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71.
Al TA Banks V Loomer D Parker BL Ulrich Mayer K 《Journal of contaminant hydrology》2006,88(1-2):137-152
The potential for trace-metal contamination of aquifers as a side effect of In Situ Chemical Oxidation (ISCO) of chlorinated solvent contamination by KMnO(4) is investigated with column experiments. The experiments investigate metal mobility during in situ chemical oxidation of TCE by KMnO(4) under conditions where pH, flow rate, KMnO(4), TCE, and trace-metal concentrations were controlled. During ISCO, the injection of MnO(4) creates oxidizing conditions, and acidity released by the reactions causes a tendency toward low pH in aquifers. In order to evaluate the role of pH buffering on metal mobility, duplicate columns were constructed, one packed with pure silica sand, and one with a mixture of silica sand and calcite. Aqueous solutions of TCE and KMnO(4) (with 1 mg/L Cu, Pb, Zn, Mo, Ni, and Cr(VI)) were allowed to mix at the inlet to the columns. After the completion of the experiments, samples of Mn oxide were removed from the columns and analyzed by analytical scanning and transmission electron microscopy. In order to relate the results of the laboratory experiments to field settings, the analyses of Mn-oxide samples from the lab experiments were compared to samples of Mn oxide collected from a field-scale chemical-oxidation experiment that were also analyzed by analytical electron microscopy as well as time-of-flight secondary-ion mass spectroscopy. The pH ranged from 2.40 in the silica sand column to 6.25 in the calcite-containing column. The data indicate that aqueous Mo, Pb, Cu and Ni concentrations are attenuated almost completely within the columns. In contrast, Zn concentrations are not significantly attenuated and Cr(VI) is transported conservatively. The results indicate that within the range 2.40 to 6.25, metal mobility is not affected by pH. Comparison of analyses of Mn-oxide from the lab and field demonstrate that a variety of metals are sequestered from solution by Mn oxide. 相似文献
72.
The paper presents the application of thermal remote sensing for mapping hydrocarbon polluted sites. This has been achieved by mono-window algorithm for land surface temperature (LST) measurements, using multi-date band 6 data of Landsat Thematic Mapper (TM). The emissivity, transmittance and mean atmospheric temperature were used as critical factors to estimate LST. The changes in the surface emissivity due to oil pollution alter the apparent temperature, which was used as a recognition element to map out oil polluted surfaces. The LST contrast was successfully used to map spatial distribution of hydrocarbon pollution in the Burgan Oil field area of Kuwait. The methodology can be positively used to detect waste dumping, oil spills in oceans and ports, besides environmental management of oil pollution at or near the land surface. 相似文献
73.
Thirty N-acyl homoserine lactone (AHL) analogs with variable antibacterial activity and displaying inhibition of biofilm formation were selected to develop models for establishing three-dimensional quantitative structure-activity relationships (3D-QSAR). Comparative molecular field analysis (CoMFA) and comparative similarity indices analysis (CoMSIA) were carried out to determine the optimum structural requirements for selectivity and potency of quorum-sensing and bacterial biofilm inhibition. The best CoMFA model predicted a q2 value of 0.519 and an r2 value of 0.984 and revealed that electrostatic and steric properties play a significant role in potency and selectivity. The CoMSIA model predicted a q2 value of 0.411 and an r2 value of 0.938 based on a combination of steric, electrostatic, and hydrophobic effects. The analysis of the contour maps from each model provide insight into the structural requirements for increasing the activity of a compound. Consequently, manipulating the chemical and physical properties of substituted acyl groups on the homoserine lactone moiety can provide important information toward enhancing the antibacterial properties of the target chemical compound. 相似文献
74.
T. Al Austin W. F. Riddle R. Q. Landers 《Journal of the American Water Resources Association》1979,15(5):1265-1280
ABSTRACT: A flood control reservoir protects valuable developments on the downstream flood plain by storing flood waters and releasing them at a rate that will reduce the downstream damage. The water surface level of the flood pool behind the dam can fluctuate considerably during the occurrence of a large magnitude flood causing severe impacts on shoreline vegetation and water based recreation facilities located in the flood pool. A mathematical simulation model describing shoreline vegetative succession in response to flooding is presented. Plant species are grouped into ecologically similar compartments. Differential equations describing compartment intrinsic growth, intraspecies competition, interspecies competition, and other growth limiting factors are solved numerically. The model is used to evaluate the impacts of various operating policies on plant succession for a new reservoir in Central Iowa. 相似文献
75.
76.
