory findings.