Navigating uneven terrain: The roles of political skill and LMX differentiation in prediction of work relationship quality and work outcomes

Drawing from social/political influence, leader–member exchange (LMX), and social comparison theories, the present two‐study investigation examines three levels of LMX differentiation (i.e., individual‐level, meso‐level, and group‐level LMX differentiation) and further tests a model of the joint effects of political skill and LMX differentiation on LMX, relative LMX, and employee work outcomes. In Study 1, we used data from 231 employees and found support for the interactive effect of political skill and individual perceptions of LMX differentiation on LMX quality. We also found partial support for the moderating role of individual‐level LMX differentiation on the indirect effects of political skill on self‐rated task performance and job satisfaction via LMX. In Study 2, we used data from 185 supervisor–subordinate dyads and examined both meso‐level and group‐level LMX differentiation via a multilevel moderated mediation model. Results supported the moderating role of group‐level LMX differentiation and group mean LMX on the indirect effects of political skill on supervisor‐rated task performance and contextual performance/citizenship behavior as well as job satisfaction via relative LMX. Overall, the results suggest that politically skilled employees reap the benefits of LMX differentiation, as they enjoy higher absolute LMX and relative (i.e., to their peers) LMX quality. Copyright © 2016 John Wiley & Sons, Ltd.     

The adsorption of short single-stranded DNA oligomers to mineral surfaces

We studied the adsorption of short single-stranded deoxyribonucleic acid (ssDNA) oligomers, of approximately 30 nucleotides (nt) in length, of varying sequence, adenine + guanine + cytosine (AGC) content, and propensity to form secondary structure, to equal surface area samples of olivine, pyrite, calcite, hematite, and rutile in 0.1 M NaCl, 0.05 M pH 8.1 KHCO₃ buffer. Although the mineral surfaces have widely varying points of zero charge, under these conditions they show remarkably similar adsorption of ssDNA regardless of oligomer characteristics. Mineral surfaces appear to accommodate ssDNA comparably, or ssDNA oligomers of this length are able to find binding sites of comparable strength and density due to their flexibility, despite the disparate surface properties of the different minerals. This may partially be due charge shielding by the ionic strength of the solutions tested, which are typical of many natural environments. These results may have some bearing on the adsorption and accumulation of biologically derived nucleic acids in sediments as well as the abiotic synthesis of nucleic acids before the origin of life.     

Incidence of thyroid disease following exposure to polybrominated biphenyls and polychlorinated biphenyls, Michigan, 1974-2006

Thyroid hormones, which influence body metabolism and development, could be affected by persistent organic pollutants. We sought to examine the relationship between polybrominated biphenyls (PBBs) and polychlorinated biphenyls (PCBs) and thyroid disease. We employed incidence density sampling to perform a nested case control analysis of the Michigan Long-Term PBB Cohort. Cohort members (n = 3333) were exposed to PBBs through contaminated cattle feed in 1973-1974 and to PCBs through daily life. Those with detectable serum PBB and PCB concentrations at enrollment were categorized into tertiles of PBB and PCB exposure. Case-patients were cohort members answering “Yes” to “Has a healthcare provider ever told you that you had a thyroid problem?” during follow-up interviews; control-patients were cohort members answering “No”. We used odds ratios (OR) with 95% confidence intervals (CI) to compare odds of thyroid disease by PBB and PCB exposure and by various risk factors. Total cumulative thyroid disease incidence after 33 years was 13.9% among women and 2.6% among men. After adjusting for body mass index, we found no statistically significant differences in odds of any type of thyroid disease among women or men with elevated PBB or PCB exposure. Compared to control-patients, women with thyroid disease had increased odds of being overweight/obese (OR = 2.82, 95% CI: 1.94-4.11) and developing infertility (OR = 1.71, 95% CI: 1.08-2.69), diabetes (OR = 1.61, 95% CI: 1.04-2.51), or arthritis (OR = 1.71, 95% CI: 1.18-2.50) during follow-up. Additional research should explore potential associations between PBBs/PCBs and thyroid disease among children exposed in utero.     

