全文获取类型
收费全文 | 543篇 |
免费 | 4篇 |
国内免费 | 2篇 |
专业分类
安全科学 | 18篇 |
废物处理 | 26篇 |
环保管理 | 23篇 |
综合类 | 74篇 |
基础理论 | 92篇 |
环境理论 | 1篇 |
污染及防治 | 195篇 |
评价与监测 | 78篇 |
社会与环境 | 41篇 |
灾害及防治 | 1篇 |
出版年
2022年 | 13篇 |
2021年 | 10篇 |
2020年 | 4篇 |
2019年 | 15篇 |
2018年 | 16篇 |
2017年 | 21篇 |
2016年 | 27篇 |
2015年 | 12篇 |
2014年 | 32篇 |
2013年 | 88篇 |
2012年 | 28篇 |
2011年 | 35篇 |
2010年 | 28篇 |
2009年 | 18篇 |
2008年 | 20篇 |
2007年 | 26篇 |
2006年 | 27篇 |
2005年 | 16篇 |
2004年 | 11篇 |
2003年 | 10篇 |
2002年 | 5篇 |
2001年 | 4篇 |
2000年 | 7篇 |
1997年 | 2篇 |
1996年 | 2篇 |
1995年 | 2篇 |
1992年 | 3篇 |
1991年 | 3篇 |
1987年 | 2篇 |
1985年 | 2篇 |
1982年 | 4篇 |
1978年 | 1篇 |
1974年 | 1篇 |
1973年 | 2篇 |
1972年 | 2篇 |
1970年 | 3篇 |
1969年 | 2篇 |
1968年 | 2篇 |
1967年 | 1篇 |
1966年 | 2篇 |
1964年 | 2篇 |
1963年 | 1篇 |
1961年 | 2篇 |
1960年 | 4篇 |
1959年 | 5篇 |
1958年 | 5篇 |
1957年 | 3篇 |
1956年 | 6篇 |
1955年 | 1篇 |
1954年 | 2篇 |
排序方式: 共有549条查询结果,搜索用时 15 毫秒
31.
32.
Dragun Zrinka Filipović Marijić Vlatka Krasnići Nesrete Ramani Sheriban Valić Damir Rebok Katerina Kostov Vasil Jordanova Maja Erk Marijana 《Environmental science and pollution research international》2017,24(20):16917-16926
Environmental Science and Pollution Research - A lipid peroxidation product, malondialdehyde (MDA), was studied in Vardar chub (Squalius vardarensis Karaman) as an indicator of oxidative stress,... 相似文献
33.
Sorption-desorption behavior of imidacloprid in six soils collected from five coastal regions in Croatia at 20, 30 and 40°C was investigated using batch equilibrium technique. Isothermal data were applied to Freundlich, Langmuir and Temkin equations, and the thermodynamic parameters ΔH°, ΔG°, ΔS° were calculated. The sorption isotherm curves were non-linear and may be classified as L-type, suggesting a relatively high sorption capacity for imidacloprid. Our results showed that the K( sor ) ( F ) values decreased for all the tested soils as the temperature increased, indicating that the temperature strongly influences the sorption. Values of ΔG° were negative (-4.65 to -2.00 kJ/mol) indicating that at all experimental temperatures the interactions of imidacloprid with soils were spontaneous processes. The negative and small ΔH° values (-19.79 to -8.89 kJ/mol) were in the range of weak forces, such as H-bonds, consistent with interactions and partitioning of the imidacloprid molecules into soil organic matter. The ΔS° values followed the range of -57.12 to -14.51 J/molK, suggesting that imidacloprid molecules lose entropy during transition from the solution phase to soil surface. It was found that imidacloprid desorption from soil was concentration and temperature-dependent, i.e. at lower imidacloprid concentrations and temperature, lower desorption percentage occurred. Desorption studies revealed that hysteretic behavior under different temperature treatments existed, and it was more pronounced at 20°C in the soils with higher OC content. The study results emphasize the importance of thermodynamic parameters in controlling soil pesticide mobility in different geographical locations, seasons and greenhouse conditions. 相似文献
34.
