基于白碳黑的水化硅酸钙制备及其磷回收特性简

以白碳黑、硅灰、硅藻土和硅胶筛选硅质原料，并与钙质原料电石渣制备了水化硅酸钙。借助XRF、BET、FTIR等表征手段，通过多次重复除磷实验，研究了硅质原料特性对水化硅酸钙回收磷性能的影响。结果表明，白碳黑具有极高的反应活性，因此可作为制备具有磷回收特性的水化硅酸钙的硅质原料。结合XRD等表征发现，白碳黑的有效利用率是影响水化硅酸钙回收磷性能的关键，该利用率取决于白碳黑与电石渣的摩尔配比以及水热反应温度。当电石渣与白碳黑的摩尔比为1.6：1，反应温度为170℃时，白碳黑具有最佳的利用效率。该条件制备的水化硅酸钙可作为晶种，在其表面结晶形成羟基磷灰石，从而达到磷回收的目的，磷回收后固体物质中的磷含量为19.05%。     

Comparative quantification of oxygen release by wetland plants: electrode technique and oxygen consumption model

Understanding oxygen release by plants is important to the design of constructed wetlands for wastewater treatment. Lab-scale systems planted with Phragmites australis were studied to evaluate the amount of oxygen release by plants using electrode techniques and oxygen consumption model. Oxygen release rate (0.14 g O₂/m²/day) measured using electrode techniques was much lower than that (3.94–25.20 gO₂/m²/day) calculated using the oxygen consumption model. The results revealed that oxygen release by plants was significantly influenced by the oxygen demand for the degradation of pollutants, and the oxygen release rate increased with the rising of the concentration of degradable materials in the solution. The summary of the methods in qualifying oxygen release by wetland plants demonstrated that variations existed among different measuring methods and even in the same measuring approach. The results would be helpful for understanding the contribution of plants in constructed wetlands toward actual wastewater treatment.     

酸性洗涤塔-生物滤塔-生物曝气池组合工艺处理恶臭气体NH3和H2S

采用酸性洗涤塔、生物滤塔和生物曝气池的组合工艺处理NH3、H2S恶臭混合气体,研究表明,该组合工艺对NH3和H2S有很好的去除效果,在进气流量为35 L/min,喷淋量45 L/h时,NH3进气浓度50.15~525.4 mg/m3,H2S进气浓度10.23~110.36 mg/m3时,NH3单一进气去除率稳定在99%以上,H2S单一进气去除率90%以上。混合进气后,NH3去除率几乎为100%,H2S的去除率提高至98%以上。在一定的浓度范围内,NH3和H2S之间的相互作用对两者的去除效果没有明显的影响,而且起到了相互促进降解的作用。同时,进气流量和填料层高度都会影响NH3、H2S的去除率。系统对进气容积负荷变化的缓冲能力强,在偶尔超负荷条件下运行并不能使系统崩溃,并且微生物对高负荷逐渐表现出适应性。大部分溶于水的氨由生物曝气池去除,去除率达到96.9%。     

Parental phenols exposure and spontaneous abortion in Chinese population residing in the middle and lower reaches of the Yangtze River

Widespread use of phenols has led to ubiquitous exposure to phenols. In experimental animals, phenols increased resorptions, reduced live litter size and fetal body weights. However, there are limited epidemiological evidences of the relationships between exposure to phenols and pregnancy outcomes. We evaluated the associations between parental urinary levels of various phenols and spontaneous abortion in a Chinese population residing in the middle and lower reaches of the Yangtze River. A case-control study was conducted that included 70 case couples with medically unexplained spontaneous abortion and 180 control couples who did not have a history of spontaneous abortion and had at least one living child. Both parental urinary phenols were measured by ultra-high performance liquid chromatography-tandem mass spectrometry including bisphenol A (BPA), benzophenone-3 (BP-3), 2,3,4-trichlorophenol (2,3,4-TCP), pentachlorophenol (PCP), 4-n-octylphenol (4-n-OP) and 4-n-nonylphenol (4-n-NP). Compared with the low exposure group, there was an increased risk of spontaneous abortion with high paternal urinary PCP concentration [odds ratio (OR) = 2.09, 95% Confidence Interval (CI), 1.05–4.14], and maternal exposure to 4-n-OP and alkylphenol(s) also significantly increased the risk of spontaneous abortion (OR = 2.21, 95% CI, 1.02–4.80; OR = 2.81, 95% CI, 1.39–5.65, respectively). Our study firstly provides the evidence that paternal PCP exposure, maternal 4-n-OP and alkylphenol(s) exposure are associated with spontaneous abortion in humans.     

