Geochemical fractionation of trace elements in sediments of Hugli River (Ganges) and Sundarban wetland (West Bengal, India)

A sequential extraction procedure was carried out to determinate the concentrations of 11 elements (Al, As, Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, Zn) in different geochemical phases of sediments collected along the Hugli (Ganges) River Estuary and in the Sundarban mangrove wetland, eastern coastal part of India. The chemical speciation of elements was determined using the three-step sequential extraction procedure described by the European Community Bureau of Reference. Total metal concentration was determined using a microwave-assisted acid digestion procedure. Metal concentrations were near the background level except for As for which a moderate pollution can be hypothesized. The mobility order of the metals was: Cd?>?Mn?>?Cu?>?Zn?>?As?>?Co?>?Pb?>?Ni?>?Fe?>?Cr?>?Al. The highest percentage of Cd (>60%) was found in the most labile phase. Residual fraction was prevailing for Fe, Cr and Al, while Pb was mainly associated with the reducible fraction. Data were compared with Sediment Quality Guidelines to estimate the relationship between element concentrations and adverse biological effects on benthic community, finding the possibility of some toxic effects due to the presence of As in the entire studied area and Cd, only in Calcutta.     

Surfactant enhanced pyrene degradation in the rhizosphere of tall fescue (Festuca arundinacea)

Environmental Science and Pollution Research - The present study was conducted to evaluate the effect of two non ionic surfactants (Tween 80 and Triton X-100), a biosurfactant (Lecithin), and...     

Feasibility of the hydrogen sulfide test for the assessment of drinking water quality in post-earthquake Haiti

In 2010, a magnitude 7.0 earthquake struck Haiti, severely damaging the drinking and wastewater infrastructure and leaving millions homeless. Compounding this problem, the introduction of Vibrio cholerae resulted in a massive cholera outbreak that infected over 700,000 people and threatened the safety of Haiti’s drinking water. To mitigate this public health crisis, non-government organizations installed thousands of wells to provide communities with safe drinking water. However, despite increased access, Haiti currently lacks the monitoring capacity to assure the microbial safety of any of its water resources. For these reasons, this study was designed to assess the feasibility of using a simple, low-cost method to detect indicators of fecal contamination of drinking water that could be implemented at the community level. Water samples from 358 sources of drinking water in the Léogâne flood basin were screened with a commercially available hydrogen sulfide test and a standard membrane method for the enumeration of thermotolerant coliforms. When compared with the gold standard method, the hydrogen sulfide test had a sensitivity of 65 % and a specificity of 93 %. While the sensitivity of the assay increased at higher fecal coliform concentrations, it never exceeded 88 %, even with fecal coliform concentrations greater than 100 colony-forming units per 100 ml. While its simplicity makes the hydrogen sulfide test attractive for assessing water quality in low-resource settings, the low sensitivity raises concerns about its use as the sole indicator of the presence or absence of fecal coliforms in individual or community water sources.     

Development of Anticorrosive Poly(Ether-Urethane) Amide Coatings from Linseed Oil: A Sustainable Resource

Polyetheramide(PEtA) resin was synthesized by the condensation polymerization of N,N-bis(2-hydroxy ethyl) linseed oil fatty amide diol (HELA) with resorcinol. It was further treated with different percentage of toluylene 2-4-diisocyanate (TDI) to obtain the urethane modified polyetheramide resins (UPEtA). The structural elucidation of PEtA and urethane modified polyetheramide(UPEtA) were carried out by FT-IR, ¹H-NMR and ¹³C-NMR spectroscopic techniques. These analyses confirm the formation of PEtA and UPEtA. Physico-chemical and physico-mechanical analysis were performed by standard laboratory methods. The resin composition UPEtA-24 showed best physico-mechanical properties with scratch hardness 2.0 kg, impact resistance 150 lb/in. and good bending ability. The thermal stability and curing behavior of polymers were respectively studied by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). Thermal analysis shows that these coatings can be used safely upto 190 °C. The coatings of UPEtA resins were prepared on mild steel strips. The anticorrosive behavior of UPEtA coatings were investigated in acid, alkali, water and xylene. All the coatings exhibit good chemical resistance performance in acid, alkali, saline and organic solvents, while the resin UPEtA-24 shows the best performance.     

