Assessment of Uncertainties in Modelling Land Use Change with an Integrated Cellular Automata–Markov Chain Model

Environmental Modeling & Assessment - Uncertainty in future land use change modelling is crucial to study as it may result in varying spatial characteristics and features of the model. An...     

Utility of fuzzy cross-impact simulation in environmental assessment

Fuzzy cross-impact simulation is a qualitative technique, where interactions within a system are represented by a cross-impact matrix that includes linguistic elements. It can be used effectively to visualize dynamic evolution of a system. The utility of the fuzzy cross-impact simulation approach is: (1) in dealing with uncertainties in environment-development systems; (2) scoping cumulative effect assessment; and (3) integrating societal response structure in environment impact assessment. Use of the method is illustrated in a case concerning the textile industry in Indore, India. Consequences of policy alternatives for cleanup and pollution abatement are predicted in terms of environmental quality and quality of life, using the simulation model. The consequence analysis is used to arrive at preferred policy options.     

Tribal institutions and conservation of the bioculturally valuable ‘tasat’ (Arenga obtusifolia) tree in the eastern Himalaya

This study reports on the biocultural dimensions of the tasat (Arenga obtusifolia Griff.) tree and its conservation by various informal institutions of the Adi tribe of Arunachal Pradesh, India. The study included 240 Adi community members (120 men and 120 women) residing in 12 villages of the East Siang and Upper Siang districts of Arunachal Pradesh. The study was conducted using personal interviews and participatory methods. Results indicated that the stem of tasat is used as a traditional food during droughts and in preparing an ethnic beverage. Tasat is being conserved by the Adi tribe in various habitats. Plant populations of tasat were observed relatively higher in Upper Siang than the East Siang district. The study found differences in the status of biocultural knowledge between genders and different age groups. Kebang and reglep are two indigenous institutions of men and women, respectively, and play leading roles in sustaining tasat plants in various habitats. Women of the Upper Siang district still maintain a knowledge network for diffusing biocultural knowledge related to tasat, among others, through a barter system. Changing land use patterns in agriculture affects tasat conservation. The value addition for tasat based products, and rewarding women who conserve tasat, can enhance the sustainability of tasat based on biocultural knowledge and institutions.     

Synthesis and bioefficacy evaluation of new 3-substituted-3,4-dihydro-1,3-benzoxazines

A new series of 1, 3-Benzoxazines were synthesized, characterized (¹H NMR and ¹³C NMR) and evaluated for their pesticidal activity. Six new 3-alkyl-3, 4-dihydro-4-methyl-2H-1, 3-benzoxazines (1-6) were prepared by hydroxymethylation of secondary amines with formaldehyde in 65–68% yields. These compounds were screened for there IGR activity against Spodoptera litura and for antifungal fungal activity in vitro against Sclerotium rolfsii ITCC 6181 by poisoned food technique. Insect Growth Regulatory (IGR) activity against Spodoptera litura showed that compound 3-Nonyl-3,4-dihydro-4-methyl-2H-1,3-benzoxazines was most effective as IGR with larval GI₅₀ of 1.863 μ g/Insect. Compounds 3-Octyl-3,4-dihydro-4-methyl-2H-1,3-benzoxazines and 3-Decyl-3,4-dihydro-4-methyl-2H-1,3-benzoxazines were effective IGRs. Antifungal screening revealed that compound 3-Dodecyl-3, 4-dihydro-4-methyl-2H-1,3-benzoxazines, was highly effective against Sclerotium rolfsii with LC₅₀ value 31.7 mg L^?1 comparable with commercial fungicide Hexaconazole (LC₅₀ 1.27 mg L^?1). Also compounds 3-Nonyl-3, 4-dihydro-4-methyl-2H-1,3-benzoxazines and 3-Decyl-3,4-dihydro-4-methyl-2H-1,3-benzoxazines displayed promising fungitoxicity. The results described in this paper are promising and provides new array of synthetic chemicals to be utilized as pesticides.     

Chemical Approach to Study the Environmental Implications of Humic Acid and Gamma-Hch Interaction

Pesticide-humic interactions are known to have environmental significance in modifying the toxicity and mobility of agricultural chemicals. to test this, interaction between gamma-hexachlorocyclohexane (gamma-HCH) released from the sand coated with gamma-HCH and humic acid was investigated using thin layer chromatography and spectral studies such as UV (ultraviolet), IR (infrared), mass and FAB (fast atom bombardment) mass spectrometry. These studies revealed the evidence of loose interchelation between gamma-HCH and humic acid. the significance of the results in relation to detoxification of gamma-HCH in aquatic ecosystems are discussed.     

