Decay profile and metabolic pathways of quinalphos in water, soil and plants

The widespread occurrence of pesticide residues in different agricultural and food commodities has raised concern among the environmentalists and food chemists. In order to keep a proper track of these materials, studies on their decay profiles in the various segments of ecosystem under varying environmental conditions are needed. In view of this, the metabolites of quinalphos in water and soil under controlled conditions and in plants, namely tomato and radish in field conditions have been analysed and possible pathways suggested. In order to follow the decay of the pesticide, an HPLC procedure has been developed. Studies conducted in water at different temperatures, pH and organic content reveal that the persistence of the pesticide decreases with the increase in all the three variables. In the three different types of soils studied, the effect of pH is more or less apparent on a similar line. On an average a faster decay is observed in the case of plants than in water and soil. The decay profiles in all these cases follow first order kinetics. The metabolites were identified by GC-MS. The investigations reflect that degradation occurs through hydrolysis, S-oxidation, dealkylation and thiono-thiol rearrangement. The pathways seem to be complex and different metabolites were observed with the change in the matrix. Quinalphos oxon, O-ethyl-O-quinoxalin-2-yl phosphoric acid, 2-hydroxy quinoxaline and quinoxaline-2-thiol were observed in all the matrices. Results further indicate that the metabolites, 2-hydroxy quinoxaline and oxon, which are more toxic than parent compound, persist for a longer time.     

Phytoremediation of a sulphonated azo dye Green HE4B by <Emphasis Type="Italic">Glandularia pulchella</Emphasis> (Sweet) Tronc. (Moss Verbena)

Purpose  

The dyes and dye stuffs present in effluents released from textile dyeing industries are potentially mutagenic and carcinogenic. Phytoremediation technology can be used for remediating sites contaminated with such textile dyeing effluents. The purpose of the work was to explore the potential of Glandularia pulchella (Sweet) Tronc. to decolorize different textile dyes, textile dyeing effluent, and synthetic mixture of dyes.     

Reconstituting “America”: The Clean Energy Economy Ventriloquized

With the foregrounding of “clean energy” policies by climate change concerns, the rhetorical constitution of “America” as a collective subject, mobilized to adopt the clean energy economy (CEE), becomes crucial. Here, I analyze the constitutive rhetoric of Pew Charitable Trusts’ landmark 2009 report on the CEE, drawing from the ventriloqual perspective to communication. I argue that this approach provides a more pragmatic, conversational understanding of the interpellative process constituting “America,” noting it to be hybridized and composed of various human and nonhuman agents. Tracing the ingoing interaction among agents—some manifest in the text, others spectral—sheds light on the complex relations of power at stake, recognizes the open-ended possibilities (and restrictions) of agency, and the role of material structures shaping environmental communication and policy.     

Origin and characterisation of microparticles in an ice core from the Central Dronning Maud Land, East Antarctica

The scanning electron microscopy-energy dispersive spectroscopic (SEM-EDS) study of selected samples from an ice core collected from Central Dronning Maud Land (CDML), East Antarctica, revealed several microparticles. They are mainly siliceous and carbonaceous particles and have distinct variations in their shape and composition. The morphology and major element chemistry of the particles suggest their origin from either volcanic eruptions or continental dust. The EDS analysis revealed that the volcanic particles are enriched in silica (average SiO2 62%), compared to the continental dust particle (average SiO2 56%). We found that the tephra relating to Agung (1963) and Karkatau (1883) volcanic eruptions, as recorded, in the ice core harbored microbial cells (both coocoid and rods). The occurrence of organic and inorganic particles which bear relation to volcanic eruption and continental dust implies significant environmental changes in the recent past.     

