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81.
Abdul Ghaffar Masaaki Tabata Farhana Mazher Azhar Mashiatullah 《Environmental Chemistry Letters》2012,10(2):171-176
This article reports high dechlorination of toxic polychlorinated biphenyls (PCBs) under mild conditions. PCBs are priority
pollutants acting as endocrine disruptors, human carcinogens and environmental estrogens. Previous remediation methods involving
high temperature and pressure have drawbacks such as high cost, de novo dioxins synthesis and difficult recovery of vaporized
PCBs. On the other hand, dechlorination methods using mild conditions show the problem of catalyst deactivation. Here, activated
carbon was used for the first time as catalyst to dechlorinate 2,4,5 trichlorobiphenyl. High dechlorination, of 87%, was achieved
under mild conditions. 2,4,5 trichlorobiphenyl was treated at 40–150°C with calcium hydroxide, sodium hydroxide and sulfur
in mixed water and organic solvents. Dechlorination products were biphenyl, orthohydroxy biphenyls, 2,4 dihydroxy biphenyls
and biphenyl-2-thiol. Dichlorobiphenyl and orthochlorobiphenyls were found in trace quantities. We found that carbon particles
catalysed dechlorination by substitution reactions and suppressed further chlorination. Dechlorination at biphenyl ortho position
was preceded by substitution reaction by hydroxyl and thiol ions. Moreover, in the absence of carbon, dechlorination was lower
and substituted products were not observed. These findings may be applied at industrial scale to remediate PCB-contaminated
waste. 相似文献
82.
Metal contamination of surface soils of industrial city Sialkot,Pakistan: a multivariate and GIS approach 总被引:3,自引:0,他引:3
Riffat Naseem Malik Waqar Azeem Jadoon Syed Zahoor Husain 《Environmental geochemistry and health》2010,32(3):179-191
In this study concentrations of selected metals viz., Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Na, Ni, Pb and Zn in surface soils of
Sialkot city known worldwide for tanneries and pharmaceutical industries were measured to assess the status of urban soil
pollution and to identify sources of contamination. Hierarchical cluster analysis (HACA) indicated concentrations of Mg and
Ca related to parent rock material, Cd, Co, and Pb with traffic related activities, Cr, Cu, Ni and Zn either associated with
automobiles activities or industrial pollution and Fe, K and Na related with anthropogenic activities or lithogenous materials.
Correlation analyses and principal component analysis based on factor analysis confirmed the results of HACA. Spatial distribution
maps exhibited relatively higher concentrations of Cd, Co, Cu, Ni, Pb, Cr and Zn along traffic routes in the city and streams.
The results highlighted concentration of Cd, Ni, Cr, Zn, and Pb measured in urban soil exceeded the permissible limit of surface
soils and advocated an imperative need for detailed baseline investigations of spatial distribution of heavy metals and other
contaminants for the formulation of geochemical database that should be made available to stakeholder involved in monitoring,
assessment and conservation of soil contamination for future planning and management of the Sialkot city. 相似文献
83.
Uddin KM Juraimi AS Ismail MR Othman R Rahim AA 《Journal of environmental biology / Academy of Environmental Biology, India》2011,32(3):309-312
Fresh water, coupled with soil salinization in many areas has resulted in an increased need forscreening of salt tolerant turf grasses. Relative salinity tolerance of eightwarm season turfgrass species were examined in this study in sand culture. Grasses were grown in a glasshouse, irrigated with either distilled water or saline sea water adjusted to 24, 48 or 72 dSm-1. Salt tolerances of the grasses were assessed on the basis of their shoot and root growth, leaf firing and turf quality. Regression analysis indicated that Zoysiajaponica (Japanese lawn grass) (JG), Stenotaphrum secundatum (St. Augustine) (SA), Cynodon dactylon (satiri) (BS), Zoysia teneuifolia (Korean grass) (KG), Digitaria didactyla (Serangoon grass) (SG), Cynodon dactylon (Tifdwarf) (TD), Paspalum notatum (Bahia grass) (BG) and Axonopus compressus(Pearl blue) (PB) suffered a 50% shoot growth reduction at 36.0, 31.8, 30.9, 28.4, 26.4, 25.7, 20.0 and 18.6 dSm1 of salinity, respectively and a root growth reduction at44.9, 43.7, 33.4, 31.0, 29.5 27.5, 21.5 and 21.4 dSm- of salinity, respectively. Leaf firing and turf quality of the selected species, as a whole, were also found to be affected harmoniously with the change in root and shoot growth. On the basis of the experimental results the selected species were ranked for salinity tolerance as JG>SA>BS>KG>SG >TD>BG>PB. 相似文献
84.