Management of disease complex caused by root knot nematode and root wilt fungus on pigeonpea through soil organically enriched with Vesicular Arbuscular Mycorrhiza,karanj (Pongamia pinnata) oilseed cake and farmyard manure

This investigation was undertaken to compare the percentage response of colonization and development of VA-Mycorrhiza (Glomus fasciculatum) on a number of pulse crops viz. cowpea, chickpea, soybean, pigeonpea and lentil under glasshouse conditions. Among the above-mentioned crops, pigeonpea exhibited the best performance and was selected for further studies. In this host the development and colonization percentage of G. fasciculatum was investigated under two separate substrates i. e. soil amended with FYM and karanj oilseed cake keeping a control treatment of field soil. A third treatment amended with karanj oilseed cake and farm yard manure (FYM) was also kept which responded best in terms of colonization percentage. This treatment showing improved plant health as well as integration with G. fasciculatum was selected as an ideal treatment for the management of disease complex caused by root knot nematode, Meloidogyne incognita and root wilt fungus, Fusarium udum on pigeonpea. Thus the treatment constituting FYM, karanj oilseed cake and VA-Mycorrhiza reduced the disease incidence caused by both maladies to a great extent with the most promising improvement in plant growth parameters as compared to all others. The present investigation, in addition to proposing an ideal eco-friendly treatment for the management of this disease complex also proposed an excellent medium for the proliferation of the obligate bio-protectant, G. fasciculatum.     

Bioreactors for treatment of VOCs and odours – A review

Volatile organic compounds (VOCs) and odorous compounds discharged into the environment create ecological and health hazards. In the recent past, biological waste air treatment processes using bioreactors have gained popularity in control of VOCs and odour, since they offer a cost effective and environment friendly alternative to conventional air pollution control technologies. This review provides an overview of the various bioreactors that are used in VOC and odour abatement, along with details on their configuration and design, mechanism of operation, insights into the microbial biodegradation process and future R&D needs in this area.     

Recovery of lithium and cobalt from waste lithium ion batteries of mobile phone

In view of the stringent environmental regulations, availability of limited natural resources and ever increasing need of alternative energy critical elements, an environmental eco-friendly leaching process is reported for the recovery of lithium and cobalt from the cathode active materials of spent lithium-ion batteries of mobile phones. The experiments were carried out to optimize the process parameters for the recovery of lithium and cobalt by varying the concentration of leachant, pulp density, reductant volume and temperature. Leaching with 2 M sulfuric acid with the addition of 5% H₂O₂ (v/v) at a pulp density of 100 g/L and 75 °C resulted in the recovery of 99.1% lithium and 70.0% cobalt in 60 min. H₂O₂ in sulfuric acid solution acts as an effective reducing agent, which enhance the percentage leaching of metals. Leaching kinetics of lithium in sulfuric acid fitted well to the chemical controlled reaction model i.e. 1 ? (1 ? X)^1/3 = k_ct. Leaching kinetics of cobalt fitted well to the model ‘ash diffusion control dense constant sizes spherical particles’ i.e. 1 ? 3(1 ? X)^2/3 + 2(1 ? X) = k_ct. Metals could subsequently be separated selectively from the leach liquor by solvent extraction process to produce their salts by crystallization process from the purified solution.     

Analysis of volatile organic compounds released during food decaying processes

A number of volatile organic compounds (VOCs) including acetone, methyl ethyl ketone, toluene, ethylbenzene, m,p-xylene, styrene, and o- xylene released during food decaying processes were measured from three types of decaying food samples (Kimchi (KC), fresh fish (FF), and salted fish (SF)). To begin with, all the food samples were contained in a 100-mL throwaway syringe. These samples were then analyzed sequentially for up to a 14-day period. The patterns of VOC release contrasted sharply between two types of fish (FF and SF) and KC samples. A comparison of data in terms of total VOC showed that the mean values for the two fish types were in the similar magnitude with 280 ± 579 (FF) and 504 ± 1,089 ppmC (SF), while that for KC was much lower with 16.4 ± 7.6 ppmC. There were strong variations in VOC emission patterns during the food decaying processes between fishes and KC that are characterized most sensitively by such component as styrene. The overall results of this study indicate that concentration levels of the VOCs differed significantly between the food types and with the extent of decaying levels through time.