Accumulation of mercury and other heavy metals in edible fishes of Cochin backwaters, Southwest India

Mercury, a global pollutant, has become a real threat to the developing countries like India and China, where high usage of mercury is reported. Mercury and other heavy metals deposited in to the aquatic system can cause health risk to the biota. The common edible fishes such as Mugil cephalus, Arius arius, Lutjanus ehrenbergii, Etroplus suratensis were collected from Cochin backwaters, Southwest India and analysed for mercury and other heavy metals (zinc, cadmium, lead and copper) in various body parts. Kidney and liver showed highest concentration of metals in most fishes. The omnivore and bottom feeder (E. suratensis) showed high concentration of mercury (14.71 mg/kg dry weight) and other metals (1.74 mg/g-total metal concentration). The average mercury concentration obtained in muscle was 1.6 mg/kg dry weight (0.352 mg/kg wet weight), which is higher than the prescribed limits (0.3 mg/kg wet weight). The concentration of other heavy metals in the muscles of fishes were found in a decreasing order Zn>Cu>Cd>Pb and are well below WHO permissible limits that were safe for human consumption. Metal selectivity index (MSI) obtained for all the metals except mercury showed that both carnivores and omnivores have almost same kind of affinity towards the metals especially Zn and Cd, irrespective of their feeding habit. The MSI values also indicate that the fishes have the potential to accumulate metals. High tissue selectivity index (TSI) values were reported for kidney, muscle and brain for all metals suggests that the metal concentration in these tissues can serve as an indication of metal polluted environment. Even if the daily intakes of Zn, Cd, Pb and Cu from these fishes are within the provisional maximum daily intake recommended by WHO/FAO, the quality is questionable due to the high hazard index obtained for mercury (>1). Fishes like E. suratensis being a favourite food of people in this region, the high consumption of it can lead to chronic disorders as this fish has high concentration of metals.     

Water and sediment quality of Ashtamudi estuary, a Ramsar site, southwest coast of India—a statistical appraisal

Ashtamudi estuary, situated on the southwest coast of India, is enormously affected by anthropogenic interventions. Physicochemical quality of water and sedimentological features of the estuary are evaluated during monsoon and nonmonsoon seasons to elucidate its quality variations and to link the same with existing environmental scenario. The whole data has been factorized using principal component analysis for extracting the total variability and linear relationships existing among a set of different physicochemical parameters of the backwater system. In PCA, high loadings were obtained for conductivity, salinity, fluoride, calcium, magnesium, sulfate, boron, and pH. The results were revealed that all the physicochemical processes depend upon seasonal fluctuation of freshwater input and seawater intrusion. Wide spatial concentration fluctuations of organic carbon and iron in bottom sediment have been noticed and both constituents reveal good correlation with sediment texture. The results showed high deterioration of the physicochemical quality of water during nonmonsoon season with respect to monsoon season.     

Comparative toxicity of a brominated flame retardant (tetrabromobisphenol A) on microalgae with single and multi-species bioassays

The potential threat of emerging chemicals to the aquatic flora is a major issue. The purpose of the study was to develop a multispecies microalgae test in order to determine the impact of species interactions on the cytoxicity of an emergent toxic contaminant: the tetrabromobisphenol A (TBBPA). Single and multi-species tests were thus performed to study the effects of this flame retardant on two microalgae (Pseudokirchneriella subcapitata and Nitzschia palea) commonly observed in freshwater. A synthetic medium was designed to allow the growth of both species. The algae were exposed to 1.8, 4.8, 9.2, 12.9 and 16.5 μM of TBBPA for 72 h. After staining with fluorescein diacetate (FDA), viable cells of each alga species were analyzed by flow cytometry based on chlorophyll autofluorescence and intracellular esterase activity. Density and abundance of viable cells were assessed to follow the population growth and the cell viability. In TBBPA treated samples, the growth of the two microalgae was significantly inhibited at the three highest concentrations (9.2, 12.9 and 16.5 μM) in the two tests. At the end of the experiment (t = 72 h), the cell viability was also significantly smaller at these concentrations. The decreases of growth rate and viable cell abundance in TBBPA treated populations of N. palea were significantly higher in multi-species test in comparison with the single-species test. No significant differences were noticed between the two tests for P. subcapitata populations exposed to TBBPA.     

A catchment scale assessment of water balance components: a case study of Chittar catchment in South India

Environmental Science and Pollution Research - The detailed analyses of the water balance components (WBCs) of the catchment help assess the available water resources, especially in the arid...     

