冷-干直接抽取法CEMS冷凝器的选型

探讨了烟气冷凝器的关键性能指标,提出烟气冷凝器脱水率、SO2组分丢失率和烟气出口露点温度等关键参数的计算公式,提出了适合不同工况条件下烟气冷凝器选型的依据和方法,为解决冷-干直接抽取法CEMS所面临的湿法脱硫后的高湿、低浓度SO2,及如何准确、客观地反映污染排放的现实问题,提供了一个合理的解决方案。     

A Comparison of Mass,Lead, Sulfate,and Nitrate Concentrations in a Field Study Using Dichotomous,Size-Selective,and Standard Hi-Vol Samplers

Air monitoring In the San Francisco Bay Area was carried out to measure outdoor community air concentrations of poly cyclic aromatic hydrocarbons (PAH) and mutagenlc activity (mutagenlclty) In participate organic matter (POM). Monitoring began In 1979 and Is currently conducted at six stations. PAH and mutagenlclty tests were performed on organic extracts prepared from high volume (hl-vol) filters composited every four months, by meteorological season. PAH were determined by high pressure liquid chromatography (HPLC) with fluorescence and ultraviolet detection. Mutagenlclty was measured In the Ames Salmonella bloas-say using strain TA98 with and without metabolic activation. The nine-year mean concentration of benzo(a)pyrene (BaP) was 0.4 ng/m³. The mutagenlcfty of this amount of BaP accounted for only about 0.2% of the observed mutagenicity In POM and other measured PAH accounted for even less. Concentrations of PAH and mutagenlclty were three to nine times higher during the winter than during other seasons. Year-to-year wintertime trends In several PAH were also seen. Early In the 1980s, winter concentrations of BaP and benzo (g,h,i)perylene Increased. However since the mld-1980’s, their concentrations have fallen. The decrease In PAH concentrations may be the result of an Increasing proportion of vehicles with relatively low organic emissions. In contrast to PAH, mutagenlcfty did not show significant year-to-year time trends.     

Emission factors and particulate matter size distribution of polycyclic aromatic hydrocarbons from residential coal combustions in rural Northern China

Coal consumption is one important contributor to energy production, and is regarded as one of the most important sources of air pollutants that have considerable impacts on human health and climate change. Emissions of polycyclic aromatic hydrocarbons (PAHs) from coal combustion were studied in a typical stove. Emission factors (EFs) of 16 EPA priority PAHs from tested coals ranged from 6.25 ± 1.16 mg kg^?1 (anthracite) to 253 ± 170 mg kg^?1 (bituminous), with NAP and PHE dominated in gaseous and particulate phases, respectively. Size distributions of particulate phase PAHs from tested coals showed that they were mostly associated with particulate matter (PM) with size either between 0.7 and 2.1 μm or less than 0.4 μm (PM_0.4). In the latter category, not only were more PAHs present in PM_0.4, but also contained higher fractions of high molecular weight PAHs. Generally, there were more than 89% of total particulate phase PAHs associated with PM_2.5. Gas-particle partitioning of freshly emitted PAHs from residential coal combustions were thought to be mainly controlled by absorption rather than adsorption, which is similar to those from other sources. Besides, the influence of fuel properties and combustion conditions was further investigated by using stepwise regression analysis, which indicated that almost 57 ± 10% of total variations in PAH EFs can be accounted for by moisture and volatile matter content of coal in residential combustion.     

用固体力学化学理论研究岩土的力学化学行为——以成都龙泉紫色土为例

根据固体力学化学理论 ,提出用化学动力学方法研究岩土破坏及滑坡形成的机理 ,并以成都龙泉紫色土为例研究了在力与水协同作用下易滑土层的力学化学行为。实验表明 ,土长期抗剪强度降低的幅度与溶液的pH值有关 ,土的溶解速度与易溶盐含量有关 ,且溶解曲线略呈“S”型。这初步证明了龙泉紫色土破坏的力学 化学效应及其可能存在的自催化趋势。通过实验了解了力与水协同作用导致土破坏的力学化学规律 ,并将定量求解滑面长期抗剪强度与反应机理研究结合起来 ,为定量评价地下水和应力对岩土破坏机理这一滑坡学关键问题打下基础。     

