Concentrations,atmospheric partitioning,and air–water/soil surface exchange of polychlorinated dibenzo-p-dioxin and dibenzofuran along the upper reaches of the Haihe River basin,North China

Polychlorinated dibenzo-p-dioxin and dibenzofuran (PCDD/PCDF) were overall measured and compared in ambient air, water, soils, and sediments along the upper reaches of the Haihe River of North China, so as to evaluate their concentrations, profiles, and to understand the processes of gas–particle partitioning and air–water/soil exchange. The following results were obtained: (1) The average concentrations (toxic equivalents, TEQs) of 2,3,7,8-PCDD/PCDF in air, water, sediment, and soil samples were 4,855 fg/m³, 9.5 pg/L, 99.2 pg/g dry weight (dw), and 56.4 pg/g (203 fg TEQ/m³, 0.46 pg TEQ/L, 2.2 pg TEQ/g dw, and 1.3 pg TEQ/g, respectively), respectively. (2) Although OCDF, 1,2,3,4,6,7,8-HpCDF, OCDD, and 1,2,3,4,6,7,8-HpCDD were the dominant congeners among four environmental sinks, obvious discrepancies of these congener and homologue patterns of PCDD/PCDF were observed still. (3) Significant linear correlations for PCDD/PCDF were observed between the gas–particle partition coefficient (K _p) and the subcooled liquid vapor pressure (P _L ⁰) and octanol–air partition coefficient (K _oa). (4) Fugacity fraction values of air–water exchange indicated that most of PCDD/PCDF homologues were dominated by net volatilization from water into air. The low-chlorinated PCDD/PCDF (tetra- to hexa-) presented a strong net volatilization from the soil into air, while high-chlorinated PCDD/PCDF (hepta- to octa-) were mainly close to equilibrium for air–soil exchange.     

镍渣的重金属浸出特性

在分析镍渣的矿物相组成和重金属元素含量的基础上,鉴定了镍渣样品的浸出毒性,并考察了pH、液固比和浸出时间等条件对镍渣样中铬、铅、铜和锌等重金属浸出特性的影响。结果表明,镍渣中的重金属总量约为渣样的0.9%,且铬、铜和锌的含量较高,需进行安全管理。实验所用镍渣样品为第Ⅰ类一般工业固体废物。在强酸条件下镍渣中重金属浸出浓度较大,pH3后浸出浓度显著降低;液固比40 L/kg时,镍渣中重金属不断溶出,液固比40 L/kg后,浸出达到饱和,浸出浓度趋于平衡;随着浸出时间的增加,重金属离子的浸出浓度先增加后减少,但由于各重金属性质不同,各重金属达到最大浸出浓度的时间不同。     

优势菌种对餐厨垃圾高温好氧消化的促进

为研究优势菌种对餐厨垃圾高温好氧消化(TAD)的促进作用,本研究通过淀粉水解、油脂降解及明胶液化等生化实验,从餐厨垃圾中筛选出若干对其主要成分具有显著降解效果的优势菌种。通过对样品水溶性TOC(TOCw)、水溶性凯氏氮(KNw)、水溶性C/N(KNw)、pH以及含水率等指标的分析,考察优势菌种对餐厨TAD的促进作用。研究表明,优势菌种制剂最优添加量为1%。在此剂量下,好氧消化60 h,TOCw由8.53%降低为2.49%,C/Nw由18.71降低至6.14,以上指标说明加入优势菌种可加速TAD反应。添加量1%样本的水溶性凯氏氮和pH在反应48 h后开始回升,而未添加生物制剂的样本相关参数回升时间需96 h以上,由此推断优势菌种对TAD的促进机制是加快了蛋白质等大分子有机物的降解速度。     

基于环境一号卫星的PM2.5浓度遥感反演研究

2014年12月29—30日,青岛市发生了一次空气污染过程,利用环境一号卫星CCD遥感影像数据和实测PM_(2.5)浓度数据,分析了该过程前后5 d的实测PM_(2.5)浓度与环境一号卫星CCD遥感影像的DN值之间的相关性,分别按日期和区域建立了反演模型。结果表明,按日期拟合反演模型相关系数为0.02~0.51,按区域拟合反演模型相关系数为0.01~0.80,总体来说,区域拟合结果较好。     

Adsorptive conversion of nitrogen dioxide from etching vent gases over activated carbon

Some metal etching operations emit limited flow rates of waste gases with reddish-brown NO₂ fume, which may cause visual and acidic-odor complaints, as well as negative health effects. In this study, tests were performed by passing caustic-treated waste gases vented from Al-etching operations through columns packed either with virgin or regenerated granular activated carbon (GAC) to test their adsorptive conversion performance of NO₂ in the gases. The gases contained 5–55 ppm NO₂ and acetic and nitric acids of below 3 ppm. Exhausted carbon was regenerated by scrubbing it with caustic solution and water, and dried for further adsorption tests. Results indicate that with an (empty bed residence time (EBRT) of 0.15 sec for the gas through the GAC-packed space, around 60% of the influent NO₂ of 54 ppm could be removed, and 47% of the removed NO₂ was converted by and desorbed from the carbon as NO. GAC used in the present study could be regenerated at least twice to restore its capacity for NO₂ adsorption. Within EBRTs of 0.076–0.18 sec, the adsorptive conversion capacity was linearly varied with EBRT. In practice, with an EBRT of 0.20 sec, a conversion capacity of 0.80 kg NO₂ (kg GAC)^?1 with an influent NO₂ of 40 ppm can be used as a basis for system design.

