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Jesús R. Rodríguez-Núñez Tomás J. Madera-Santana Dalia I. Sánchez-Machado Jaime López-Cervantes Herlinda Soto Valdez 《Journal of Polymers and the Environment》2014,22(1):41-51
The addition of plasticizers to biopolymer films is a good method for improving their physicochemical properties. The aim of this study was to evaluate the effect of chitosan (CHI) blended with two hydrophilic plasticizers glycerol (GLY) and sorbitol (SOR), at two concentrations (20 and 40 wt%) on their mechanical, thermal, barrier, structural, morphological and antimicrobial properties. The chitosan was prepared through the alkaline deacetylation of chitin obtained from fermented lactic from shrimp heads. The obtained chitosan had a degree of deacetylation (DA) of 84 ± 2.7 and a molecular weight of 136 kDa, which indicated that a good film had formed. The films composed of CHI and GLY (20 wt%) exhibited the best mechanical properties compared to the neat chitosan film. The percentage of elongation at break increase to over 700 % in the films that contained 40 % GLY, and these films also exhibited the highest values for the water vapor transmission rate (WVTR) of 79.6 ± 1.9 g m2 h?1 and a yellow color (b o = 17.9 ± 2.0) compared to the neat chitosan films (b o = 8.8 ± 0.8). For the structural properties, the Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction analyses revealed an interaction in the acetamide group and changes in the crystallinity of plasticized films. The scanning electron micrographs revealed that all formulations of the chitosan films were smooth, and that they did not contain aggregations, pores or microphase separation. The thermal analysis using differential scanning calorimetry (DSC) revealed a glass transition temperature (Tg) of 130 °C for neat chitosan film, but the addition of SOR or GLY elicited a decrease in the temperature of the peak (120 °C). In addition, the antimicrobial activity of the chitosan films was evaluated against Listeria monocytogenes, and reached a reduction of 2 log after 24 h. The plasticizer concentration of 20 % GLY is sufficient for obtaining flexible chitosan films with good mechanical properties, and it could serve as an alternative as a packaging material to reduce environmental problems associated with synthetic packaging films. 相似文献
13.
S. S. Morales-García P. F. Rodríguez-Espinosa M. P. Jonathan M. Navarrete-López M. A. Herrera-García N. P. Muñoz-Sevilla 《Environmental monitoring and assessment》2014,186(1):55-67
Forty-eight air-filter samples (PM10) were analysed to identify the concentration level of partially leached metals (PLMs; As, Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb and V) from Puebla City, México. Samples were collected during 2008 from four monitoring sites: (1) Tecnológico (TEC), (2) Ninfas (NIN), (3) Hermanos Serdán (HS) and (4) Agua Santa (AS). The results indicate that in TEC, As (avg. 424 ng m?3), V (avg. 19.2 ng m?3), Fe (avg. 1,202 ng m?3), Cu (avg. 86.6 ng m?3), Cr (41.9 ng m?3) and Ni (18.6 ng m?3) are on the higher side than other populated regions around the world. The enrichment of PLMs is due to the industrial complexes generating huge dust particles involving various operations. The results are supported by the correlation of metals (Mn, Cd and Co) with Fe indicating its anthropogenic origin and likewise, As with Cd, Co, Fe, Mn, Pb and V. The separate cluster of As, Fe and Mn clearly signifies that it is due to continuous eruption of fumaroles from the active volcano Popocatépetl in the region. 相似文献
14.
Stephanie C. Payne Mindy E. Bergman Jennifer M. Rodríguez Jeremy M. Beus Jaime B. Henning 《Journal of Loss Prevention in the Process Industries》2010,23(6):806-812
In order to evaluate the leading and lagging effects of process safety climate on incidents, we correlated safety climate survey data with organizational safety records from before and after the survey time period. We obtained data from a large, multinational organization with manufacturing operations involving a number of complex processes, chemicals, and hazardous substances. A total of 7728 employees from 62 sites responded to a safety climate survey in 2007. Individual responses were aggregated to the site-level and matched to site-level organizational records of process safety incidents 1 year before and 1 year after survey administration. Employees’ perceptions of good routine housekeeping were significantly related to environmental impact incidents as both a leading and a lagging indicator, as well as fires/explosions and property damage outcomes. Employees’ perceptions of systems to prevent backlogs and the extent to which health and safety problems are promptly corrected were also related to environmental releases and fires/explosions. Implications for process safety climate research, organizational survey strategies, and organizational climate change are discussed. 相似文献
15.