上海人口自然变动负增长与社会经济发展

1993年上海人口自然变动在全国率先进入负增长,自然增长率为-0.78‰,并将持续一个较长的时期。这是长期以来本市经济和社会发展以及计划生育工作共同作用的必然结果,其中计划生育政策的成功推行起着重要的作用。上海除了继续控制人口增长的数量外,还要调节人口规模和人口结构,大力提高人口素质,不断使人口与社会经济发展、生态平衡、资源利用等方面达到协调发展。由负增长引发的劳动力短缺和老龄化程度加剧要采取相应的对策。     

壳聚糖-丙烯酰胺-二甲基二烯丙基氯化铵三元接枝共聚物的合成及应用

在N2保护下，以硝硬驱铈铵为引发剂，将壳聚糖（CTS）、丙烯酰胺（AM）及二甲基二烯丙基氯化铵（DMDAAC）接枝共聚得到CTS-AM-DMDAAC三元接枝共聚物，考察了反应条件对接枝共聚反应的影响。实验结果表明，在反应温度50℃、反应时间5-6h，m（CTS）：m（AM）：m（DMAAAC）=1：6：0.67、c（Ce^4＋）=0.8mmol/L的最佳反应条件下，接枝共聚反应的接枝率和接枝效率分别为64%和10.5%。用傅里叶变换红外光谱仪对CTS-AM-DMDAAC进行了表征。絮凝实验结果表明：CTS-AM-DMDAAC对高岭土水样具有较强的絮凝能力，可在很宽的pH范围内使用。用CTS-AM-DMDAAC处理COD为165.5mg/L的啤酒生产废水，COD去除率达90.1%.     

长时间单调模拟驾驶对疲劳的影响研究

通过模拟驾驶实验,综合评估长时间驾驶以及单调环境对驾驶员疲劳程度的影响是笔者研究的主要课题内容。借助于在模拟驾驶座舱上,4个健康样本分别参加高速公路(单调环境)和一般公路(非单调环境)的两组驾驶仿真实验,每组测试均持续两小时,一共进行10次实验。实验过程中,样本的操控数据(车速和方向盘转角)、反应时间、心电信号、主观疲劳状况等都同步记录并保存。实验结果表明长时间驾驶对操控能力、反应时间、心率、主观疲劳都有显著性影响(p<0.050),单调环境(高速公路)和非单调环境(一般公路)相比,车速方差区别显著,而尽管被试在高速公路的单调环境下驾驶后主观感觉更疲劳一些,但反应时间、心率等因素并没有显著性差异。     

阵性泥石流运动与堆积的欧拉─拉格朗日模型──Ⅰ.理论

自然界中的泥石流具有突发性和非恒定性的特点。为了模拟典型泥石流现象，在流团模型的 基础上，进一步完善了基于欧拉─拉格朗日（Ｅ—Ｌ）观点的ＰＩＣ（Ｐａｒｃｅｌ　Ｉｎ　Ｃｅｌｌ）算法，细化了流元结 构，建立了能够模拟典型阵性泥石流发生、运动和堆积的准结构两相流模型。求解该模型不仅可以 模拟泥石流运动过程，而且可以对泥石流的堆积过程、停积形态、冲刷特征及泥石流中多组分颗粒 的分选特征进行定量描述。     

聚硅酸氯化铝处理皂素废水的研究

制备了聚硅酸氯化铝(PASC)絮凝剂，并用其进行了皂素废水处理实验。考察了絮凝剂投加量、pH值、搅拌速度对COD和浊度去除率的影响。结果表明，当絮凝剂投加量为9～13.5 mg/L、pH值5～7、搅拌速度150～250 r/min时，COD和浊度去除效果较好。最佳工艺条件为：絮凝剂投加量11.25 mg/L、pH值6、搅拌速度200 r/min。此时，COD去除率为93.7％，浊度去除率为97.5％。PASC的絮凝性能明显优于PAC。     

灾难事件后继风险决策

对小概率/高风险的灾难事件的后继风险决策进行探讨,着重在决策的认知神经经济模型框架下,讨论灾难事件后继风险决策的影响因素。灾难事件后人们的风险觉知、信念和假定、经验等认知因素以及灾后情绪因素对于决策分别有不同的影响;人们灾后决策的特点为决策更多直觉化而较少运用理性分析;灾难后继决策有随时间变化的趋势,灾难事件后人们为寻求安全感而出现"损失偏差"(loss bias),该偏差在"获得"和"损失"两种条件下的影响是不同的。灾后风险决策的内在机制或可用思维和决策的双加工系统(dual-process)模型来解释。最后展望了灾难事件后继决策进一步的研究方向。