Implications: Some metal etching operations emit waste gases with reddish-brown (yellow when diluted) NO₂ fume which may cause visual and acidic-odor complaints, as well as negative health effects. This study provides a simple process for the adsorptive conversion of NO₂ in caustic-treated waste gases vented from metal-etching operations through a GAC column. With an EBRT of 0.20 sec, a conversion capacity of 0.80 kg NO₂ (kg GAC)^?1 with an influent NO₂ of 40 ppm can be used as a basis for system design. Saturated GAC can be regenerated at least twice by simply scrubbing it with aqueous caustic solution.     

道路交通噪声预测声源简化研究

为了分析《环境影响评价技术导则声环境》(HJ 2.4—2009)中将道路声源简化为1条位于道路中心线处的线声源与按照车道数简化为多条线声源之间的误差,针对不同宽度的道路,推导了多条线声源与1条线声源在接收点噪声影响的误差计算公式,并基于Predictor-lima预测软件预测和现场噪声衰减规律实测进行了验证。研究结果表明,对于接收点到道路边缘的距离大于道路宽度的情况,可简化为1条线声源;对于接收点到道路边缘的距离小于道路宽度的情况,应按照车道数简化为多条线声源。     

阿什河底栖动物群落特征及影响因子

阿什河作为松花江的一级支流,全境包含了从Ⅰ类到劣Ⅴ类的各种类型水质。通过对阿什河沿线底栖动物群落构成进行调查,结合典范对应性分析(CCA)对底栖动物群落与环境因子进行相关性分析得出结论,溶解氧和高锰酸盐指数为研究区域内底栖动物群落构成的主要限制因子。为分析不同水质条件下底栖动物种群变化成因和从生物学角度提出阿什河治理方法提供技术依据。     

环境管理战略转型研究综述

由于经济社会的发展伴随的环境问题越来越复杂,资源相对不足、环境容量有限越来越突出,环境管理转型问题引起越来越多的国内外学者关注。所谓环境管理转型,是指环境管理思维、策略和方式的转变,是以环境质量为目标导向,从被动应对向主动防控的转变。本文通过文献梳理的方法,综述了国内外学术界对于环境管理战略进行的多角度探讨。通过综述发现,国外学者主要注重环境管理理论研究,如环境管理的模型研究和不同环境管理战略的研究,且国外学者在研究不同环境管理战略时,研究对象多为微观层面的企业组织;而我国学者的研究则主要集中在宏观层面,即从国家的角度来探讨环境管理战略如何完成转型,从而促进我国经济社会的良性发展。现有的国内外研究是环境管理战略相关理论发展和实践推行的重要基础,在环境管理战略研究领域,本文认为还有一些问题需要进一步研究:一是环境管理的转型不仅需要宏观层面的统筹、微观方面的变革,也需要从中观层面来推进,所以中观层面的环境管理研究同样具有重要的现实意义。二是环境管理的转型不仅需要法律手段的支撑、经济手段的配置,也需要公民环保意识的觉醒,所以关于公民环保意识层面的研究也需要加强。     

基于主成分分析-多元线性回归的松花江水体中多环芳烃源解析

对松花江全流域14个监测断面的16种美国环保局优先控制的多环芳烃(PAHs)的主要来源及其贡献率应用主成分因子分析-多元线性回归模型(PCA-MLR)进行了来源解析。结果表明:松花江全流域为化石和石油燃料的复合PAHs污染,水体环境中PAHs首要污染源为化石燃料燃烧和交通污染,合计贡献率为63.1%,第二大污染源为工业和民用燃煤污染,合计贡献率为36.9%,沿江的石化、石油基地、大型焦化厂、电厂都是PAHs的主要来源。     

多氯联苯Aroclor系列的弗罗里硅土小柱淋洗条件

使用商品化弗罗里硅土小柱对废水中的Aroclor进行净化。比较了不同极性洗脱溶剂和洗脱体积下弗罗里硅土小柱的净化效果。采用1 g/6 mL的弗罗里硅土小柱净化时，洗脱液体积大于8.0 mL，洗脱完全，未有目标物质被检出。淋洗溶剂的极性改变，对初始洗脱体积（0~3.0 mL）的洗脱效率会产生一定影响。随着极性的增加，目标物的回收率随之增加，但是共流出的干扰物也随之增加。