Assessment of solar driven TiO2-assisted photocatalysis efficiency on amoxicillin degradation

The objective of this work was to evaluate the efficiency of a solar TiO₂-assisted photocatalytic process on amoxicillin (AMX) degradation, an antibiotic widely used in human and veterinary medicine. Firstly, solar photolysis of AMX was compared with solar photocatalysis in a compound parabolic collectors pilot scale photoreactor to assess the amount of accumulated UV energy in the system (Q _UV) necessary to remove 20 mg L^?1 AMX from aqueous solution and mineralize the intermediary by-products. Another experiment was also carried out to accurately follow the antibacterial activity against Escherichia coli DSM 1103 and Staphylococcus aureus DSM 1104 and mineralization of AMX by tracing the contents of dissolved organic carbon (DOC), low molecular weight carboxylate anions, and inorganic anions. Finally, the influence of individual inorganic ions on AMX photocatalytic degradation efficiency and the involvement of some reactive oxygen species were also assessed. Photolysis was shown to be completely ineffective, while only 3.1 kJ_UV?L^?1 was sufficient to fully degrade 20 mg L^?1 AMX and remove 61 % of initial DOC content in the presence of the photocatalyst and sunlight. In the experiment with an initial AMX concentration of 40 mg L^?1, antibacterial activity of the solution was considerably reduced after elimination of AMX to levels below the respective detection limit. After 11.7 kJ_UV?L^?1, DOC decreased by 71 %; 30 % of the AMX nitrogen was converted into ammonium and all sulfur compounds were converted into sulfate. A large percentage of the remaining DOC was in the form of low molecular weight carboxylic acids. Presence of phosphate ions promoted the removal of AMX from solution, while no sizeable effects on the kinetics were found for other inorganic ions. Although the AMX degradation was mainly attributed to hydroxyl radicals, singlet oxygen also plays an important role in AMX self-photosensitization under UV/visible solar light.     

Embryonic development and maternal–embryo relationships of the Portuguese dogfish <Emphasis Type="Italic">Centroscymnus coelolepis</Emphasis>

The embryonic development and the level of dependency of the embryos from the maternal organism were investigated for Centroscymnus coelolepis. During the development, there is a 22–32% loss of organic matter and gains of 95–122% and 29–46% on moisture and inorganic matter, respectively. Only 28–48% of the initial yolk energy is conserved in embryos, being the remaining used in catabolism. In late pregnancy, the epithelium thickness of uterine villi decreases and vascularity increases. Results suggest that only water and minerals are transferred from the mother to the embryos. Monounsaturated fatty acids are the main type of fatty acids representing 48% of the total yolk fatty acid content, followed by polyunsaturated (30%) and saturated fatty acids (18–21%).     

Mercury and methyl mercury ratios in caimans (Caiman crocodilus yacare) from the Pantanal area, Brazil

The Pantanal region is the largest floodplain area in the world and of great biological importance due to its unique flora and fauna. This area is continuously undergoing increasing anthropogenic threats, and has also experienced mercury contamination associated with gold mining and other anthropogenic activities. Pantanal caimans are top-level predators, and, as such, show great potential to accumulate mercury (Hg) by biomagnification. In this study 79 specimens from four locations in the Pantanal were analyzed for total Hg and methyl mercury (MeHg) by cold vapor atomic absorption spectrometry. Total Hg contents ranged from 0.02 to 0.36 μg g(-1) (ww), and most specimens presented MeHg ratios above 70%. One of the sites, impacted by anthropogenic activities, presented significantly higher total Hg in comparison to three less impacted sites, supporting the hypothesis that caimans can, in fact, be considered effective bioindicators of ecosystem health.     

Association between occupational exposure to domestic solid waste and dental caries: a cross-sectional study

Environmental Science and Pollution Research - Studies have shown that domestic waste collectors are exposed to toxicants including infectious pathogens, which may be linked to their oral health...     

