Could alternative energy sources in the transport sector decarbonise the economy without compromising economic growth?

There are numerous challenges that evaluators face when determining the success of urban climate resilience initiatives (e.g., how to attribute impacts to initiatives). Fortunately, a growing body of literature—much of it dealing with climate change adaptation—has emerged which can help address these challenges. This narrative review of academic and grey literature reviews various monitoring and evaluation methods that can assess the inputs, processes, outputs, outcomes, and impacts that result from climate resilience planning and action. Since there is no commonly accepted monitoring and evaluation approach, the literature stresses the importance of acknowledging the context in which resilience is being evaluated, in order to ensure that appropriate methods are chosen. This context includes the ways that the resilience framework and definition chosen for a project constrain and determine the monitoring and evaluation approaches which can be adopted. As a result of this, a blend of quantitative and qualitative approaches is often recommended, with sufficient evidence suggesting that qualitative approaches (e.g., outcome harvesting) are essential. Nuanced approaches to monitoring and evaluation give evaluators additional means of reporting progress, and of demonstrating success, which is especially important as cities begin to implement resilience initiatives in the coming years.     

Antifungal activities against toxigenic Fusarium specie and deoxynivalenol adsorption capacity of ion-exchanged zeolites

Zeolites are often used as adsorbents materials and their loaded cations can be exchanged with metal ions in order to add antimicrobial properties. The aim of this study was to use the 4A zeolite and its derived ion-exchanged forms with Zn²⁺, Li⁺, Cu²⁺ and Co²⁺ in order to evaluate their antifungal properties against Fusarium graminearum, including their capacity in terms of metal ions release, conidia germination and the deoxynivalenol (DON) adsorption. The zeolites ion-exchanged with Li⁺, Cu²⁺, and Co²⁺ showed an excellent antifungal activity against F. graminearum, using an agar diffusion method, with a zone of inhibition observed around the samples of 45.3 ± 0.6 mm, 25.7 ± 1.5 mm, and 24.7 ± 0.6 mm, respectively. Similar results using agar dilution method were found showing significant growth inhibition of F. graminearum for ion-exchanged zeolites with Zn²⁺, Li⁺, Cu²⁺, and Co²⁺. The fungi growth inhibition decreased as zeolite-Cu²⁺>zeolite-Li⁺>zeolite-Co²⁺>zeolite-Zn²⁺. In addition, the conidia germination was strongly affected by ion-exchanged zeolites. With regard to adsorption capacity, results indicate that only zeolite-Li⁺ were capable of DON adsorption significantly (P < 0.001) with 37% at 2 mg mL^?1 concentration. The antifungal effects of the ion-exchanged zeolites can be ascribed to the interactions of the metal ions released from the zeolite structure, especially for zeolite-Li⁺, which showed to be a promising agent against F. graminearum and its toxin.     

Does energy efficiency and trade openness matter for energy transition? Empirical evidence for countries in the Organization for Economic Co-operation and Development

Environment, Development and Sustainability - An energy transition is currently underway around the world, in response to the objectives laid out by international agreements. Since the Kyoto...     

Does financial openness cause the intensification of environmental degradation? New evidence from Latin American and Caribbean countries

Environmental Economics and Policy Studies - The impact of financial openness on environmental degradation, mainly via carbon dioxide emissions, was investigated for a panel of 21 Latin American...     

Ultrasensitive determination of carbendazim in water and orange juice using a carbon paste electrode

A carbon paste electrode was used for the electrochemical quantification of carbendazim in water and orange juice samples. Carbendazim oxidation on the electrode surface was found to be controlled by adsorption. The novel electrochemical procedure for carbendazim quantification employed differential pulse voltammetry using a carbon paste electrode under optimal conditions. Carbendazim oxidation currents were linear at concentrations of 2.84 to 45.44 µg L^?1, with a limit of detection of 0.96 µg L^?1. The proposed method was applied to carbendazim quantification in ultrapurified water, river water, and orange juice. Recovery rates in water and orange juice samples were in the 97%–101% range, indicating that the method can be employed to determine carbendazim in these matrices, with advantages including shorter analysis time and lower cost than routine methods such as chromatography or spectroscopy. The electrode showed good reproducibility, remarkable stability, and especially good surface renewability by simple mechanical polishing. The recovery rates observed were highly concordant with those obtained for high-performance liquid chromatography, having a relative standard deviation of less than 1.3%.     