Groundwater modeling of Saq Aquifer Buraydah Al Qassim for better water management strategies 总被引:2,自引:0,他引:2
Ibrahim S. Al-Salamah Yousry M. Ghazaw Abdul Razzaq Ghumman 《Environmental monitoring and assessment》2011,173(1-4):851-860
Saudi Arabia is an arid country. It has limited water supplies. About 80?C90% of water supplies come from groundwater, which is depleting day by day. It needs appropriate management. This paper has investigated groundwater modeling of Saq Aquifer in Buraydah Al Qassim to estimate the impact of its excessive use on depletion of Saq Aquifer. MODFLOW model has been used in this study. Data regarding the aquifer parameters was measured by pumping tests. Groundwater levels and discharge of wells in the area for the year 2008 and previous record of year 1999 have been collected from Municipal Authority of Buraydah. Location of wells was determined by Garmin. The model has been run for different sets of pumping rates to recommend an optimal use of groundwater resources and get prolonged life of aquifer. Simulations have been made for a long future period of 27?years (2008?C2035). Model results concluded that pumping from the Saq Aquifer in Buraydah area will result into significant cones of depression if the existing excessive pumping rates prevail. A drawdown up to 28?m was encountered for model run for 27?years for existing rates of pumping. Aquifer withdrawals and drawdowns will be optimal with the conservation alternative. The management scheme has been recommended to be adopted for the future protection of groundwater resources in Kingdom of Saudi Arabia. 相似文献
85.
Desalination is the only means of reliable water supply in most of the Arabian Gulf States including Kuwait, Saudi Arabia, Bahrain, Qatar, and United Arab Emirates. Huge desalination capacities are installed on the western margin of the Arabian Gulf contributing to increased salinity off the coast. This paper presents long term salinity observation made near outfall of Az Zour Power and Desalination Plant in South Kuwait. The salinity values peak at around 50 ppt at observation station located in open gulf around 5 km from the outfall of the power and desalination plant. The observation highlights the stress on the local marine environment continued incremental salinity can impair the marine biodiversity in the area. The study suggests that a stringent post construction and operational offshore water quality assessment can help in early detection of potentially complex environmental issues. 相似文献
86.
Abdul R. Ghumman Yousry Mahmoud Ghazaw Muhammed F. Niazi Hashim N. Hashmi 《Environmental monitoring and assessment》2011,172(1-4):189-197
Waterlogging and salinity due to seepage from canals have polluted land and environment in various parts of Pakistan. A sustainable environment requires urgent remedial measures for this problem. The research in this paper presents the impacts of the Fourth Drainage Project, Faisalabad on the twin problem of waterlogging and salinity. Monitoring of the project was made on regular basis. The key performance indicators for the project include the lowering of water table, improvement of water quality and soil salinity, increase in area under cultivation, cropping intensity, and socioeconomic status of the project population. Data regarding water levels and discharge from the drain pipes were collected to monitor the impact on waterlogging. Soil samples were tested to evaluate the impact of drainage on land. It has been found that the percentage of the contaminated land in the project area has considerably been decreased, while the cropping intensities have been increased. 相似文献
87.
