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951.
固相萃取与气相色谱-质谱联用测定水中痕量多环芳烃 总被引:3,自引:0,他引:3
采用固相萃取与气相色谱-质谱联用测定水中痕量多环芳烃(PAHs)。通过正交试验,得到最佳固相萃取条件为:上样流速为5mL/min、采用二氯甲烷洗脱、洗脱剂用量为3mL、洗脱流速为2mL/min。测定结果显示,固相萃取与气相色谱—质谱联用技术对萘、菲、荧蒽3种PAHs的检出限为0.03~0.07μg/L,加标回收率为70%~100%,相对标准偏差为3.90%~9.58%。该方法精密度高、准确度好,能满足实际水样中痕量PAHs的测定要求。 相似文献
952.
Chul H. Song Mi E. Park En J. Lee Jae H. Lee Bo K. Lee Dong S. Lee Jhoon Kim Jin S. Han Kwang J. Moon Yutaka Kondo 《Atmospheric environment (Oxford, England : 1994)》2009,43(13):2168-2173
Simultaneous measurements of gaseous species and fine-mode, particulate inorganic components were performed at the University of Seoul, Seoul in Korea. In the simultaneous measurements, a certain level of nitrous acid (HONO) was observed in the gas-phase, indicating possible heterogeneous HONO production on the surface of the ambient aerosols. On the other hand, high particulate nitrite (NO2?) concentrations of 1.41(±2.26) μg/m3 were also measured, which sometimes reached 18.54 μg/m3. In contrast, low HONO-to-NO2 ratios of 0.007(±0.006) were observed in Seoul. This indicates that a significant fraction of HONO is dissolved in atmospheric aerosols. Around the Seoul site, sufficient alkalinity may have been provided to the atmospheric aerosols from the excessive presence of NH3 in the gas-phase. Due to the alkaline particulate conditions (defined in this study as a particle pH >~3.29), the HONO molecules produced at the surface of the atmospheric aerosols appeared to have been converted into particulate nitrite, thereby preventing their further participation in the atmospheric O3/NOy/HOx photochemical cycles. It was estimated that a minimum average of 65% of HONO was captured by alkaline, anthropogenic, urban particles in the Seoul measurements. 相似文献
953.
954.
CuO/γ-Al_2O_3负载型催化剂催化燃烧处理油烟 总被引:1,自引:1,他引:0
采用等体积漫渍法制备不同CuO负载量的CuO/γ-Al2O3负载型催化剂,用X射线衍射仪、扫描电镜对该催化剂负载层活性组分的表面形态、晶相结构和颗粒大小进行表征,考察了该催化荆催化燃烧处理油烟的催化活性(以油烟净化效率表征).结果显示,催化活性随CuO负载量的增加.反应温度的升高而提高,但随烟气流量的增大而降低;在CuO负载量为20%(质量分数)、反应温度为350℃.烟气流量为5 L/min的最佳实验条件下,CuO/γ-Al2O3负载型催化剂的油烟净化效率最高.可达88.6%.该催化剂对油烟的催化燃烧具有较高的催化活性. 相似文献
955.
956.
Abstract: Frustration with the lack of action on conservation issues by governments has sparked debate around the policy role of conservation biologists. We analyzed the political economy of conservation biology, that is, of the dynamics of the political and economic structures within which conservation biology operates, and we suggest more productive means for conservation biologists to achieve conservation goals. Within the modern state, conservation goals are marginalized because the growth needs of industrial capital have the highest priority. Environmental advocacy within this system largely addresses only proximate concerns and has limited success. Science is a product of modern society, but scientists now need to foster novel institutional arrangements in which humans can function within the limits of natural systems. This entails a larger recognition of the inherent contradictions residing within current institutions that themselves depend on unsustainably high resource flows. As one critical counterbalance to these institutions, we discuss community-based management and research as primary institutions through which sustainable use of natural resources might be achieved. 相似文献
957.