(210)Pb and composition data of near-surface sediments and interstitial waters evidencing anthropogenic inputs in Amazon River mouth, Macapá, Brazil

Activity profiles of excess ²¹⁰Pb determined in three sediment cores from Amazon River mouth, Macapá city, Brazil, provided the evaluation of sedimentation rates, contributing to a better knowledge of the hydrological conditions in the site that is the capital of Amapá State and is drained by the waters of the huge Amazon River. Chemical data were also determined in the sediments, allowing identify signatures coupled to anthropogenic inputs held in the past in Amapá State. Significant direct relationships between LOI (loss on ignition) and organic matter were found for all sediments profiles. Silica was found to be inversely related to organic matter in the three profiles; its decrease accompanied an increase on the specific surface of the sediments. This relationship was confirmed by a great number of inverse significant correlations among silica and oxides Na₂O, K₂O, CaO, MgO, Al₂O₃, P₂O₅, Fe₂O₃ and MnO. It was possible to identify the role of organic matter on adsorption of several oxides in the core sediments profiles. Apparent sediment mass accumulation rates corresponding to values between 450 and 2510 mg cm⁻² yr⁻¹ were obtained, and are compatible with the results of others studies. The ²¹⁰Pb activities in one sampling point suggested the occurrence of anthropogenic inputs related to the initial period of the mining activities conducted in Serra do Navio, Amapá State, for the commercialization of Mn ores. This was reinforced by the abrupt fluctuations in chemical data obtained for the sediments and composition of the interstitial waters occurring there. The Atlantic hurricane activity also appeared to affect the sedimentation rates in the area, as two different values were recorded in each profile.     

Structure-activity relationships of larvicidal monoterpenes and derivatives against Aedes aegypti Linn

In the search for larvicidal compounds against Aedes aegypti L. (Diptera: Culicidae), a collection of monoterpenes were selected and evaluated. R- and S-limonene exhibited the highest larvicidal potency (LC₅₀ = 27 and 30 ppm, respectively), followed by γ-terpinene (LC₅₀ = 56 ppm) and RS-carvone (LC₅₀ = 118 ppm). Structural characteristics which may contribute to the understanding of the larvicidal activity of monoterpenes were empirically identified. The presence of heteroatoms in the basic hydrocarbon structure decreases larvicidal potency. Conjugated and exo double bonds appear to increase larvicidal potency. Replacement of double bonds by more reactive epoxides decreases the larvicidal potency. The presence of hydroxyls in the cyclic structure resulted in decreased potency, probably due to increased polarity indicanting that lipophilicity seems to play an important role in increasing the larvicidal potency in this set of compounds.     

Experimental and statistical validation of SPME-GC-MS analysis of phenol and chlorophenols in raw and treated water

A procedure based on solid-phase microextraction (SPME) and gas chromatography coupled with mass spectrometry (GC-MS) was developed and validated in order to analyse 10 phenols in water samples. The optimised conditions were obtained using polyacrylate fibre (PA), 20ml of sample volume, 10% NaCl, pH 4.0 and direct extraction at 35 degrees C and 1000rpm, for 40min. The linear range and quantification limits for these compounds by SPME-GC-MS were defined. An evaluation of the main uncertainty sources of this method is included, which allows expanded uncertainties in the 9.4-35% range for the majority of the compounds. The main source of uncertainty is associated with matrix effects. The validated method is suitable for monitoring the production and distribution of potable water and was used, in field trials, for the analysis of samples from main intakes of water (surface or underground) and from water supply system of a large area (Lisbon and neighbour municipalities).     

Effects of soil mechanical resistance on nematode community structure under conventional sugarcane and remaining of Atlantic Forest

Nematodes present high potential as a biological indicator of soil quality. In this work, it was evaluated relations between soil physical properties and nematode community under sugarcane cropping and remaining of Atlantic Forest areas in Northeastern Pernambuco, Brazil. Soil samples were collected from September to November 2009 along two 200-m transects in both remaining of Atlantic Forest and sugarcane field at deeps of 0–10, 10–20, 20–30, 30–40, and 40–50 cm. For soil characterization, it was carried out analysis of soil size, water content, total porosity, bulk density, and particle density. The level of soil mechanical resistance was evaluated through a digital penetrometer. Nematodes were extracted per 300 cm³ of soil through centrifugal flotation in sucrose being quantified, classified according trophic habit, and identified in level of genus or family. Data were analyzed using Pearson correlation at 5% of probability. Geostatistical analysis showed that the penetration resistance, water content, total porosity, and bulk density on both forest and cultivated area exhibited spatial dependence at the sampled scale, and their experimental semivariograms were fitted to spherical and exponential models. In forest area, the ectoparasites and free-living nematodes exhibited spherical model. In sugarcane field, the soil nematodes exhibited pure nugget effect. Pratylenchus sp. and Helicotylenchus sp. were prevalent in sugarcane field, but in forest, there was prevalence of Dorylaimidae and Rhabditidae. Total amount of nematode did not differ between environments; however, community trophic structure in forest presented prevalence of free-living nematodes: omnivores followed by bacterial-feeding soil nematodes, while plant-feeding nematodes were prevalent in sugarcane field. The nematode diversity was higher in the remaining of Atlantic Forest. However, the soil mechanical resistance was higher under sugarcane cropping, affecting more directly the free-living nematodes; especially Dorylaimidae which was the most sensible to changes in soil physical properties.