Solvent toxicity to amphibian embryos and larvae

Organic micropollutants are often damaging for aquatic organisms. Being usually hydrophobic compounds, they are often dissolved in an organic co-solvent which increases their solubility in water. The aim of this study was to study the toxicity of various solvents on embryos (protected or not by jelly coat) and on tadpoles of the common frog (Rana temporaria). Tested solvents were methanol (MeOH), methylene chloride (CH(2)Cl(2)), dimethyl sulfoxyde (DMSO), acetone (Ac) and ethanol (EtOH). Embryos exhibited higher mortality rates than tadpoles. Embryos with jelly were more sensitive to high concentration of solvents than embryos without jelly (except for acetone). According to these results, Ac, DMSO and CH(2)Cl(2) can be used as co-solvents in water to help the dissolution of micropollutants at concentration equal to or lower than 0.001 ml/l for frog embryos, and EtOH, Ac and CH(2)Cl(2) at concentration equal to or lower than 0.01 ml/l for Rana temporaria tadpoles.     

Spatial variability of sediment ecotoxicity in a large storm water detention basin

Detention basins are valuable facilities for urban storm water management, from both the standpoint of flood control and the trapping of pollutants. Studies performed on storm water have shown that suspended solids often constitute the main vector of pollutants (heavy metals, polycyclic aromatic hydrocarbon (PAH), etc.). In order to characterise the ecotoxicity of urban sediments from storm water detention basins, the sediments accumulated over a 6-year period were sampled at five different points through the surface of a large detention basin localised in the east of Lyon, France. A specific ecotoxicological test battery was implemented on the solid phase (raw sediment) and the liquid phase (interstitial water of sediments). The results of the study validated the method formulated for the ecotoxicological characterization of urban sediments. They show that the ecotoxicological effect of the sediments over the basin is heterogeneous and greater in areas often flooded. They also show the relationship between, on one hand, the physical and chemical characteristics of the sediments and, on the other hand, their ecotoxicity. Lastly, they contribute to a better understanding of the dynamics of the pollution close to the bottom of detention basins, which can be useful for improving their design. The results of this research raise particularly the issue of using oil separators on the surface of detention basins.     

Indicators for hydraulic and pollution retention assessment of stormwater infiltration basins

Infiltration basins are frequently used for stormwater management even though their long-term evolution is not well understood nor controlled. The two main problems encountered are clogging which compromises the hydraulic capacity of the basin and possible contamination of underlying soil and groundwater. This paper defines a framework for evaluating the hydraulic and pollution retention performance of infiltration basins in the long-term. Sets of context and performance indicators are proposed, along with two complementary modes of evaluation. Context indicators are identified in order to define the clogging and contamination states of the basins. Performance indicators are developed to assess several aspects of basin performance: drainage duration, overflow frequency, predictive life period, particle filtration and pollution trapping. Modes of evaluation include field investigation and long-term simulation modeling. Indicators are tested on five infiltration basins in suburban Lyon (France). Both context indicators and hydraulic performance indicators are reliable and their evaluation is representative of basin behavior. This is not the case for pollution retention performance indicators. Their assessment is difficult because of data quality. Field data has high uncertainties. The model is satisfactory for the hydraulic simulation and the evolution of clogging. Improvements are necessary for pollution flow simulation and the acquisition of better quality data is required.