Jeong-Hun Kim Yong-Chil Seo Deepak Pudasainee Sang-Hyeob Lee Sung-Jin Cho Ha-Na Jang Ju-Myon Park Geum-Ju Song Kyu-Shik Park 《Journal of Material Cycles and Waste Management》2009,11(3):183-190
The development of regulations patterned after the United States’ requirement for maximum achievable control technology (MACT)
to control hazardous air pollutants from major industrial sources in Korea is in progress. Current management practices and
installed air pollution control devices were surveyed; emission tests and continuous emission data collected from facilities
under operation were assessed considering other MACT requirements such as reporting, report keeping requirements. Emission
sampling and air pollutant analysis were carried out at representative hazardous waste incinerators installed with wet-type
and dry-type air pollution control devices. Korean and United States Environmental Protection Agency methods were used for
sampling and analysis. The major heavy metals emitted were Zn, Ni, Pb, and Cr. The heavy metal removal efficiency of existing
air pollution control devices was greater than 99%. The average mercury removal efficiency was more than 30%. Toluene; m,p-xylene; o-xylene; benzene; dichloromethane; styrene; ethylbenzene; 1,3-dichlorobenzene; and 1,2,4-trimethylbenzene were the major volatile
organic compounds emitted. The emissions from field tests were compared, reviewed, and analyzed with respect to MACT regulations
to check applicability. Finally, draft guidelines were suggested for effective hazardous air pollutant management in Korea. 相似文献
958.
959.
Sue Ellen C. Bottrel Camila C. Amorim Mônica M.D. Leão Elizângela P. Costa Igor A. Lacerda 《Journal of environmental science and health. Part. B》2013,48(4):263-270
In this study, photocatalytic (photo-Fenton and H2O2/UV) and dark Fenton processes were used to remove ethylenethiourea (ETU) from water. The experiments were conducted in a photo-reactor with an 80 W mercury vapor lamp. The mineralization of ETU was determined by total organic carbon analysis, and ETU degradation was qualitatively monitored by the reduction of UV absorbance at 232 nm. A higher mineralization efficiency was obtained by using the photo-peroxidation process (UV/H2O2). Approximately 77% of ETU was mineralized within 120 min of the reaction using [H2O2]0 = 400 mg L?1. The photo-Fenton process mineralized 70% of the ETU with [H2O2]0 = 800 mg L?1 and [Fe2+] = 400 mg L?1, and there is evidence that hydrogen peroxide was the limiting reagent in the reaction because it was rapidly consumed. Moreover, increasing the concentration of H2O2 from 800 mg L?1 to 1200 mg L?1 did not enhance the degradation of ETU. Kinetics studies revealed that the pseudo-second-order model best fit the experimental conditions. The k values for the UV/H2O2 and photo-Fenton processes were determined to be 6.2 × 10?4 mg L?1 min?1 and 7.7 × 10?4 mg L?1 min?1, respectively. The mineralization of ETU in the absence of hydrogen peroxide has led to the conclusion that ETU transformation products are susceptible to photolysis by UV light. These are promising results for further research. The processes that were investigated can be used to remove pesticide metabolites from drinking water sources and wastewater in developing countries. 相似文献
960.
A/O和A2/O工艺对膜生物反应器处理焦化废水影响的研究 总被引:3,自引:1,他引:2
为提高膜生物反应器对焦化废水的处理效果,采用A/O和A2/O两种工艺的膜生物反应器处理焦化废水,通过对比处理效果、分析膜污染情况,寻求膜生物反应处理焦化废水的最优工艺。实验结果表明:A2/O工艺系统对酚、NH3-N、COD的去除率分别为99%、90%和95%;A/O工艺系统对酚、NH3-N和COD的去除率分别为97%、75%和93%。A2/O膜生物反应器系统对焦化废水中NH3-N的去除效果明显优于A/O膜生物反应器系统,其反硝化率为50%~70%。对膜污染分析表明不同工艺对膜污染的影响不显著,A2/O工艺膜通量衰减59%,A/O工艺膜通量衰减56%。研究表明在膜生物反应器中,A2/O工艺对焦化废水的去除效果要优于A/O工艺。 相似文献