Ivan S. Ristić Ljiljana Tanasić Ljubiša B. Nikolić Suzana M. Cakić Olivera Z. Ilić Radmila Ž. Radičević Jaroslava K. Budinski-Simendić 《Journal of Polymers and the Environment》2011,19(2):419-430
Different synthesis methods were applied to determine optimal conditions for polymerization of (3S)-cis-3,6-dimethyl-1,4-dioxane-2,5-dione (l-lactide), in order to obtain poly(l-lactide) (PLLA). Bulk polymerizations (in vacuum sealed vessel, high pressure reactor and in microwave field) were performed
with tin(II) 2-ethylhexanoate as the initiator. Synthesis in the vacuum sealed vessel was carried out at the temperature of
150 °C. To reduce the reaction time second polymerization process was carried out in the high pressure reactor at 100 °C and
at the pressure of 138 kPa. The third type of rapid synthesis was done in the microwave reactor at 100 °C, using frequency
of 2.45 GHz and power of 150 W at the temperature of 100 °C. The temperature in this method was controlled via infrared system
for in-bulk measuring. The solution polymerization (with trifluoromethanesulfonic acid as initiator) was possible even at
the temperature of 40 °C, yielding PLLA with narrow molecular weight distribution in a very short period of time (less than
6 h). The obtained polymers had the number-average molecular weights ranging from 43,000 to 178,000 g mol−1 (polydispersity index ranging from 1 to 3) according to the gel permeation chromatography measurements. The polymer structure
was characterized by Fourier transform infrared and NMR spectroscopy. Thermal properties of the obtained polymers were investigated
using thermogravimetry and differential scanning calorimetry. 相似文献
35.
Pavlova Ekaterina Pashkunova-Martic Irena Schaier Martin Petrova Emilia Gluhcheva Yordanka Dorkov Peter Helbich Thomas H. Keppler Bernhard Koellensperger Gunda Ivanova Juliana 《Environmental science and pollution research international》2021,28(6):6784-6795
Environmental Science and Pollution Research - In this study, we compare the effects of deferiprone (Def) and tetraethylammonium salt of salinomycinic acid (Sal) on lead (Pb)-induced toxicity in... 相似文献
36.
Evidence of rich microbial communities in the subsoil of a boreal acid sulphate soil conducive to greenhouse gas emissions 总被引:1,自引:0,他引:1
Miloslav Šimek Seija Virtanen Václav Krištůfek Asko Simojoki Markku Yli-Halla 《Agriculture, ecosystems & environment》2011,140(1-2):113-122
The largest areas of acid sulphate (AS) soils in Europe are located in Finland, where 67,000–130,000 ha of AS soils are in agricultural use. In addition to their acidifying effects on waters, AS soils might be a significant source of greenhouse gases. In this pilot research, carbon and nitrogen content and microbial activity were studied in an AS and a non-AS soil. Large carbon and nitrogen stocks (110 Mg Corg ha?1 and 15 Mg Ntot ha?1) as well as high substrate induced respiration (33 μg CO2–C g?1h?1) were found in the C horizons of the AS soil but not in the non-AS soil. High microbial activity in these horizons of the AS soil was further confirmed by the measurement of dehydrogenase activity, basal respiration, the numbers of culturable bacterial cells, and the ratio of culturable to total numbers of cells. Still, the denitrifying enzyme activity was very low in the anaerobic horizons of the AS soil, indicating the prevalence of microbes other than denitrifiers. We suspect that the microbial community originated with the genesis of AS soil and has been supported by the large stocks of accumulated carbon and mineral nitrogen in the C horizons. If these permanently water-saturated subsoils are exposed to oxygen and their microbial activity consequently increases, large carbon and nitrogen stocks are likely to be mobilised, resulting in increased emission of greenhouse gases. Additional studies of boreal AS soils are needed to assess their potential contribution to increases in greenhouse gas fluxes at the local, regional, and global scales. 相似文献
37.