Optimisation of rainwater tank design from large roofs: A case study in Melbourne, Australia

Rainwater tanks for larger roof areas need optimisation of tank size, which is often not carried out before installation of these tanks. This paper presents a case study of rainwater tank evaluation and design for large roof areas, located in Melbourne, Australia, based on observed daily rainfall data representing three different climatic regimes (i.e. dry average, and wet years). With the aim of developing a comprehensive Decision Support Tool for the performance analysis and design of rainwater tanks, a simple spreadsheet based daily water balance model is developed using daily rainfall data, contributing roof area, rainfall loss factor, available storage volume, tank overflow and irrigation water demand. In this case study, two (185 m³ and 110 m³) underground rainwater tanks are considered. Using the developed model, effectiveness of each tank under different climatic scenarios are assessed. The analysis shows that both the tanks are quite effective in wet and average years, however less effective in dry years. A payback period analysis of the tanks is preformed which reveals that the total construction cost of the tanks can be recovered within 15-21 years time depending on tank size, climatic conditions and future water price increase rates. For the tanks, a relationship between water price increase rates and payback periods is developed. The study highlights the need for detailed optimisation and financial analysis for large rainwater tanks to maximise the benefits.     

The environmental Kuznets curve hypothesis for Bangladesh: the importance of natural gas,liquefied petroleum gas,and hydropower consumption

Environmental Science and Pollution Research - Mitigating environmental pollution has become a global agenda keeping the sustainability of socioeconomic and environmental development into...     

The management of Industry 4.0 technologies and environmental assets for optimal performance of industrial firms in Malaysia

Environmental Science and Pollution Research - The integration of Industry 4.0 (I4.0) has emerged as an innovative paradigm for industrial firms contemplating environmental and economic issues....     

Life-cycle assessment of flash pyrolysis of wood waste

This work analyzes a process known as flash pyrolysis, which produces bio fuels using biomass for power generation. A life-cycle assessment of flash pyrolysis of wood waste was conducted to study whether a flash pyrolysis plant set up locally would be environmentally friendly. The results obtained show that the process of flash pyrolysis of wood waste is in fact environmentally friendly, and the process has little contribution to the environment. However, efforts still have to be made to address the global warming potential issue. Continuous research and developments must be carried out to further reduce the global warming potential of the flash pyrolysis.     

Organochlorine,PCB, PAH,and metal concentrations in eggs of loggerhead sea turtles (Caretta caretta) from northwest Florida,USA

Abstract

Composite samples of unhatched and physically unaltered loggerhead sea turtle, Caretta caretta, eggs collected from 20 nests along northwest Florida were analyzed for organochlorine pesticides (OCPs), polychlorinated biphenyls (PCBs), polycyclic aromatic hydrocarbons (PAHs), and metals. Chemical analyses revealed that turtle eggs contained detectable amounts of metals, PAHs, and PCBs. Only one OCP, p, p'‐DDD, was detected, and its presence was restricted to eggs from two nesting sites. None of the PCB concentrations exceeded the Food and Drug Administration's (FDA) action limit. Concentrations of dioxin‐like PCB congeners, 105, 118, and 126, and total PCBs were also detected and are contributors to the toxic burden of loggerhead sea turtle eggs. Concentrations of PAHs, 1,2,5,6‐dibenzanthracene, 1‐methyl naphthalene, Cl‐naphthalene and naphthalene were variable at nesting sites. Comparison of mean metal burdens in eggs from different beaches suggested that no uniform geographic gradients exist. Presence of OCPs, PCBs, PAHs and metals and their additive or synergistic toxicity is a concern to loggerhead sea turtle eggs; however, additive or synergistic impacts for loggerhead sea turtles are largely undocumented.