Calorimetric studies on the thermal stability of methyl ethyl ketone peroxide (MEKP) formulations

The energetic decomposition of methyl ethyl ketone peroxide (MEKP) and its formulations have long been known to present a significant risk. Indeed, MEKP has the highest number of reported decomposition incidents of all organic peroxides, many of which have led to significant numbers of fatalities, injuries and damage. It is noteworthy that incidents have been reported at all stages of the product lifecycle.This paper is derived from incident-investigation work and provides a summary of serious incidents involving MEKP, followed by details of calorimetric experiments performed to investigate thermal stability of representative MEKP formulations containing varying amounts of MEKP monomer. In particular we report the wide degree of variation that exists between commercial MEKP formulations, even between materials that are of the same nominal formulation. Such variations are detectable using differential scanning calorimetry (DSC).Follow-up studies performed on a representative MEKP formulation containing MEKP monomer indicate that a risk of decomposition exists at temperatures well below the reported self-accelerating decomposition temperature (SADT) of the products. As such, the experimental results reported here suggest that lower storage temperatures (commonly recommended by manufacturers to maximise shelf life) should be considered as being essential throughout the product lifecycle to reduce the risk of accidents in storage and transportation.     

Mapping green technologies literature published between 1995 and 2019: a scientometric review from the perspective of the manufacturing industry

Environmental Science and Pollution Research - This study presents a comprehensive literature review and gives an insight into the increasing research trends that are based on the discipline of...     

A review on detection of heavy metals from aqueous media using nanomaterial-based sensors

Environmental Science and Pollution Research - The extensive release of heavy metals into the natural water bodies has become globally prevalent from past few decades. Heavy metal toxicity is...     

Do higher education research and development expenditures affect environmental sustainability? New evidence from Chinese provinces

Environmental Science and Pollution Research - Even though higher education R&D expenditures (HEEXP) are important determinants of economic growth that facilitate science, technology, new...     

The impact of financial development and globalization on environmental quality: evidence from South Asian economies

Environmental Science and Pollution Research - Climate change resulting from the higher concentration of greenhouse gases in the atmosphere is a threat to the sustainability of life on earth. To...     

Arsenic and lead in the indoor residential settings of different socio-economic status; assessment of human health risk via dust exposure

Environmental Science and Pollution Research - In the present study, occurrence of arsenic (As) and lead (Pb) is reported in rural and urban household dust (floor and AC filter dust) of the Kingdom...     

Bacteriological study of Upper Lake of Bhopal, India

In order to assess the water quallty of the upper lake of Bhopal (India) after the leakage of methyl isocyanate (MIC) gas from the Union Carbide factory, Bhopal, bacteriological study of the lake water was carried out. Water samples were collected from eight different sampling stations from the eastern, western, northern and southern sides of the lake. The study has revealed that the coliform bacteria are increased (24000/mL) at the onset of summer and are dropped to a minimum (120/mL) during monsoon season against the permissible limit of 100/mL recommended by the World Health Organisation (WHO) for water to be used for drinking purposes. The data collected show that the water quality of the Upper lake is deteriorated and is gradually becoming unfit for drinking.     

Investigating degradation metabolites and underlying pathway of azo dye “Reactive Black 5” in bioaugmented floating treatment wetlands

Environmental Science and Pollution Research - The direct discharge of azo dyes and/or their metabolites into the environment may exert toxic, mutagenic, and carcinogenic effects on exposed fauna...     

Assessment of Hg accumulation in fish and scalp hair in fishing communities along river Swat,Pakistan

Environmental Science and Pollution Research - Mercury (Hg) bioaccumulation in fish poses severe threats to the food safety and human health. This study was conducted to assess Hg bioaccumulation...     

Correction to: Health risk assessment of hexachlorocyclohexane in soil,water and plants in the agricultural area of Potohar region,Punjab, Pakistan

Environmental Geochemistry and Health - A correction to this paper has been published: https://doi.org/10.1007/s10653-021-00910-5