Farwell AJ Vesely S Nero V Rodriguez H McCormack K Shah S Dixon DG Glick BR 《Environmental pollution (Barking, Essex : 1987)》2007,147(3):540-545
The growth of transgenic canola (Brassica napus) expressing a gene for the enzyme 1-aminocyclopropane-1-carboxylate (ACC) deaminase was compared to non-transformed canola exposed to flooding and elevated soil Ni concentration, in situ. In addition, the ability of the plant growth-promoting bacterium Pseudomonas putida UW4, which also expresses ACC deaminase, to facilitate the growth of non-transformed and transgenic canola under the above mentioned conditions was examined. Transgenic canola and/or canola treated with P. putida UW4 had greater shoot biomass compared to non-transformed canola under low flood-stress conditions. Under high flood-stress conditions, shoot biomass was reduced and Ni accumulation was increased in all instances relative to low flood-stress conditions. This is the first field study to document the increase in plant tolerance utilizing transgenic plants and plant growth-promoting bacteria exposed to multiple stressors. 相似文献
77.
Geochemical study of groundwater from a structurally deformed granitic terrain near Hyderabad (India) was carried out to understand
and evaluate the hydrogeochemical processes and quality of groundwater. Several trace elements (Fe, Mn, Be, Al, V, Cr, Co,
Ni, Cu, Zn, As, Sr, Mo, Cd, Sb, Ba, Pb, U) along with major ions and minor elements were precisely estimated in shallow and
drilled wells to know the suitability of water for drinking and irrigation purposes. Analytical data shows that pH and major
ion chemistry in dug wells and bore wells do not vary significantly, while some trace elements (Fe, Mn, Al, Be, Co, Pb, U
and Zn) vary in dug wells and bore wells, which can be attributed to differential mineral weathering and dissolution/precipitation
reactions along fractures/joints. Although the water is not potable, it was found to be suitable for irrigation with little
danger in the development of harmful level of exchangeable sodium. It is inferred that the chemical composition of the groundwater
in this region is likely to have its origin from silicate weathering reactions and dissolution/precipitation processes supported
by rainfall and groundwater flow. 相似文献
78.
Jamrah A Al-Futaisi A Prathapar S Harrasi AA 《Environmental monitoring and assessment》2008,137(1-3):315-327
This study aims to evaluate the potential of greywater availability in Muscat Governorate in the Sultanate of Oman, to establish
a methodology for greywater quantity estimation, to test greywater quality in order to assess reuse potential, and to examine
public acceptance for reuse.Total fresh water consumption and greywater generation from different household sources were measured
by water meters in five selected households during summer and winter. Additionally, a survey was designed and conducted in
five administrative areas of Muscat Governorate, with the objective of testing a methodology for estimating greywater generation
potential in these areas. Collected data were compared with that used by the Ministry of Housing, Electricity and Water, Sultanate
of Oman. The survey covered a total of 169 houses and 1,365 people. Greywater samples were collected and analyzed from showers,
laundries, kitchens and sinks in some of these households to determine their water quality parameters. Statistical analysis
results indicated that there is no significant variance in the total fresh water consumption between data used by the ministry
and those measured and estimated during this study, highlighting the applicability of the tested method. The study concluded
that the average per capita greywater generation rate is 151 Lpcd. Greywater production ranged from 80 to 83% of the total
fresh water consumption and most of the greywater is generated from showers. Further, 55 to 57% of the greywater generated
in a typical Omani household originated from the shower, 28 to 33% originated from the kitchen, 6 to 9% originated from laundry,
and 5 to 7% originated from sink, which constitutes approximately 81% of the total fresh water consumption. The physical,
chemical, and biological analyses of the grab samples revealed that greywater contains significant levels of suspended solids,
inorganic constituents, total organic carbon, chemical and biochemical oxygen demands, total Coliforms and Escherichia Coliform
bacteria. The public acceptance survey illustrated that approximately 76% of the respondents accepted the reuse of greywater
for gardening, 53% for car washing and 66% for toilet flushing. 相似文献
79.
Standardising and mapping open-source information for crisis regions: the case of post-conflict Iraq
Painting an accurate picture of the situation on the ground in countries in crisis is vital for the efficiency of humanitarian aid and reconstruction agencies. This study describes a method for standardising and mapping the plethora of open-source information. The test site for the study is post-conflict Iraq. Important information on aid distribution, reconstruction and security in Iraq can be derived from the reports of humanitarian aid agencies and the media, before being formatted, inserted into a database and mapped. The product is a visual, cartographic structure of otherwise random information, showing which organisations are working in the country, which thematic and geographic areas are being prioritized in the field, and which areas most frequently experience security events. This type of mapping not only highlights the overall working environment within different parts of the country, but it may also serve as a decision-making tool for donors and humanitarian aid agencies planning to deploy personnel. 相似文献
80.