环保型民用建筑墙体节能工程施工质量监督策略研究

环保型民用建筑墙体节能工程施工的材料、设备、工艺复杂,需要进行建筑施工优化管理和质量监督,从而确保施工进度和工程质量,对环保型民用建筑墙体节能工程施工实施全过程质量控制,加强墙体施工的质量监督和管理。对建筑项目做好工程施工质量的风险预估,结合材料和设备、环境等方面的影响因素进行工程质量技术指导和风险控制。在施工过程中进行质量监督的动态过程控制,按照标准和规范,进行环保型节能建筑墙体施工质量的量化管理,使得建筑施工质量符合规范标准要求。     

Air Pollution in Singapore: Its Multielemental Aspect as Measured by Nuclear Analytical Techniques

Aerosol samples were collected in 1994 in Singapore on two occasions: once in June during the normal meteorological conditions and later in October during a long haze period caused by the heavy forest fire in Indonesia. Filtration and impaction collection methods were used simultaneously so that detailed elemental analysis of bulk as well as of different size fractions could be performed. Accelerator based nuclear analytical techniques such as Particle Induced X-Ray Emission (PIXE), Rutherford Backscattering (RBS) and Nuclear Microscopy (NM) were used for analysis. These techniques are fast, truly multielemental and perfectly suited for routine analysis of a large number of aerosol samples. Typically all samples were analysed for the following 24 elements: Na, Mg, Al, Si, P, S, Cl, K, Ca, Ti, V, Mn, Cr, Fe, Co, Ni, Cu, Zn, Ga, As, Br, Rb, Sr and Pb. Detection limits for bulk analysis were generally below ng/m3 and for single particle analysis absolute detectable mass was approximately 10-17 g. Additionally, trace elements such as Cd, Sn, Sb and Ba whose characteristic X-ray lines were normally "obscured" by the lines of other more abundant elements, were detected when analysing by nuclear microscope in single particle mode.Judging by the average concentrations of lead and sulphur which are good indicators of industrial component of air pollution the situation in Singapore is satisfactory. Pb was typically found in concentrations of 5 to 50 ng/m3 and sulphur in concentrations of 1 to 2 µg/m3. These concentrations are well below limits set by the World Health Organisation (1500 ng/m3 and 40 µg/m3, respectively). On the other hand during the haze period the average concentrations of elements like S, K, Ti, V, Mn, Ni, As and Pb were found to be 3 to 6 times higher than usual. Results are presented and discussed.     

环境样品中 PCBs 的测定

通过碱解、酸洗、萃取、净化、浓缩、脱硫等步骤处理实际样品,利用毛细管柱GC/ECD进行PCBs的定性和定量.方法定性准确,定量良好,具有较高的回收率.各同系物的方法检出限,水样为0.01～0.08ng/L;土壤样为0.003～0.03μg/kg,可以应用于土壤、沉积物、水样、油样等环境样品中PCBs的测定     

The organic composition of diesel particulate matter, diesel fuel and engine oil of a non-road diesel generator

Diesel-powered equipment is known to emit significant quantities of fine particulate matter to the atmosphere. Numerous organic compounds can be adsorbed onto the surfaces of these inhalable particles, among which polycyclic aromatic hydrocarbons (PAHs) are considered potential occupational carcinogens. Guidelines have been established by various agencies regarding diesel emissions and various control technologies are under development. The purpose of this study is to identify, quantify and compare the organic compounds in diesel particulate matter (DPM) with the diesel fuel and engine oil used in a non-road diesel generator. Approximately 90 organic compounds were quantified (with molecular weight ranging from 120 to 350), which include alkanes, PAHs, alkylated PAHs, alkylbenzenes and alkanoic acids. The low sulfur diesel fuel contains 61% alkanes and 7.1% of PAHs. The identifiable portion of the engine oil contains mainly the alkanoic and benzoic acids. The composition of DPM suggests that they may be originated from unburned diesel fuel, engine oil evaporation and combustion generated products. Compared with diesel fuel, DPM contains fewer fractions of alkanes and more PAH compounds, with the shift toward higher molecular weight ones. The enrichment of compounds with higher molecular weight in DPM may be combustion related (pyrogenic).     

