Lithological and hydrochemical controls on distribution and speciation of uranium in groundwaters of hard-rock granitic aquifers of Madurai District,Tamil Nadu (India)

Uranium is a radioactive element normally present in hexavalent form as U(VI) in solution and elevated levels in drinking water cause health hazards. Representative groundwater samples were collected from different litho-units in this region and were analyzed for total U and major and minor ions. Results indicate that the highest U concentration (113 µg l^?1) was found in granitic terrains of this region and about 10 % of the samples exceed the permissible limit for drinking water. Among different species of U in aqueous media, carbonate complexes [UO₂(CO₃) ₂ ^2? ] are found to be dominant. Groundwater with higher U has higher pCO₂ values, indicating weathering by bicarbonate ions resulting in preferential mobilization of U in groundwater. The major minerals uraninite and coffinite were found to be supersaturated and are likely to control the distribution of U in the study area. Nature of U in groundwater, the effects of lithology on hydrochemistry and factors controlling its distribution in hard rock aquifers of Madurai district are highlighted in this paper.     

Chemically modified biochar produced from conocarpus waste increases NO<Subscript>3</Subscript> removal from aqueous solutions

Biochar has emerged as a universal sorbent for the removal of contaminants from water and soil. However, its efficiency is lower than that of commercially available sorbents. Engineering biochar by chemical modification may improve its sorption efficiency. In this study, conocarpus green waste was chemically modified with magnesium and iron oxides and then subjected to thermal pyrolysis to produce biochar. These chemically modified biochars were tested for NO₃ removal efficiency from aqueous solutions in batch sorption isothermal and kinetic experiments. The results revealed that MgO-biochar outperformed other biochars with a maximum NO₃ sorption capacity of 45.36 mmol kg^?1 predicted by the Langmuir sorption model. The kinetics data were well described by the Type 1 pseudo-second-order model, indicating chemisorption as the dominating mechanism of NO₃ sorption onto biochars. Greater efficiency of MgO-biochar was related to its high specific surface area (391.8 m² g^?1) and formation of strong ionic complexes with NO₃. At an initial pH of 2, more than 89 % NO₃ removal efficiency was observed for all of the biochars. We conclude that chemical modification can alter the surface chemistry of biochar, thereby leading to enhanced sorption capacity compared with simple biochar.     

Residual veterinary antibiotics in pig excreta after oral administration of sulfonamides

Sulfonamides (SAs) are applied widely as feed additives in the farming of livestock and poultry. It can lead to the excretion of large amounts of SAs in manure and result in persistent environmental pollution. We evaluated the fate of four SAs, sulfamerazine (SM₁), sulfachloropyridazine (SCP), sulfadimoxine (SDM′) and sulfaquinoxaline (SQ), from oral administration to excretion in urine and feces in pigs. The four SAs were added to homemade feed to make them reach the required concentration gradient, which were 0, 50 and 100 mg/kg (low, normal and high concentrations, respectively). In different treatments, excretions of the four SAs were 35.68–86.88 %. With regard to total excretion, the order was SQ > SCP > SM₁ > SDM′ for all treatments. The concentration of SAs in the feed had significant effects on the amount of the four SAs excreted every day. The concentration of SAs in feces and in the urine for different treatments was 15.03–26.55 and 14.54–69.22 %, respectively. In each treatment, excretions of SCP, SDM′ and SQ in feces were lower than that in urine. The four SAs remained longer in urine than in feces. Excretions in urine and feces were lower if SAs were administered orally rather than by injection.     