Irena Šutiaková Natália Kovalkovičová Jaroslav Legáth Václav Šutiak 《Journal of environmental science and health. Part. B》2013,48(7):606-611
The fungicide tolylfluanid (N - dichlorofluoromethylthio-N′, N - dimethyl - N - p - tolylsulfamide), was investigated by cytokinesis-block micronucleus assay. Tolylfluanid at the lowest concentration (1 × 10? 6mol L? 1)did not influence significantly the frequency of micronuclei in sheep lymphocyte cultures in comparison with control (32.33 ± 3.51/1000 binucleated cells versus 30.33 ± 2.82/1000 binucleated cells in dimethylsulfoxide (DMSO) control, P = 0.44). Higher tolylfluanid concentrations (1 × 10? 4 and, 1 × 10? 5 mol L? 1) resulted in a significant dose-dependent increase in the number of micronuclei in comparison with control (74.00 ± 13.00/1000 binucleated cells and 52.67 ± 10.12/1000 binucleated cells versus 30.33 ± 2. 82/1000 binucleated cells in DMSO control, P = 0.005 and 0.02, respectively, ANOVA followed by Tukey test P < 0.05). Many of the treated cells also possessed multiple micronuclei. Tolylfluanid did not affect the nuclear division index at all treatment concentrations. Our in vitro results thus demonstrate that tolylfluanid had a significant genotoxic effect at only the highest concentration tested. 相似文献
38.
Ivana Potočnik Jelena Vukojević Mirjana Stajić Emil Rekanović Svetlana Milijašević Biljana Todorović 《Journal of environmental science and health. Part. B》2013,48(4):365-370
Twenty microfungal isolates were collected from diseased fruiting bodies of Agaricus bisporus sampled from Serbian mushroom farms during 2003–2007. Based on morphological characteristics and pathogenicity tests, the isolates were identified as Cladobotryum dendroides. The isolates of C. dendroides and A. bisporusF56 and U3 were tested for sensitivity to several selected fungicides in vitro. C. dendroides isolates were found to be more sensitive to prochloraz manganese and flusilazole + carbendazim than to the other fungicides tested (EC50 values were 0.09 and 0.11 mg L? 1, respectively) and weakly resistant to thiophanate-methyl (EC50 values ranged between 6.53 and 12.09 mg L? 1). Selectivity indexes of the tested fungicides on both C. dendroidesand A. bisporusindicated that thiophanate-methyl, cyproconazole + carbendazim and flusilazole + carbendazim had much less selective fungitoxicity than benomyl, carbendazim and prochloraz manganese. 相似文献
39.
Dragović S Gajić B Dragović R Janković-Mandić L Slavković-Beškoski L Mihailović N Momčilović M Ćujić M 《Journal of environmental monitoring : JEM》2012,14(1):127-137
The specific activities of natural radionuclides ((40)K, (226)Ra and (232)Th) and Chernobyl-derived (137)Cs were measured in soil profiles representing typical soil types of Belgrade (Serbia): chernozems, fluvisols, humic gleysols, eutric cambisols, vertisols and gleyic fluvisols. The influence of soil properties and content of stable elements on radionuclide distribution down the soil profiles (at 5 cm intervals up to 50 cm depth) was analysed. Correlation analysis identified associations of (40)K, (226)Ra and (137)Cs with fine-grained soil fractions. Significant positive correlations were found between (137)Cs specific activity and both organic matter content and cation exchange capacity. Saturated hydraulic conductivity and specific electrical conductivity were also positively correlated with the specific activity of (137)Cs. The strong positive correlations between (226)Ra and (232)Th specific activities and Fe and Mn indicate an association with oxides of these elements in soil. The correlations observed between (40)K and Cr, Ni, Pb and Zn and also between (137)Cs and Cd, Cr, Pb and Zn could be attributed to their common affinity for clay minerals. These results provide insight into the main factors that affect radionuclide migration in the soil, which contributes to knowledge about radionuclide behaviour in the environment and factors governing their mobility within terrestrial ecosystems. 相似文献
40.
Spatial distribution of 238U and 226Ra activities in sediment columns along the Krka River and estuary, were studied using gamma spectrometry. Markedly different 238U and 226Ra activities between riverine, estuarine and marine sediments were observed. Distribution of these radionuclides, as well as their anthropogenic and natural origin, was evaluated by activity measurements, taking into account sedimentation rates estimated by 137Cs distribution in sediment columns. 相似文献