Mohammad Zubair Alam Shamim Ahmad Abdul Malik 《Environmental monitoring and assessment》2011,178(1-4):281-291
In the present study, a total of 198 bacteria were isolated, 88 from the tannery effluents and 110 from agricultural soil irrigated with the tannery effluents. Tannery effluents and soils were analyzed for metal concentrations by atomic absorption spectrophotometer. The tannery effluents and soil samples were found to be contaminated with chromium, nickel, zinc, copper, and cadmium. All isolates were tested for their resistance against Cr6?+?, Cr3?+?, Ni2?+?, Zn2?+?, Cu2?+?, Cd2?+?, and Hg2?+?. From the total of 198 isolates, maximum bacterial isolates were found to be resistant to Cr6?+? 178 (89.9%) followed by Cr3?+? 146 (73.7%), Cd2?+? 86 (43.4%), Zn2?+? 83 (41.9%), Ni2?+? 61 (30.8%), and Cu2?+? 51 (25.6%). However, most of the isolates were sensitive to Hg2?+?. Among the isolates from tannery effluents, 97.8% were resistant to Cr6?+? and 64.8% were resistant to Cr3?+?. Most of the soil isolates were resistant against Cr6?+? (83.6%) and Cr3?+? (81.8%). All isolates were categorized into Gram-positive and Gram-negative bacteria. In a total of 114 Gram-positive isolates, 91.2% were resistant to Cr6?+? followed by 73.7% to Cr3?+?, 42.1% to Zn2?+?, 40.4% to Cd2?+?, and 32.5% to Ni2?+?. Among Gram-negative isolates, 88.1% were found showing resistance to Cr6?+?, 75.0% to Cr3?+?, and 47.6% were resistant to Cd2?+?. Majority of these metal-resistant isolates were surprisingly found sensitive to the ten commonly used antibiotics. Out of 198 isolates, 114 were found sensitive to all antibiotics whereas only two isolates were resistant to maximum eight antibiotics at a time. Forty-one and 40 isolates which constitute 20.7% and 20.2% were resistant to methicilin and amoxicillin, respectively. 相似文献
88.
The ability of cadmium uptake by metal-resistant yeast, Candida tropicalis, from the liquid medium and wastewater was evaluated. The minimum inhibitory concentration of Cd2?+? against C. tropicalis was 2,500 mg L???1. The yeast also showed tolerance toward Zn2?+? (1,400 mg L???1), Ni2?+? (1,000 mg L???1), Hg2?+? (1,400 mg L???1), Cu2?+? (1,000 mg L???1), Cr6?+? (1,200 mg L???1), and Pb2?+? (1,000 mg L???1). The yeast isolate showed typical growth curves, but lag and log phases extended in the presence of cadmium. The yeast isolate showed optimum growth at 30°C and pH 8. The metal processing ability of the isolate was determined in a medium containing 100 mg L???1 of Cd2?+?. C. tropicalis could decline Cd2?+? 70%, 85%, and 92% from the medium after 48, 96, and 144 h, respectively. C. tropicalis was also able to remove Cd2?+? 40% and 78% from the wastewater after 6 and 12 days, respectively. Cd produced an increase in glutathione (GSH) and nonprotein thiol levels by 135% and 134% at 100-mg L???1 concentration, respectively. An increase in the synthesis of GSH is involved in metal tolerance, and the presence of increasing GSH concentrations may be a marker for high metal stress in C. tropicalis. C. tropicalis, which is resistant to heavy metal ions and is adaptable to the local environmental conditions, may be employed for metal detoxification operations. 相似文献
89.
Objective
The objective of this study was to evaluate repeated patient handling injuries following a multi-factor ergonomic intervention program among health care workers.Methods
This was a quasi-experimental study which had an intervention group and a non-randomized control group. Data were collected from six hospitals in Saskatchewan, Canada from September 1, 2001 to December 1, 2006.Results
A total of 1,480 individuals who had a previous injury were eligible for the study. Medium and small size hospitals in the intervention group had significantly fewer repeated injuries than in the control group. Multivariate analysis showed that the intervention group had 38.1% lower odds of having repeated injury compared to the control group, after adjusting for hospital size.Conclusions
The work-related repeated injury after a multi-factor intervention program was reduced. The synergistic relationships between components of multi-factor intervention and applicability of injury prevention programs to different settings need to be further explored.Impact on Industry
Implementing a multi-factor program with the right equipment and training can lower the risk of injury among health care workers. 相似文献90.
Jawad Ali H. Rangabhashiyam S. Abdulhameed Ahmed Saud Syed-Hassan Syed Shatir A. ALOthman Zeid A. Wilson Lee D. 《Journal of Polymers and the Environment》2022,30(7):2759-2773
Journal of Polymers and the Environment - A new biocomposite cross-linked glutaraldehyde-chitosan/MgO/Fe3O4 (CTS-GL/MgO/Fe3O4) adsorbent with magneto-responsiveness was prepared and applied for the... 相似文献