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31.
Concentrations of ten metals (As, Cd, Cr, Cu, Fe, Mn, Ni, Pb, Zn and Hg) in the edible muscle of Arius maculatus captured from eight different near‐shore and off‐shore sites off the south west coast of the Arabian Sea, Pakistan, were determined by atomic absorption spectrophotometry. Relevant water and sediment samples from the sites were also analysed for the metals. Zinc showed the highest metal concentration (6.763 μg/g, wet weight) in the muscle of the fish, while Mn and Hg showed lowest level (0.019 μg/g, wet weight). Of all the metals investigated, largest scatter (measured as σ) was observed for Zn (σ = 2.058 /μg/g) in fish muscle, for Fe and Mn in sediment (σ = 27481 and 44.50 μg/g) and for As in water (σ = 0.270 μg/L). The metal distribution data pertaining to water, fish and sediment were examined on the basis of simple metal correlations. The statistical study revealed that Ni, Cr, Pb and Cu had significant positive correlations (r > 0.830 at ρ = 0.01). The finding substantiated a trace metal concentration gradient in the area, thereby indicating that the local marine environment is contaminated by anthropogenic sources. 相似文献
32.
Eleven metals (Ca, Mg, Fe, Zn, Cu, Mn, Cd, Co, Cr, Ni and Pb) were estimated in hair samples of metal arc welders and a control group with the same socioeconomic background. Nitric acid–perchloric acid wet digestion procedure was adopted for the estimation of endogenous metal contents by ICP-AE technique. The study exhibited the following increasing order of the metal concentrations: Cd??1, dry weight, respectively. On average, the levels of Mn, Ni, Pb and Fe were found to be 1.5–2.4 times higher in the hair of welders compared with controls. Besides age and exposure which were strongly correlated, Cu–Mg, Mn–Mg, Ca–Co and Cd–Zn also showed significantly positive correlations. The identification of metal sources, done by cluster and principal component analyses, revealed four factors: age and exposure; Cu, Mg, Mn and Fe; Ca and Co; Cd, Zn, Ni and Pb. High levels of Fe were found to have a depleting impact on Co levels. The arc welders were feared to accumulate heavy metals in their bodies due to long-term endogenous exposure. 相似文献
33.
Asghar Naveed Majeed Muhammad Tariq Khan Muhammad Waqas Anwar Awais 《Environmental science and pollution research international》2023,30(1):145-160
Environmental Science and Pollution Research - Biomass energy is an important source of energy consumption. It is a renewable, abundant, and easily produced energy source. Its usage supports... 相似文献
34.
Sadullah Mir Tariq Yasin Humaira Masood Siddiqi Ghulam Murtaza 《Journal of Polymers and the Environment》2017,25(4):1011-1020
In this study water soluble sodium carboxymethyl cellulose (CMC) was blended with high density polyethylene (HDPE) by peroxide-initiated melt compounding technique. The compatibility of the blended polymers were carried out by silane crosslinking agent. A series of blends were prepared by varying the CMC contents up to a maximum of 50 phr. The physical properties of non-crosslinked and crosslinked blends were investigated in detail. FTIR analysis of crosslinked blend confirmed the presence of Si–O–Si and Si–O–C absorption peaks at 1050 and 1159 cm?1. Thermal stability of crosslinked blends improved as compared to its non-crosslinked congener. Rheological study of crosslinked blends illustrated high complex viscosity and dynamic shear storage modulus. The tensile strength of virgin polyethylene was 8.1 MPa whereas the maximum tensile strength of 19.6 MPa was observed in crosslinked blend. Similarly lower deformation was observed in crosslinked blends under static load. Scanning electron microscopy of crosslinked formulations also showed strong adhesion between the polymers interface. The compatibility of HDPE and CMC is attributed to both free radical and condensation reactions. 相似文献
35.
Hussani Mubarak Li-Yuan Chai Nosheen Mirza Zhi-Hui Yang Arshid Pervez Madiha Tariq 《毒物与环境化学》2015,97(10):1296-1318
In view of increasing emissions of antimony (Sb) into the environment due to industrialization and consequent carcinogenicity, it is essential to remove this metal from the ecosystem. Antimony and arsenic (As) are analogs. Although numerous studies examined arsenic removal, few reports are available on Sb removal. In this review, various Sb removal techniques are described to understand how this process occurs and what research gaps are needed to improve efficiency. At present, surface adsorption technique is the most widely used for Sb removal. Biological treatment namely phytoremediation is also a promising method and more investigations are required in this regard. The selection of a suitable technique for a given area depends on the conditions including economic, environmental, and social conditions. 相似文献
36.