Products of biotransformation of polycyclic aromatic hydrocarbons in fishes of the Athabasca/Slave river system,Canada

Concentrations of products of biotransformation of polycyclic aromatic hydrocarbons (PBPAH) were measured in bile of five fishes of nutritional, cultural and ecological relevance from the Athabasca/Slave river system. Samples were collected in Alberta and the Northwest Territories, Canada, during three seasons. As a measure of concentrations of PBPAHs to which fishes are exposed and to gain information on the nature and extent of potential exposures of people or piscivorous wildlife, concentrations of biotransformation products of two- and three-ringed, four-ringed and five-ringed PAHs were measured using synchronous fluorescence spectroscopy. Spatial and seasonal differences were observed with greater concentrations of PBPAHs in samples of bile of fish collected from Fort McKay as well as greater concentrations of PBPAHs in bile of fish collected during summer compared to those collected in other seasons. Overall, PBPAHs were greater in fishes of lower trophic levels and fishes more closely associated with sediments. In particular, goldeye (Hiodon alosoides), consistently contained greater concentrations of all the PBPAHs studied.     

Estimated lead (Pb) exposures for a population of urban community gardeners

Urban community gardens provide affordable, locally grown, healthy foods and many other benefits. However, urban garden soils can contain lead (Pb) that may pose risks to human health. To help evaluate these risks, we measured Pb concentrations in soil, vegetables, and chicken eggs from New York City community gardens, and we asked gardeners about vegetable consumption and time spent in the garden. We then estimated Pb intakes deterministically and probabilistically for adult gardeners, children who spend time in the garden, and adult (non-gardener) household members. Most central tendency Pb intakes were below provisional total tolerable intake (PTTI) levels. High contact intakes generally exceeded PTTIs. Probabilistic estimates showed approximately 40 % of children and 10 % of gardeners exceeding PTTIs. Children’s exposure came primarily from dust ingestion and exposure to higher Pb soil between beds. Gardeners’ Pb intakes were comparable to children’s (in µg/day) but were dominated by vegetable consumption. Adult household members ate less garden-grown produce than gardeners and had the lowest Pb intakes. Our results suggest that healthy gardening practices to reduce Pb exposure in urban community gardens should focus on encouraging cultivation of lower Pb vegetables (i.e., fruits) for adult gardeners and on covering higher Pb non-bed soils accessible to young children. However, the common practice of replacement of root-zone bed soil with clean soil (e.g., in raised beds) has many benefits and should also continue to be encouraged.     

A numerical model of periodically forced circulation near the shore of a lake

Numerical calculations for a model of the near-shore circulation in a lake subject to two diurnal forcing mechanisms are presented. The first mechanism is a heating/cooling term in the heat equation representing the daytime heating and nighttime cooling of the diurnal cycle. The second is a periodic surface stress modelling a sea-breeze/gully wind system typical of some coastal regions. The two forcing mechanisms can either act together or against each other depending on their relative phase. The numerical solutions are compared with previously published analytical solutions and used to explore the extra dynamics associated with non-linear effects (specifically advection). The latter dynamics include the formation of gravity currents and unstable density profiles leading to secondary circulation.     

Development and testing of a micro wind tunnel for on-site wind erosion simulations

Wind erosion processes affect soil surfaces across all land uses worldwide. Understanding the spatial and temporal scales of wind erosion is a challenging undertaking because these processes are diverse and highly variable. Wind tunnels provide a useful tool as they can be used to simulate erosion at small spatial scales. Portable wind tunnels are particularly valued because erosion can be simulated on undisturbed soil surfaces in the field. There has been a long history of use of large portable wind tunnels, with consensus that these wind erosion simulation tools can meet real world aerodynamic criteria. However, one consequence of striving to meet aerodynamic reality is that the size of the tunnels has increased, making them logistically difficult to work with in the field and resulting in a tendency to homogenise naturally complex soil surfaces. This homogenisation is at odds with an increasing awareness of the importance that small scale processes have in wind erosion. To address these logistical and surface homogenisation issues we present here the development and testing of a micro wind tunnel (MWT) designed to simulate wind erosion processes at high spatial resolution. The MWT is a duct-type design—0.05 m tall 0.1 m wide and with a 1.0 m working section. The tunnel uses a centrifugal motor to suck air through a flow‐conditioning section, over the working section and then through a sediment collection trap. Simulated wind velocities range from 5 to 18 m s^?1, with high reproducibility. Wind speeds are laterally uniform and values of u _* at the tunnel bed (calculated by measuring the pressure gradients within the MWT) are comparable with those of larger tunnels in which logarithmic profiles can be developed. Saltation sediment can be added. The tunnel can be deployed by a single person and operated on slopes ranging from 0 to 10°. Evidence is presented here that the MWT provides new and useful understanding of the erodibility of rangelands, claypans and ore stockpiles.     