Model Evaluation of Dry Deposition to Vegetation for Volatile and Semi-Volatile Organic Compounds in a Multimedia Environment

Gas-phase atmospheric deposition wasevaluated in a screening level model of themultimedia environmental distribution of toxics(MEND-TOX). Algorithmic additions to MEND-TOXfor the estimation of gas-phase depositionvelocity over vegetated surfaces were analyzedusing recently published dry deposition fluxmeasurements for nitric acid. Model outputs arecompared to similar estimates from the NOAAmultilayer dry deposition model. Results of theevaluation indicate that MEND-TOX performs wellas a screening level model for the estimation ofgas-phase dry deposition velocity of nitric acidover soybeans. The present study expandsprevious laboratory results for organic speciesto include an inorganic species and open fieldand dry leaf, conditions.(On assignment to the National Exposure Research Laboratory, U.S. Environmental Protection Agency); (author for correspondence, e-mail     

Degradation of ethylenethiourea pesticide metabolite from water by photocatalytic processes

In this study, photocatalytic (photo-Fenton and H₂O₂/UV) and dark Fenton processes were used to remove ethylenethiourea (ETU) from water. The experiments were conducted in a photo-reactor with an 80 W mercury vapor lamp. The mineralization of ETU was determined by total organic carbon analysis, and ETU degradation was qualitatively monitored by the reduction of UV absorbance at 232 nm. A higher mineralization efficiency was obtained by using the photo-peroxidation process (UV/H₂O₂). Approximately 77% of ETU was mineralized within 120 min of the reaction using [H₂O₂]₀ = 400 mg L^?1. The photo-Fenton process mineralized 70% of the ETU with [H₂O₂]₀ = 800 mg L^?1 and [Fe²⁺] = 400 mg L^?1, and there is evidence that hydrogen peroxide was the limiting reagent in the reaction because it was rapidly consumed. Moreover, increasing the concentration of H₂O₂ from 800 mg L^?1 to 1200 mg L^?1 did not enhance the degradation of ETU. Kinetics studies revealed that the pseudo-second-order model best fit the experimental conditions. The k values for the UV/H₂O₂ and photo-Fenton processes were determined to be 6.2 × 10^?4 mg L^?1 min^?1 and 7.7 × 10^?4 mg L^?1 min^?1, respectively. The mineralization of ETU in the absence of hydrogen peroxide has led to the conclusion that ETU transformation products are susceptible to photolysis by UV light. These are promising results for further research. The processes that were investigated can be used to remove pesticide metabolites from drinking water sources and wastewater in developing countries.     

Tundra in the Rain: Differential Vegetation Responses to Three Years of Experimentally Doubled Summer Precipitation in Siberian Shrub and Swedish Bog Tundra

Precipitation amounts and patterns at high latitude sites have been predicted to change as a result of global climatic changes. We addressed vegetation responses to three years of experimentally increased summer precipitation in two previously unaddressed tundra types: Betula nana-dominated shrub tundra (northeast Siberia) and a dry Sphagnum fuscum-dominated bog (northern Sweden). Positive responses to approximately doubled ambient precipitation (an increase of 200 mm year^?1) were observed at the Siberian site, for B. nana (30 % larger length increments), Salix pulchra (leaf size and length increments) and Arctagrostis latifolia (leaf size and specific leaf area), but none were observed at the Swedish site. Total biomass production did not increase at either of the study sites. This study corroborates studies in other tundra vegetation types and shows that despite regional differences at the plant level, total tundra plant productivity is, at least at the short or medium term, largely irresponsive to experimentally increased summer precipitation.     