Paisio CE Talano MA González PS Busto VD Talou JR Agostini E 《Environmental science and pollution research international》2012,19(8):3430-3439
Introduction
Wastewater derived from leather production may contain phenols, which are highly toxic, and their degradation could be possible through bioremediation technologies.Materials, methods and results
In the present work, microbial degradation of phenol was studied using a tolerant bacterial strain, named CS1, isolated from tannery sediments. This strain was able to survive in the presence of phenol at concentrations of up to 1,000?mg/L. On the basis of morphological and biochemical properties, 16S rRNA gene sequencing, and phylogenetic analysis, the isolated strain was identified as Rhodococcus sp. Phenol removal was evaluated at a lab-scale in Erlenmeyer flasks and at a bioreactor scale in a stirred tank reactor. Rhodococcus sp. CS1 was able to completely remove phenol in a range of 200 to 1,000?mg/L in mineral medium at 30 ± 2?°C and pH 7 as optimal conditions. In the stirred tank bioreactor, we studied the effect of some parameters, such as agitation (200?C600 rpm) and aeration (1?C3?vvm), on growth and phenol removal efficiency. Faster phenol biodegradation was obtained in the bioreactor than in Erlenmeyer flasks, and maximum phenol removal was achieved at 400?rpm and 1 vvm in only 12?h. Furthermore, Rhodococcus sp. CS1 strain was able to grow and completely degrade phenols from tannery effluents after 9?h of incubation.Conclusion
Based on these results, Rhodococcus sp. CS1 could be an appropriate microorganism for bioremediation of tannery effluents or other phenol-containing wastewaters. 相似文献16.
Fernanda Menezes França Teresa C. Brazil De Paiva Adriana S. Marcantônio Patrícia C. Teixeira Cláudia Maris Ferreira 《Journal of environmental science and health. Part. B》2013,48(6):406-410
The objective of this study was to determine the acute toxicity of some pesticides used in irrigated rice farming to Lithobates catesbeianus tadpoles. The LC50-96h for commercial formulations containing bentazon, penoxsulam, vegetable oil, permethrin and carbofuran, separately and their mixtures, were determined at the proportions commonly used in the field. The limits of risk concentrations of these products for the studied species were also established. The LC50-96h for tadpoles was 4,530 mg L?1 for bentazon; 7.52 mg L?1 for penoxsulam + 145.66 mg L?1 of vegetable oil; 81.57 mg L?1 for vegetable oil; 0.10 mg L?1 for permethrin; 29.90 mg L?1 for carbofuran (active ingredients), and 38.79 times the dose used in the field for the mixture of these products. The environmental risk was determined only for permethrin, and care should be taken when using the vegetable oil. 相似文献
17.
JOACHIM CLAUDET JOSÉ ANTONIO GARCÍA‐CHARTON PHILIPPE LENFANT 《Conservation biology》2011,25(1):105-114
Abstract: The links between species–environment relations and species’ responses to protection are unclear, but the objectives of marine protected areas (MPAs) are most likely to be achieved when those relations are known and inform MPA design. The components of a species’ habitat vary with the spatial resolution of the area considered. We characterized areas at two resolutions: 250 m2 (transect) and approximately 30,000 m2 (seascape). We considered three categories of environmental variables: substrate type, bottom complexity, and depth. We sought to determine at which resolution habitat characteristics were a better predictor of abundance and species composition of fishes and whether the relations with environmental variables at either resolution affected species’ responses to protection. Habitat features accounted for a larger proportion of spatial variation in species composition and abundances than differences in protection status. This spatial variation was explained best by habitat characteristics at the seascape level than at the transect level. Species’ responses to protected areas were specific to particular seascape characteristics, primarily depth, and bottom complexity. Our method may be useful for prioritizing marine areas for protection, designing MPAs, and monitoring their effectiveness. It identified areas that provided natural shelter, areas acting as buffer zones, and areas where fish species were most responsive to protection. The identification of such areas is necessary for cost‐effective establishment and monitoring of MPAs. 相似文献
18.
Sá Roberson Davis Rodríguez-Pérez Adriana Patricia Rodrigues-Silva Fernando de Paula Vinicius de Carvalho Soares Prola Liziê Daniela Tentler de Freitas Adriane Martins de Carvalho Karina Querne de Liz Marcus Vinicius 《Environmental science and pollution research international》2021,28(19):24180-24190
Environmental Science and Pollution Research - The photo-Fenton process was performed with four radiation settings to treat clinical analysis laboratory wastewater (CALWW) from a hospital, with the... 相似文献
19.
Gentaz Lucile Saheb Mandana Verney-Carron Aurélie Sessegolo Loryelle Chabas Anne Nuns Nicolas Remusat Laurent Gonzalez-Cano Adriana Fourdrin Chloé Mertz Jean-Didier 《Environmental science and pollution research international》2021,28(3):2810-2821
Environmental Science and Pollution Research - For a long time, limestone has been massively used in stone building and monuments because of its easy extraction and common presence in the... 相似文献
20.
Sánchez-Gavilán Irene Rufo Lourdes Rodríguez Nuria de la Fuente Vicenta 《Environmental science and pollution research international》2021,28(3):2719-2727
Environmental Science and Pollution Research - A complete survey is presented on the inorganic composition of the euhalophyte annual succulent species Salicornia patula (Chenopodiaceae), including... 相似文献