Modeling the interaction between tides and storm surges for the Taiwan coast

An unstructured grid, two-dimensional hydrodynamic model was established and applied to the coast of Taiwan to investigate the tide-surge interaction. Tidal elevations at the open boundaries coupled with a global ocean tidal model and the meteorological conditions using a cyclone model are used to drive the model. The model was calibrated and verified with the observed tidal levels at six tidal stations for seven typhoon events to ascertain the capability and feasibility of the model. The results show reasonable agreement between the simulated and observed tidal levels. The validated model was then applied to probe the influence of tide-surge interaction on phase, water levels, and storm surge height. We found that the tide-surge interaction influenced both the magnitude and timing of the surge, which depended on the typhoon path. The storm surge heights at different tidal stations were significantly influenced by wind stresses and directions. The water level rise due to the storm surge during high tide was greater at neap tide than at spring tide. Changing tidal ranges altered the prediction of the surge enough to induce the changes in peak water levels.     

Characteristics of flow structure of free-surface flow in a partly obstructed open channel with vegetation patch

Free-surface flows over patchy vegetation are common in aquatic environments. In this study, the hydrodynamics of free-surface flow in a rectangular channel with a bed of rigid vegetation-like cylinders occupying half of the channel bed was investigated and interpreted by means of laboratory experiments and numerical simulations. The channel configurations have low width-to-depth aspect ratio (1.235 and 2.153). Experimental results show that the adjustment length for the flow to be fully developed through the vegetation patch in the present study is shorter than observed for large-aspect-ratio channels in other studies. Outside the lateral edge of the vegetation patch, negative velocity gradient (\(\partial \overline{u}/\partial z < 0\)) and a local velocity maximum are observed in the vertical profile of the longitudinal velocity in the near-bed region, corresponding to the negative Reynolds stress (\(- \overline{{u^{\prime}w^{\prime}}} < 0\)) at the same location. Assuming coherent vortices to be the dominant factor influencing the mean flow field, an improved Spalart–Allmaras turbulence model is developed. The model improvement is based on an enhanced turbulence length scale accounting for coherent vortices due to the effect of the porous vegetation canopy and channel bed. This particular flow characteristic is more profound in the case of high vegetation density due to the stronger momentum exchange of horizontal coherent vortices. Numerical simulations confirmed the local maximum velocity and negative gradient in the velocity profile due to the presence of vegetation and bed friction. This in turn supports the physical interpretation of the flow processes in the partly obstructed channel with vegetation patch. In addition, the vertical profile of the longitudinal velocity can also be explained by the vertical behavior of the horizontal coherent vortices based on a theoretical argument.     

Modeling and experiments of polydisperse particle clouds

A model for polydisperse particle clouds has been developed in this study. We extended the monodisperse particle cloud model of Lai et al. (Environ Fluid Mech 13(5):435–463, 2013) to the case of polydisperse particles. The particle cloud is first considered to be a thermal or buoyant vortex ring, with the thermal induced velocity field modeled by an expanding spherical Hill’s vortex. The buoyancy of the composite thermal is assumed to be the sum of buoyancy contributed by the all particles inside the thermal. Individual particles (of different particle properties) in the cloud are then tracked by the particle tracking equation using the computed induced velocity field. The turbulent dispersion effect is also accounted for by using a random walk model. Experiments of polydisperse particle clouds were carried out to validate the model. The agreement between model predictions and experiments was reasonable. We further validate our model by comparing it with the LES study of Wang et al. (J Hydraul Eng ASCE 141(7):06015006, 2014). The limitations of our model are then discussed with reference to the comparison. Overall, although some flow details are not captured by our model, the simplicity and generality of the model makes it useful in engineering applications.