Speciation of heavy metals in biosolids of wastewater treatment plants at Mysore,Karnataka, India

Urban wastewater treatment leads to the generation of large quantities of biosolids. Accumulation of biosolids is a problem of environmental relevance due to the existence of heavy metals in the biosolids. Determination of total metal in biosolid provides information relating pollution levels. Determination of their mobilization capacity and behaviour in the environment is an important task. An experimental approach commonly used for studying the mobility, transport and bioavailability of metal in biosolids is the use of selective sequential extraction procedure. In the present study an attempt has been made to study the heavy metal properties in biosolid samples collected from urban wastewater treatment plants located at Mysore, Karnataka. Few heavy metals selected for the present study are cadmium, chromium, copper, iron, nickel and zinc. The concentration of these metals in biosolids and their partition in different fractions are studied. The speciation of metals based on the sequential extraction scheme was carried out. The concentration of heavy metals is lower than that established by European legislation. The residual fraction has the maximum percentage of heavy metals whereas, only a small fraction of heavy metals (Fe, Zn and Cd) are extracted in the most soluble fractions, exchangeable and carbonate fractions.     

Groundwater Pollution Around an Industrial Area in the Coastal Stretch of Maharashtra State, India

The main objective of this paper is to examine pollution threat, especially to the groundwater resources, around Tarapur industrial area (also called the Tarapur MIDC area) located on the Arabian Sea Coast in Thane District of Maharashtra State, India and suggest remedial measures that may also be relevant to other industrial areas on the Indian Sea Coast. One hundred and thirty one samples were collected from various sources, such as dugwells, borewells, dug-cum-borewells, effluent sumps, drainage channels (effluent channels), creeks and ocean, for chemical analyses. These analyses show that the area in general is characterized by hard water and high salinity hazard, possibly due to its proximity and hydraulic connection with the sea. Although the potability of groundwater is questionable in certain pockets, it is good enough for irrigation purposes at present. Low pH value and high heavy metal contents in the adjoining Muramba creek water is a matter of great concern and may be attributed to the indiscriminate disposal of industrial effluents to the drainage channels connecting the creek. Muramba Creek is well connected with the Arabian Sea, and there are evidences of seawater intrusion around this creek. Because of the fact that Muramba Creek is highly polluted, and is hydraulically connected with the dugwells and borewells surrounding the creek, it cannot be ruled out that the groundwater around this creek is susceptible to contamination. Unless measures are not taken immediately to stop the indiscriminate disposal of the solid wastes and liquid effluents in open ground and drainage channels, and measures are not taken to maintain the appropriate pH values at the effluent treatment facilities before their disposal, the problem would indeed be formidable one day, and it will be too late then for the authorities to take care of the resulting maladies. Few suggestions have been given for controlling and managing the industrial pollution around the Tarapur MIDC area. These suggestions are relevant to other industrial areas situated on the 7,000 km long Indian Sea Coast.     

Dissolved methane in Indian freshwater reservoirs

Emission of methane (CH₄), a potent greenhouse gas, from tropical reservoirs is of interest because such reservoirs experience conducive conditions for CH₄ production through anaerobic microbial activities. It has been suggested that Indian reservoirs have the potential to emit as much as 33.5 MT of CH₄ per annum to the atmosphere. However, this estimate is based on assumptions rather than actual measurements. We present here the first data on dissolved CH₄ concentrations from eight freshwater reservoirs in India, most of which experience seasonal anaerobic conditions and CH₄ buildup in the hypolimnia. However, strong stratification prevents the CH₄-rich subsurface layers to ventilate CH₄ directly to the atmosphere, and surface water CH₄ concentrations in these reservoirs are generally quite low (0.0028–0.305 μM). Moreover, only in two small reservoirs substantial CH₄ accumulation occurred at depths shallower than the level where water is used for power generation and irrigation, and in the only case where measurements were made in the outflowing water, CH₄ concentrations were quite low. In conjunction with short periods of CH₄ accumulation and generally lower concentrations than previously assumed, our study implies that CH₄ emission from Indian reservoirs has been greatly overestimated.     