浅论环境影响评价在油田环境管理中的作用

新疆地区的环境较为敏感,油气田开发对环境的影响较大,围绕着油气田开发所开展的各项活动必须严格执行环境影响评价。文章介绍油气田开发环境影响特点,环境影响评价工作中存在的问题。加强油田环境管理的措施为:实施战略和区域环境影响评价,在可行性研究报告审查前提出环境保护建议,在设计阶段严格执行环评中提出的环境保护措施,严格执行HSE环境管理体系,建立和完善回顾性环境影响评价制度,制定新疆油田建设项目环境保护管理方面的规定。     

膜吸收法净化低浓度甲醛和氨气简

基于膜吸收技术自制双层平板式膜吸收器，搭建净化低浓度甲醛和氨气污染模拟系统，考察不同膜结构参数、进气流量、吸收剂流量等因素对其净化效果的影响。结果表明，聚偏氟乙烯PVDF对低浓度甲醛和氨气的净化效率高于聚四氟乙烯PTFE。对同一材质膜，随着膜孔隙率的增大，甲醛和氨气的净化率呈上升趋势。随着进气流量的增加，甲醛和氨气的净化效率降低；而吸收剂流量对其净化效率影响不大。对于所有实验条件，平均膜孔径为0.22 μm的PVDF 4^#在进气流量u_g=120 L/h时，甲醛和氨气的净化效率最高，分别达94.7%和96.3%。     

Effects of Preparation Parameters on Properties of Soy Protein-Based Fiberboard

The effects of manufacturing parameters on mechanical properties of medium density fibreboard (MDF) bonded with modified soy protein-based glue were studied to find an appropriate manufacture technology. Physical properties of MDF made with different amount of wax emulsion were measured. Results indicated that water repellent had no obvious influence on physical properties of soy protein-based MDF boards. The fiberboards bonded with soy protein-based glue showed stronger water resistance properties than those bonded with urea–formaldehyde (UF) resins. Furthermore, the soy protein-based MDF boards had good quality [25.2% 24 h soak thickness swell (TS), 29.9 MPa modulus of rupture (MOR), 3130 MPa modulus of elasticity (MOE)], which met requirements of Chinese national standard. Practical processing parameters were obtained by orthogonal experiment, i.e., glue content 8.0%, hot-press temperature 200 °C, and hot-press time 150 s.     

羧酸盐型双子表面活性剂的合成及性能研究

以月桂酰氯、乙二胺与丁二酸酐为原料合成了一种羧酸盐型双子(gemini)表面活性剂。采用IR、1 HNMR对中间产物和目标产物进行结构表征,并考察了合成所得羧酸盐型gemini表面活性剂的表面活性。结果表明:合成产物即为目标产物。合成产物的临界胶束浓度为0.027mmol/L,比普通单链表面活性剂低2～3个数量级,表面张力最低可降至29.5mN/m。     

CAF涡凹气浮处理含油废水的中试试验研究

针对石化公司污水成分复杂,COD和油含量较高,还含有较多的硫化物、挥发酚和氨氮(NH3-N)等情况,选用一种新型的气浮设备CAF涡凹气浮系统对该含油废水进行了预处理中试试验。试验结果表明CAF处理石化含油废水效果明显,气浮处理效果好,出水油在10 mg/L以下,去除率高达95%,且CAF气浮的电耗小、占地面积小、操作管理和维修非常简便。采用CAF设备,占地面积可节省70%～80%,每年可节约电费50～60万元(按1000 m3/h,0.8元/kW·h),操作使用也极其简单,具有可观的经济效益。     

灾害对国民经济影响的定量分析模型及其应用

自然灾害对国民经济和人民生活能造成巨大的损失 ,因此 ,研究灾害对国民经济的影响具有重要的意义。灾害系统是一个十分复杂的系统 ,直接建立灾害对国民经济影响的定量分析模型比较困难。本文基于投入产出方法 ,讨论了直接和间接经济损失在投入 -产出表中的表达方式 ,建立了灾害损失评估的定量分析模型 ,并以农业为例 ,分析了自然灾害造成的农业总产值损失对整个经济系统的影响。