Phytotoxicity of cadmium on the physiological dynamics of Salvinia natans L. grown in macrophyte ponds

The objective of this experiment is to study the potential ability of Salvinia natans L. to use in phytoassay for the cadmium toxicity in ecotoxicological studies. It is a simple and cost competitive method. The sensitivity of S. natans in terms of biochemical changes and enzyme activities to Cd2+ was remarkably noticeable. The catalase and protease activity was significantly decreased in the presence of cadmium, with increase of peroxidase and superoxide dismutase activity. The level of protein, carbohydrate and chlorophyll decreased and proline content increased in plants. The maximum permissible concentration of cadmium in different general water quality standards was evaluated and found that cadmium standard is not stringent enough.     

Color removal of monoazo acid dye from aqueous solution by adsorption and chemical coagulation

This communication presents the results of an investigation conducted on color removal from a monoazo acid dye, C.I. Acid Red 88, by adsorption onto coal based sorbents like Lignite coal, Charfines and Bituminous coal and F-400 Activated carbon and by chemical coagulation employing Aluminum sulfate, Ferric chloride, Manganese sulfate, Manganese chloride and Barium chloride.     

An integrated approach for spatio-temporal variability analysis of wetlands: a case study of Abaya and Chamo lakes, Ethiopia

Starting with the intensification of irrigation activities in the beginning of 1980s in Abaya and Chamo lakes area, the decreasing water inflow to the lakes caused denudation of the wetlands. The ecological situation in the lake region changed significantly during last four decades. The lakes and associated wetlands change have been studied using Landsat MSS (1973), Landsat TM (1986), and Ladsat ETM (2000) satellite imagery. Along with satellite imagery, other hydro-meteorological data were collected and hydro-meteorological data analyses were done to assess the variability of wetlands. From these data, lakes morphometric property estimation at different time series and water balance analysis for both lakes were done. Wetlands are mapped from the TCT image and these maps are subject to change detection to see the temporal and spatial variability of the wetlands. Moreover, the lake-morphometric area and volume variation have been studied. The result showed that between 1986 and 2000, a significant reduction has been observed but lesser than the previous decades (6.4 km(2)). The identified reason behind this change is that the free settlement and shoreline cultivation of the wetlands causing the soil erosion and eventually adds the sediment to the wetlands.     

Electrospun nanofibers of polyvinylidene fluoride incorporated with titanium nanotubes for purifying air with bacterial contamination

Environmental Science and Pollution Research - Polyvinylidene fluoride (PVDF) blended with varying concentrations of titanium nanotubes (TNT) was electrospun to result in a nanocomposite filter...     

Spatio-temporal assessment of ambient air quality,their health effects and improvement during COVID-19 lockdown in one of the most polluted cities of India

Environmental Science and Pollution Research - The present work aims to investigate seasonal variations in air pollution levels in Lucknow and assess the ambient air quality of the city together...     

Modeling lifetime greenhouse gas emissions associated with materials for various end-of-life treatments

This research has developed mathematical models for computing lifetime greenhouse gas (GHG) emissions associated with materials. The models include embodied carbon (EC) emissions from the manufacture of materials, and GHG emissions from incineration, or landfill gas (LFG) production from landfill disposal of the material beyond their service lives. The models are applicable to all materials; however, their applications here are demonstrated for the lumber from a residential building with 50- and 100-year service lives, and with incineration, landfill, and deconstruction as end-of-life treatments. This paper introduces a new metric for lifetime GHG emissions associated with materials termed “Global Warming Impact of Materials (GWIM).” The GWIM is subdivided into two portions: (i) productive portion (GWIM_p) that includes the materials’ emissions until the service life of the facility and (ii) non-productive portion (GWIM_np) which includes the materials’ GHG emissions beyond the service life until they are eliminated from the atmosphere. In place of the current, static, EC measurements (kgCO₂e or MTCO₂e), this model reports the GWIMs in units of kgCO₂e-years or MTCO₂e-years, which includes the effects of “time of use” of a facility. Using the models, this paper has computed GHG reductions by deconstruction, with material recoveries of 30%, 50%, and 70% at demolition for reuse, recycle, or repurpose. A 70% material recovery, after a 50-year service life of the building, affected a savings of 47% and 52% if the remaining 30% debris was incinerated or landfilled respectively. All of the values computed using models checked out with manual calculations.