Utilization of anaerobically treated distillery spent wash for production of cellulases under solid-state fermentation

Pollution caused by distillery spent wash on one hand has stimulated the need to develop new technologies to treat the waste and on the other, forced us to reevaluate the efficient utilization of its nutritive potential for production of various high value compounds. In this study, anaerobically treated distillery spent wash was used for the production of cellulases by Aspergillus ellipticus under solid-state fermentation using wheat straw as a substrate. The interactions between distillery effluent concentration, initial pH, moisture content and inoculum size were investigated and modeled using response surface methodology (RSM) involving Box–Behnken design (BBD). Under optimized conditions, filter paper activity, β-glucosidase and endo-β-1,4-glucanase activities were found to be 13.38, 26.68 and 130.92 U/g of substrate respectively. Characterization of endo-β-1,4-glucanase and β-glucosidase was done after partial purification by ammonium sulfate fractionation followed by desalting. The partially purified endo-β-1,4-glucanase and β-glucosidase showed maximum activity at 60 °C. Saccharification studies performed with different lignocellulosic substrates showed that wheat bran was most susceptible to enzymatic hydrolysis. The study suggests that anaerobically treated distillery spent wash can be used as a viable nutrient source for cellulase production under solid-state fermentation by A. ellipticus.     

Pulling force prediction using neural networks

Purpose. In ergonomics and human factors investigations, pulling force (PF) estimation has usually been achieved using various types of biomechanical models, and independent approximation of PF was done with the help of upper extremity joints. Recently, multiple regression methods have gained importance for task-relevant inputs in predicting PF. Artificial neural networks (ANNs) also play a vital role in fitting the data; however, their use in work-related biomechanics and ergonomics is inadequate. Therefore, the current research aimed to accomplish comparative investigation of ANN and regression models by assessing their capacity to predict PF values. Methods. Multipositional PF data were acquired from 200 subjects at three different handle heights and body locations. ANN and regression models were formed using a random sample of three subsets (75% training, 15% selection, 10% validation) for proving the outcomes. Results. The comparison of ANN and regression models shows that the predictions of ANN models had a profoundly explained variance and lower root mean square difference values for the PF data at three handle heights. Conclusions. These outcomes advise that ANNs offer a precise and robust substitute for regression methods, and should be considered a useful method in biomechanics and ergonomics task assessments.     

Influence of Geoengineered Climate on the Terrestrial Biosphere

Various geoengineering schemes have been proposed to counteract anthropogenically induced climate change. In a previous study, it was suggested that a 1.8% reduction in solar radiation incident on the Earths surface could noticeably reduce regional and seasonal climate change from increased atmospheric carbon dioxide (CO₂). However, the response of the terrestrial biosphere to reduced solar radiation in a CO₂-rich climate was not investigated. In this study, we hypothesized that a reduction in incident solar radiation in a Doubled CO₂ atmosphere will diminish the net primary productivity (NPP) of terrestrial ecosystems, potentially accelerating the accumulation of CO₂ in the atmosphere. We used a dynamic global ecosystem model, the Integrated Biosphere Simulator (IBIS), to investigate this hypothesis in an unperturbed climatology. While this simplified modeling framework effectively separated the influence of CO₂ and sunlight on the terrestrial biosphere, it did not consider the complex feedbacks within the Earths climate system. Our analysis indicated that compared to a Doubled CO₂ scenario, reduction in incident solar radiation by 1.8% in a double CO₂ world will have negligible impact on the NPP of terrestrial ecosystems. There were, however, spatial variations in the response of NPP-engineered solar radiation. While productivity decreased by less than 2% in the tropical and boreal forests as hypothesized, it increased by a similar percentage in the temperate deciduous forests and grasslands. This increase in productivity was attributed to a 1% reduction in evapotranspiration in the Geoengineered scenario relative to the Doubled CO₂ scenario. Our initial hypothesis was rejected because of unanticipated effects of engineered solar radiation on the hydrologic cycle. However, any geoengineering approaches that reduce incident solar radiation need to be thoroughly analyzed in view of the implications on ecosystem productivity and the hydrologic cycle.