Validation of the Digital Opacity Compliance System under Regulatory Enforcement Conditions

Abstract

U.S. Environmental Protection Agency (EPA) Emission Measurement Center in conjunction with EPA Regions VI and VIII, the state of Utah, and the U.S. Department of Defense have conducted a series of long-term pilot and field tests to determine the accuracy and reliability of a visible opacity monitoring system consisting of a conventional digital camera and a separate computer software application for plume opacity determination. This technology, known as the Digital Opacity Compliance System (DOCS), has been successfully demonstrated at EPA-sponsored Method-9 “smoke schools,” as well as at a number of government and commercially operated industrial facilities.

Results from the current DOCS regulatory pilot study demonstrated that, under regulatory enforcement conditions, the average difference in opacity measurement between the DOCS technology and EPA Reference Method 9 (Method 9) was 1.12%. This opacity difference, which was computed from the evaluation of 241 regulated air sources, was found to be statistically significant at the 99% confidence level. In evaluating only those sources for which a nonzero visible opacity level was recorded, the average difference in opacity measurement between the DOCS technology and Method 9 was 1.20%. These results suggest that the two opacity measurement methods are essentially equivalent when measuring the opacity of visible emissions.

Given the costs and technical limitations associated with use of Method 9, there is a recognized need to develop accurate, reproducible, and scientifically defensible alternatives to the use of human observers. The use of digital imaging/processing brings current technology to bear on this important regulatory issue. Digital technology offers increased accuracy, a permanent record of measurement events, lower costs, and a scientifically defensible approach for opacity determination.     

Derivation of ecotoxicity thresholds for uranium

Assessment of the risk of impact from most radionuclides is based on the total radiological dose rate to the organism of concern. However, for uranium (U) there can be greater risk from chemical toxicity than radiological toxicity (depending on the isotopic composition). Chemical ecotoxicity of U is dependent on several environmental parameters. The most important are carbonate content, because of the formation of soluble carbonate complexes, and divalent cation content (Ca++ and Mg++), because of their competitive interaction with the uranyl ion (UO2++). This study summarizes the literature available to set PNECs (predicted no-effect concentrations) for chemical toxicity of U to non-human biota. The corresponding radiological doses were estimated, and as expected chemical toxicity proved to be the greater concern. There were limited data from some types of biota; however, PNECs for the types of biota of interest were as follows: terrestrial plants--250 mg U kg(-1) dry soil; other soil biota--100 mg U kg(-1) dry soil; freshwater plants--0.005 mg U L(-1) water; freshwater invertebrates--0.005 mg U L(-1) water; freshwater benthos--100 mg U kg(-1) dry sediment; freshwater fish at water hardnesses of: <10 mg CaCO3 L(-1) (very soft water)--0.4 mg U L(-1) water; 10-100 mg CaCO3 L(-1) (soft water)--2.8 mg U L(-1) water; and >100 mg CaCO3 L(-1) (hard water)--23 mg U L(-1) water; or as a function of hardness--0.26 (hardness as mg CaCO3 L(-1); mammals--0.1 mg U kg(-1) body weight d(-1).     

Effect of soil characteristics on Cd uptake by the hyperaccumulator Thlaspi caerulescens

The influence of soil characteristics on the phytoremediation potential of Thlaspi caerulescens is not well understood. We investigated the effect of soil pH and Cd concentration on plant Cd uptake on one soil type, and the variation in Cd uptake using a range of field contaminated soils. On soils with total Cd concentrations of 0.6-3.7 mg kg(-1), T. caerulescens (the Ganges ecotype) produced greater biomass in the pH range 5.1-7.6 than at pH 4.4. The highest plant Cd concentration (236 mg kg(-1)) and Cd uptake (228 microg pot(-1)) were observed at pH 5.1. On soils with total Cd concentrations of 2.6-314.8 mg kg(-1), shoot Cd concentrations were 10.9-1,196 mg kg(-1). Multiple regression analysis indicated that higher Cd in soil, low pH (within the range of >5) and coarser texture were associated with higher Cd concentration and Cd uptake by T. caerulescens.     

建筑和建造部门:可持续的要素

在全球社会为实现真正的可持续性所做的努力中,建筑和建造业比其他产业部门的潜力可能都要大.     

Socio-environmental consideration of phosphorus flows in the urban sanitation chain of contrasting cities

Understanding how cities can transform organic waste into a valuable resource is critical to urban sustainability. The capture and recycling of phosphorus (P), and other essential nutrients, from human excreta is particularly important as an alternative organic fertilizer source for agriculture. However, the complex set of socio-environmental factors influencing urban human excreta management is not yet sufficiently integrated into sustainable P research. Here, we synthesize information about the pathways P can take through urban sanitation systems along with barriers and facilitators to P recycling across cities. We examine five case study cities by using a sanitation chains approach: Accra, Ghana; Buenos Aires, Argentina; Beijing, China; Baltimore, USA; and London, England. Our cross-city comparison shows that London and Baltimore recycle a larger percentage of P from human excreta back to agricultural lands than other cities, and that there is a large diversity in socio-environmental factors that affect the patterns of recycling observed across cities. Our research highlights conditions that may be “necessary but not sufficient” for P recycling, including access to capital resources. Path dependencies of large sanitation infrastructure investments in the Global North contrast with rapidly urbanizing cities in the Global South, which present opportunities for alternative sanitation development pathways. Understanding such city-specific social and environmental barriers to P recycling options could help address multiple interacting societal objectives related to sanitation and provide options for satisfying global agricultural nutrient demand.

     

The contribution of the anthropogenic impact of biomass utilization on ecological degradation: revisiting the G7 economies

Environmental Science and Pollution Research - The debate on ecological matters that relate to the biomass emissions nexus has gained prominence and different scholars have suggested various forms...