“引江济太”对太湖北部底质及水质总磷的影响

应用GIS技术研究了"引江济太"对太湖北部底质与水质总磷(TP)浓度的影响。研究结果表明,2014—2019年,调水北部沿线4个点位底质TP浓度降幅为59.8%～80.5%;不同点位的水质TP浓度变化存在差异,入湖口点位下降14.1%,沿线其他点位分别上升37.4%、38.6%和45.0%。从空间分布来看,太湖水质TP始终呈明显的"西高东低"分布特点,但底质TP的分布未显示出该类规律。望亭水利枢纽调水情况与入湖口5#点位底质TP浓度呈一定程度的正相关,在调水入湖水量大于出湖水量的年份,5#点位底质TP浓度会偏高。"引江济太"会对太湖北部调水沿线,特别是入湖口附近水域的TP含量产生较大影响,并通过水流迁移与底质再悬浮释放影响下游水域。如何降低望虞河及周边支流的入湖泥沙量将是今后开展科学调水、保障贡湖水源地水质安全的重点研究方向之一。     

2017年上半年北京市及周边地区空气质量特征分析

依托北京市、廊坊市和保定市高密度的地面空气质量监测、气象要素监测以及PM_2.5化学组分监测和后向轨迹分析等手段，对2017年上半年三地的空气质量进行分析。研究发现：三地中北京市空气质量较好，保定市较差。分污染物来看，保定市SO₂浓度水平明显高于廊坊市和北京市，颗粒物PM₁₀和PM_2.5也呈现保定市最高、北京市最低的规律。从污染物日变化来看，CO、SO₂、NO₂、PM₁₀和PM_2.5呈双峰型分布，O₃呈单峰型分布。从区域整体分布规律来看，PM_2.5和SO₂呈现明显的"南高北低"特征。PM_2.5化学组分分析结果表明：1—4月燃煤对该区域空气质量的影响较大，5—6月机动车排放的影响更为凸显。后向轨迹分析结果表明：在2017年上半年到达北京市的气流中有24%来自于北京市南部，且这些气流多为低空传输，表明区域传输对于北京市空气质量具有一定的影响。     

城市人居环境的协调发展度研究——以上海市青浦区为例

城市人居环境的可持续发展体系是一个由人口、社会、资源、环境与经济5个子系统构成的开放巨系统。通过提出综合衡量系统“协调性”和“发展水平”的“协调发展度”模型，研究人居环境复合系统内5个子系统之间协调发展度情况。并运用灰色预测理论构建GM（1，N）动态模型，预测未来几年各子系统之间协调发展的状况。     

花岗岩类岩体与金矿床成因关系的探讨

花岗岩类岩体与金矿床存在着密切的空间联系，其成因关系一直是矿床学界争论的焦点，目前传统的岩浆热液成因观点仍居统治地位。随着地质资料的积累，高温高压实验技术，尤其是金矿床同位素定年技术的进展，传统观点受到了严峻挑战。成岩成矿的时代与时差、成矿流体的来源和成矿物质的来源等确定金矿床成因类型关键因素的综合研究表明，有密切空间关系的金矿床与花岗岩类岩体之间，在多数情况下两者并无直接的成因联系，金矿床不是岩浆热液成因，而是与大气降水或建造水有关的改造成矿作用的产物。     

金属对催化还原DDT的降解产物及其反应机制的研究

本报告介绍DDT经金属对处理后降解产物的分析鉴定和有关反应机制的初步研究。 降解产物主要是用气相色谱—质谱联用分析鉴定的。水溶液中的DDT用Cu-Zn金属对还原其降解产物经鉴定是DDD、DDMS、DDE_t,它们是DDT分子脱去烷基碳原子上不同数目的氯原子的产物。而在Cu-Fe金属对作用下,水溶液中的DDT的还原则是同时得到四种不同类型的产物。它们是DDT脱去烷基碳原子上的1个和3个氯原子的DDD和DDE_t;DDT脱氯、氧化产物DBP和DBH;DDT脱去HCI生成的DDE;两个DDT分子二聚脱氯的产物TTTB和TTDB。 实验证明金属对对DDT的作用是催化还原反应,金属对起着催化剂和还原剂双重作用。通过实验结果对DDT在金属对作用下的反应机制进行了初步探讨。     

水霉科真菌在北京地区不同污染水体中的分布和数量变化

对北京地区水霉科真菌在不同污染水体中分布和数量变化的调查研究表明,水霉科游动孢子在水体中的数量随水体污染程度的变化而不同:一般在净水中较少,在轻度污染至中度污染的水体中明显增多,污染加重时逐渐下降,在重污染区明显减少,在近于毒污染的水体中则几乎绝迹.可见水霉科真菌在不同污染水体中的分布和数量变化具有一定的规律性,将其用作对水体进行综合评价的一项生物指标的可行性值得进一步研究.