A Molecular Genetic Assessment of Mating-System Variation in a Naturally Bird-Pollinated Shrub: Contributions from Birds and Introduced Honeybees

Abstract: Introductions of European honeybees have occurred globally, potentially affecting the natural pollination ecology of many plants. Introduced honeybees are now the most frequent visitors to the inflorescences of the self-compatible, bird-pollinated Australian shrub Grevillea macleayana and may therefore be expected to have altered the mating system. To examine the degree to which birds continue to play a role in determining the mating system of G. macleayana in this disturbed system, we compared outcrossing rates in open-pollinated inflorescences with inflorescences from which birds had been selectively excluded. Outcrossing rates were estimated from the microsatellite genotypes of over 100 seeds per population in three populations. Outcrossing rates (  t ) in open-pollinated seeds were surprisingly low (0.062–0.225) and did not vary significantly among the three populations. Nevertheless, outcrossing was significantly lower when birds were excluded (data pooled from all populations). Two lines of evidence suggest that there are temporal fluctuations in outcrossing rate and hence that birds usually have a major effect on the mating system of G. macleayana . First, at one site, t was substantially lower than estimates from an earlier study (0.06 in 1995 cf. 0.85 in 1990). Second, fixation indices based on seeds were high in all populations (  >0.68), whereas values for the established plants ( parental generation) were much lower in two of the three populations (0.06–0.32). Our findings suggest that honeybee activity is so high that the contribution of birds to pollination in G. macleayana is sometimes relatively trivial.     

Linking Theory and Practice for Restoration of Step-Pool Streams

Step-pools sequences are increasingly used to restore stream channels. This increase corresponds to significant advances in theory for step-pools in recent years. The need for step-pools in stream restoration arises as urban development encroaches into steep terrain in response to population pressures, as stream channels in lower-gradient areas require stabilization due to hydrological alterations associated with land-use changes, and as step-pools are recognized for their potential to enhance stream habitats. Despite an increasingly voluminous literature and great demand for restoration using step-pool sequences, however, the link between theory and practice is limited. In this article, we present four unique cases of stream restoration using step-pools, including the evolution of the approaches, the project designs, and adjustments in the system following restoration. Baxter Creek in El Cerrito, California demonstrates an early application of artificial step-pools in which natural adjustments occurred toward geomorphic stability and ecological improvement. Restoration of East Alamo Creek in a large residential development near San Ramon, California illustrates an example of step-pools increasingly used in locations where such a channel form would not naturally occur. Construction of a step-pool channel in Karnowsky Creek within the Siuslaw National Forest, Oregon overcame constraints posed by access and the type and availability of materials; the placement of logs allowed natural scouring below steps. Dry Canyon Creek on the property of the Mountains Restoration Trust in Calabasas, California afforded a somewhat experimental approach to designing step-pools, allowing observation and learning in the future. These cases demonstrate how theories and relationships developed for step-pool sequences over the past two decades have been applied in real-world settings. The lessons from these examples enable us to develop considerations useful for deriving an appropriate course of design, approval, and construction of artificial step-pool systems. They also raise additional fundamental questions concerning appropriate strategies for restoration of step-pool streams. Outstanding challenges are highlighted as opportunities for continuing theoretical work.     

The co-occurrence of Down syndrome and autism spectrum disorder: is it because of additional genetic variations?

Individuals with Down syndrome (DS) are diagnosed with autism spectrum disorder (ASD) at a significantly higher frequency than the typical population. The differentiation of ASD symptoms from those of severe intellectual disability presents diagnostic challenges, which have led to more refined methods in the clinical evaluation of ASD in DS. These improved phenotypic characterization methods not only provide better diagnosis of ASD in DS, but may also be useful in elucidating the etiology of the increased prevalence of ASD in DS. Because all individuals with the classic presentation of DS have trisomy 21, it is possible that those with co-occurring DS and ASD may have additional genetic variants which can act as modifiers of the phenotype, leading to the development of ASD. © 2016 John Wiley & Sons, Ltd.