The influence of copper(II)chloride on selected key enzymes and metabolites in intermediary metabolism and the energy charge potential of the hyperregulating shore crab, Carcinus maenas (L.) were investigated. Crabs, collected in Odense Fjord, Denmark between September 1989 and May 1990, were exposed to 10 ppm copper(II)chloride, in 10 ppt salinity seawater at 15°C for up to 1 wk. Hexokinase activity was 77% lower in the posterior gills and 60% lower in the midgut gland than in control crabs. Phosphofructokinase activity was reduced in the midgut gland by 82% but was unaffected in the gills. Pyruvate kinase activity was undetectable in the gills of exposed crabs and reduced by 47% in the midgut gland. Citrate synthase activity was depressed by 30% in the posterior gills and unaffected in other tissues. Copper exposure had no apparent effect on tissue cytochrome c oxidase activity. Chela muscle was the only tissue in which copper exposure did not bring about reductions in the enzyme activities tested. As a result of 1 wk of copper exposure the average lactate level increased by 3.5-fold in haemolymph, 9.3-fold in posterior gills and 6.5-fold in midgut gland. The average glucose level was raised by a factor of 6 in the haemolymph, 3.4 in the posterior gills and 1.2 in the midgut gland. Energy charge potential was at a very high level (ca. 0.9) and was unaffected by copper exposure. 相似文献
37.
Downward shortwave radiation (DSR) is a highly variable solar source on spatiotemporal basis and essential for energy and agriculture systems, while its calculations are helpful in the environment-related studies, climatology, and monitoring fire risk. Statistical methods developed to extrapolate values of climatic variables and radiation could fail to generate reliable findings of DSR over a complex terrain without considering local topographic factors. In the present study, we proposed an integrative approach of MTCLIM-XL extrapolation with remote sensing (RS) and geographic information system (GIS) to estimate real-time DSR and its spatial potential over surfaces of contrasting elevated sites on a mountainous terrain of Quetta (Pakistan).Based on methodological approach, remote sensing data product of high-resolution DEM (SRTM 30m) was processed to extract topographic data, and meteorological data were obtained from a base site, Subsequently, MTCLIM-XL executed the simulation to calculate the daily-based DSR (W/m2).Spatial distribution of DSR was generated by applying deterministic interpolation with complementing quantification of Hillshade analysis for spatially obstructive surfaces, and resultant spatial hotspot-based potential was assessed on basis of specified threshold level (above 250 W/m2 = 2 kW h/m2) over the specified area. We observed usable potential of DSR at target sites and its spatial distribution during the study period of 2015 to April 2016. Using EUMETSAT CMSAF data as a standard, the validation demonstrates agreeable results of low RMSE and high correlation coefficient values for selected sites, except some sites with relatively high elevations and irregular gradients. Analysis of solar zenith angle to evaluate its inverse relation with increment in DSR values shows agreeable high inverse relation, while the negative trend for only some sites features relatively high rugged topography. In conclusion, MTCLIM-XL with RS and GIS integration manifests as a reliable approach for estimation and spatial potential assessment-based exploration of DSR over complex terrain having no ground data, while prospectively it will complement to the environment-related studies on local to mesoscale. 相似文献
38.
Ziyad Tariq Abdullah 《环境质量管理》2023,32(4):223-235
Construction is a major contributor to the solid waste stream globally and various recycling strategies are being evaluated to recover valuable resources. As a novel strategy, remanufacturing waste reinforcing steel bar (rebar) pieces from concrete waste to produce nails was applied on an industrial scale to prove the technical feasibility, where a group of alternatives were developed based on commercially available industrial machinery. The calculated economic and environmental feasibility values are sufficiently high for industrial application, and the most appropriate remanufacturing technological alternative was identified. The sustainability equation was solved to find the social feasibility and overall remanufacturing sustainability index. Rebar waste remanufacturing has a high triple-bottom-line sustainability index of 0.885. Based on the proposed process, small remanufacturing companies can be developed, thereby aiding employment and human development by earning profit of 1904–8880 USD/day. The findings of this study are beneficial to decision makers in government and industry and are globally relevant because concrete waste is ubiquitous worldwide. 相似文献
39.
Jehan Shah Ullah Ihsan Khan Sardar Muhammad Said Khattak Seema Anjum Khan Tariq 《Environmental science and pollution research international》2020,27(31):38545-38558
Environmental Science and Pollution Research - This study evaluates the characteristics of water along the Swat River, Northern Pakistan. For this purpose, water samples (n = 30) were... 相似文献
40.
Khan Muhammad Tariq Iqbal Anwar Sofia Batool Zahira 《Environmental science and pollution research international》2022,29(35):52412-52437
Environmental Science and Pollution Research - This study shows the impact of risk (hazard, exposure, and vulnerability) and resilience (infrastructure, information and communication technology,... 相似文献