River pollution remediation monitored by optical and infrared high-resolution satellite images

The Bormida River Basin, located in the northwestern region of Italy, has been strongly contaminated by the ACNA chemical factory. This factory was in operation from 1892 to 1998, and contamination from the factory has had deleterious consequences on the water quality, agriculture, natural ecosystems and human health. Attempts have been made to remediate the site. The aims of this study were to use high-resolution satellite images combined with a classical remote sensing methodology to monitor vegetation conditions along the Bormida River, both upstream and downstream of the ACNA chemical factory site, and to compare the results obtained at different times before and after the remediation process. The trends of the Normalised Difference Vegetation Index (NDVI) and the Enhanced Vegetation Index (EVI) along the riverbanks are used to assess the effect of water pollution on vegetation. NDVI and EVI values show that the contamination produced by the ACNA factory had less severe effects in the year 2007, when most of the remediation activities were concluded, than in 2006 and 2003. In 2007, the contamination effects were noticeable up to 6 km downstream of the factory, whereas in 2003 and 2006 the influence range was up to about 12 km downstream of the factory. The results of this study show the effectiveness of remediation activities that have been taking place in this area. In addition, the comparison between NDVI and EVI shows that the EVI is more suitable to characterise the vegetation health and can be considered an additional tool to assess vegetation health and to monitor restoration activities.     

Road traffic impact on urban atmospheric aerosol loading at Oporto,Portugal

At urban areas in south Europe atmospheric aerosol levels are frequently above legislation limits as a result of road traffic and favourable climatic conditions for photochemical formation and dust suspension. Strategies for urban particulate pollution control have to take into account specific regional characteristics and need correct information concerning the sources of the aerosol.With these objectives, the ionic and elemental composition of the fine (PM_2.5) and coarse (PM_2.5–10) aerosol was measured at two contrasting sites in the centre of the city of Oporto, roadside (R) and urban background (UB), during two campaigns, in winter and summer.Application of Spatial Variability Factors, in association with Principal Component/Multilinear Regression/Inter-site Mass Balance Analysis, to aerosol data permitted to identify and quantify 5 main groups of sources, namely direct car emissions, industry, photochemical production, dust suspension and sea salt transport. Traffic strongly influenced PM mass and composition. Direct car emissions and road dust resuspension contributed with 44–66% to the fine aerosol and with 12 to 55% to the coarse particles mass at both sites, showing typically highest loads at roadside. In fine particles secondary origin was also quite important in aerosol loading, principally during summer, with 28–48% mass contribution, at R and UB sites respectively. Sea spray has an important contribution of 18–28% to coarse aerosol mass in the studied area, with a highest relative contribution at UB site.Application of Spatial Variability/Mass Balance Analysis permitted the estimation of traffic contribution to soil dust in both size ranges, across sites and seasons, demonstrating that as much as 80% of present dust can result from road traffic resuspension.     

Effects of Land Use Changes on the Ecosystem Service Values of Coastal Wetlands

Changes in the coastal landscape of Southern Sinaloa (Mexico), between 2000 and 2010, were analyzed to relate spatial variations in wetlands extent with the provision and economic value of the ecosystem services (ES). Remote sensing techniques applied to Landsat TM imagery were used to evaluate land use/land cover changes while the value transfer method was used to assess the value of ES by land cover category. Five wetland types and other four land covers were found as representative of the coastal landscape. Findings reveal a 14 % decrease in the saltmarsh/forested mangrove area and a 12 % increase in the area of shrimp pond aquaculture (artificial wetland) during the study period. ES valuation shows that the total value flow increased by 9 % from $215 to $233 million (2007 USD) during the 10-year period. This increase is explained as result of the high value worldwide assigned to saltmarsh. We recognize limitations in the transfer-based approach in quantifying and mapping ES values in the region, but this method provides with value estimates spatially defined, and also provides some guidance in the preliminary screening of policies and projected development in the context of data-scarce regions.