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81.
Removal of phosphate by Fe-coordinated amino-functionalized 3D mesoporous
silicates hybrid materials
Phosphate removal from aqueous waste streams is an important approach to control the eutrophication downstream bodies of water.
A Fe(III) coordinated amino-functionalized silicate adsorbent for phosphate adsorption was synthesized by a post-grafting and metal
cation incorporation process. The surface structure of the adsorbent was characterized by X-ray di raction, N2 adsoropion/desoprotion
technique, and Fourier transform infrared spectroscopy. The experimental results showed that the adsorption equilibrium data were well
fitted to the Langmuir equation. The maximum adsorption capacity of the modified silicate material was 51.8 mg/g. The kinetic data
from the adsorption of phosphate were fitted to pseudo second-order model. The phosphate adsorption was highly pH dependent and
the relatively high removal of phosphate fell within the pH range 3.0–6.0. The coexistence of other anions in solutions has an adverse
e ect on phosphate adsorption; a decrease in adsorption capacity followed the order of exogenous anions: F?? > SO2?? 4 > NO??3 > Cl??. In
addition, the adsorbed phosphate could be desorbed by NaOH solutions. This silicate adsorbent with a large adsorption capacity and
relatively high selectivity could be utilized for the removal of phosphate from aqueous waste streams or in aquatic environment. 相似文献
82.
The toxicity of naphthalene to a freshwater microalga, Chlorella pyrenoidosa, and the subsequent recovery of algae from the damage
were investigated under two nutrient conditions, either enriched with nitrogen (N) and phosphorus (P), or starved of N and P. Results
showed that C. pyrenoidosa was more sensitive to naphthalene under N,P-enriched condition, and the inhibitory rate generally increased
at first and then decreased gradually with the evaporation of naphthalene under both nutrient conditions. Enriched N, P reduced the
inhibitory rate at initial naphthalene concentration of 5 and 10 mg/L, but enhanced it at 100 mg/L, at which more severe ultrastructure
damages were found than those under N,P-starved condition. Observed damages included partly or totally disappearance of nucleolus,
nuclear, and plasma membranes. According to the chlorophyll content and cell density measurements, C. pyrenoidosa could recover
from naphthalene damage with initial concentrations 6 50 mg/L in 7 days under both nutrient conditions, while they could not recover
if the initial concentration of naphthalene was at 100 mg/L. Under the N,P-starved condition, the inability of C. pyrenoidosa to recover
from the naphthalene damage was consistent with the results of high inhibitory rate, low value of specific growth rate (SGR, 0.05
day??1), and the severe destruction of cell structure. However, under the N,P-enriched conditions, the observed lower inhibitory rate,
higher value of SGR (0.55 day??1), and the intact cell structure of most cells suggested that algae could potentially recover from the
naphthalene damage. 相似文献
83.
Long-term joint effect of nutrients and temperature increase on algal growth in Lake Taihu, China 总被引:1,自引:0,他引:1
To study how global warming and eutrophication affect water ecosystems, a multiplicative growth Monod model, modified by incorporating the Arrhenius equation, was applied to Lake Taihu to quantitatively study the relationships between algal biomass and both nutrients and temperature using long-term data. To qualitatively assess which factor was a limitation of the improved model, temperature variables were calculated using annual mean air temperature (AT), water temperature (WT), and their average temperature (ST), while substrate variables were calculated using annual mean total nitrogen (TN), total phosphorus (TP), and their weighted aggregate (R), respectively. The nine fitted curves showed that TN and AT were two important factors influencing algal growth; AT limited growth as algal photosynthesis is mainly carried out near the water surface; N leakage of phytoplankton and internal phosphorus load from sediment explains why TN was the best predictor of peak biomass using the Monod model. The fitted results suggest that annual mean algal biomass increased by 0.145 times when annual mean AT increased by 1.0℃. Results also showed that the more eutrophic the lake, the greater the effect AT had on algal growth. Subsequently, the long-term joint effect of annual temperature increase and eutrophication to water ecosystems can be quantitatively assessed and predicted. 相似文献
84.
By using optical microscope, the microstructures of 5083/6082 friction stir welding (FSW) weld and parent materials were analyzed. Meanwhile, at ambient temperature and in 0.2 mol/L NaHS03 and 0.6 mol/L NaCl solutionby gravimetric test, potentiodynamic polarization curve test, electrochemical impedance spectra (EIS) and scanning electron microscope (SEM) observation, the electrochemical behavior of 5083/6082 friction stir welding weld and parent materials were comparatively investigated by gravimetric test, potentiodynamic polarization curve test, electrochemical impedance spectra (EIS) and scanning electron microscope (SEM) observation. The results indicated that at given processing parameters, the anti-corrosion property of the dissimilar weld was superior to those of the 5083 and 6082 parent materials. 相似文献
85.
土著微生物修复城市小型湖泊实验研究 总被引:1,自引:0,他引:1
利用生物制剂及生物修复技术对鞍山市英泽湖进行了净化治理.研究结果表明,经过8~30 d的生物净化,该湖水中的COD、植物营养元素浓度及浊度都有了大幅度的下降.其中COD降至20 mg/L以下,去除率达到70%以上;氨氮降至0.2 mg/L以下,去除率达97%;总磷降低至0.02 mg/L以下,去除率达到60%以上;浊度... 相似文献
86.
87.
88.
89.
Qiushi Shen Qilin Zhou Jingge Shang Shiguang Shao Lei Zhang Chengxin Fan 《环境科学学报(英文版)》2014,26(2):281-288
Organic matter-induced black blooms(hypoxia and an offensive odor) are a serious ecosystem disasters that have occurred in some large eutrophic shallow lakes in China. In this study, we investigated two separate black blooms that were induced by Potamogeton crispus in Lake Taihu, China. The main physical and chemical characteristics, including color- and odor-related substances, of the black blooms were analyzed. The black blooms were characterized by low dissolved oxygen concentration(close to 0 mg/L), low oxidation-reduction potential, and relatively low pH of overlying water. Notably higher Fe2+and∑S2-were found in the black-bloom waters than in waters not affected by black blooms. The black color of the water may be attributable to the high concentration of these elements, as black FeS was considered to be the main substance causing the black color of blooms in freshwater lakes. Volatile organic sulfur compounds, including dimethyl sulfide, dimethyl disulfide, and dimethyl trisulfide, were very abundant in the black-bloom waters. The massive anoxic degradation of dead Potamogeton crispus plants released dimethyl sulfide, dimethyl disulfide, and dimethyl trisulfide, which were the main odor-causing compounds in the black blooms. The black blooms also induced an increase in ammonium nitrogen and soluble reactive phosphorus levels in the overlying waters. This extreme phenomenon not only heavily influenced the original lake ecosystem but also greatly changed the cycling of Fe, S, and nutrients in the water column. 相似文献
90.
Awoke Guadie Siqing Xi Wei Jiang Lijie Zhou Zhiqiang Zhang Slawomir W. Hermanowicz Xiaoyin Xu Shuang Shen 《环境科学学报(英文版)》2014,26(4):765-774
The feasibility of struvite recovery at low (12.5 mg/L) and high (120 mg[L) phosphorus concentrations was studied by constructing a novel fluidized bed reactor with cones (FBRwc) and without cones (FBRwoc). The crystallization process was continuously operated for 133 days under different hydraulic retention times (HRT = 1-10 hr), pH (7.5-10), and molar ratios of Mg/P (0.75-1.75), N/P (1-10) and Ca/Mg (0-2). The optimum operating conditions of HRT, pH, Mg/P and N/P molar ratios were found to be 2 hr, 9, 1.25, and 7.5, respectively. Under these optimum conditions, the phosphorus precipitation efficiencies of FBRwc were 93% for low and 98% for high phosphorus influent; however, the efficiencies were 78% and 81% for FBRwoc, respectively. Due to crystal losses at each junction (17%-31%), the crystal recovery efficiency of FBRwoc was relatively low (47%-65%) for both influent concentrations. However, the losses were minimal in FBRwc, which showed 75% and 92% crystal recovery for low and high phosphorus concentrations, respectively. At low calcium concentration, crystal chemical analysis showed the product to be pure struvite (〉 99%). The scanning electron microscope and X-ray diffraction results further confirmed that the crystal recovered from FBRwc contained pure struvite, which could be considered a high quality fertilizer. Except HRT, all parameters (pH, Mg/P, N/P and Ca/Mg) were found to be influencing factors for FBRwc performance. Overall, inserting cones in each part of the reactor played a significant role in enhancing struvite recovery from a wide range of phosphorus-containing wastewater. 相似文献