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41.
Determination of selected neonicotinoid insecticides by liquid chromatography with thermal lens spectrometric detection 总被引:1,自引:0,他引:1
Valéria Guzsvány Azamela Madžgalj Polonca Trebše Ferenc Gaál Mladen Franko 《Environmental Chemistry Letters》2007,5(4):203-208
We studied the analysis of trace amounts of neonicotinoid insecticides by liquid chromatography coupled with a thermal lens
spectrometric detector (TLS). This multi-residue analysis method is based on the reversed phase separation on C18 column, isocratic elution and collinear dual beam TLS detection. The insecticides thiamethoxam, imidacloprid, acetamiprid
and thiacloprid were detected with retention times of 4.4, 5.7, 6.5 and 8.5 min and limits of quantifications of 50, 89, 10,
and 25 μg/L, respectively. The retention times agreed well with those obtained by the same chromatographic method but using
a diode-array detector (DAD). The limits of quantifications for imidacloprid were identical in both techniques. However, the
limits of quantifications for thiamethoxam, acetamiprid and thiacloprid were up to 8.5 times lower using the TLS detector
compared to the diode-array detector. The applicability of the developed procedure was tested on spiked river water and potato
samples. 相似文献
42.
In this paper, we present the hierarchical variable dependencies that were obtained from raw data with the use of two machine learning techniques on an ecological data set. The data set contains features of field margins and the corresponding number of spider species inhabiting them. This data set was used before by domain experts to construct a fuzzy qualitative model with hierarchical variable dependencies, which we use for comparison with our results. One of the machine learning methods constructs a hierarchical structure similar to the one in the experts’ model, while revealing some additional interesting relations of environmental features with respect to the number of spider species. The other method constructs a different hierarchy from the one proposed by the experts, which, according to our classification performance experiments, might be even more appropriate. 相似文献
43.
A palaeoecological study was conducted to investigate past environmental conditions and vegetation dynamics around the southwestern Ljubljana Moor. In order to find potential regularities and/or dependencies among co-existent plant species through time, different machine learning methods were applied to pollen records from the cores taken at Bistra and Ho?evarica. The data comprised relative pollen frequencies of the most common plant genera/families at particular core depths that correspond to particular ages in the Early and Mid Holocene periods. The applied methods include equation discovery and hierarchical clustering. Both methods have found plausible and explainable relationships among identified plant genera/families. 相似文献
44.
45.
Dejan Bogdanović Vladimir Stanković Snežana Urošević Miloš Stojanović 《International journal of occupational safety and ergonomics》2016,22(4):479-486
Ranking of workplaces with respect to working conditions is very significant for each company. It indicates the positions where employees are most exposed to adverse effects resulting from the working environment, which endangers their health. This article presents the results obtained for 12 different production workplaces in the copper mining and smelting complex RTB Bor – ‘Veliki Krivelj’ open pit, based on six parameters measured regularly which defined the following working environment conditions: air temperature, light, noise, dustiness, chemical hazards and vibrations. The ranking of workplaces has been performed by PROMETHEE/GAIA. Additional optimization of workplaces is done by PROMETHEE V with the given limits related to maximum permitted values for working environment parameters. The obtained results indicate that the most difficult workplace is on the excavation location (excavator operator). This method can be successfully used for solving similar kinds of problems, in order to improve working conditions. 相似文献
46.
Dušan Žagar Nataša Sirnik Matjaž Četina Milena Horvat Jože Kotnik Nives Ogrinc Ian M. Hedgecock Sergio Cinnirella Francesco De Simone Christian N. Gencarelli Nicola Pirrone 《Environmental science and pollution research international》2014,21(6):4081-4094
Mass balance of contaminants can provide useful information on the processes that influence their concentrations in various environmental compartments. The most important sources, sinks and the equilibrium or non-equilibrium state of the contaminant in individual environmental compartments can also be identified. Using the latest mercury speciation data, the results of numerical models and the results of recent studies on mercury transport and transformation processes in the marine environment, we have re-evaluated the total mercury (HgT) mass balance in the Mediterranean Sea. New calculations have been performed employing three distinct marine layers: the surface layer, the thermocline and the deep sea. New transport mechanisms, deep water formation and density-driven sinking and upwelling, were included in the mass balance calculations. The most recent data have even enabled the calculation of an approximate methylmercury (MeHg) mass balance. HgT is well balanced in the entire Mediterranean, and the discrepancies between inputs and outputs in individual layers do not exceed 20 %. The MeHg balance shows larger discrepancies between gains and losses due to measurement uncertainties and gaps in our knowledge of Hg species transformation processes. Nonetheless, the main sources and sinks of HgT (deposition and evasion) and MeHg (fluxes from sediment, outflow through the Gibraltar Strait) are in accordance with previous studies on mercury in the Mediterranean Basin. Mercury in the Mediterranean fish harvest is the second largest MeHg sink; about 300 kg of this toxic substance is consumed annually with sea food. 相似文献
47.
A. Alexiou P. Kostarakis V. N. Christofilakis T. Zervos A. A. Alexandridis K. Dangakis C. Soras V. V. Petrović B. M. Kolundžija A. R. Dordević 《The Environmentalist》2005,25(2-4):215-221
Summary The performance of a cellular phone commercial helical antenna at 900~MHz band, both in free space and in the presence of
a human head phantom was studied. Numerical simulation of the phone model for the latter case has been performed giving 3D
radiation diagrams. The effect of the phantom head on radiation diagrams is presented. The relative amount of the EM power
absorbed in the head was obtained for several distances of the phone. Measurements were carried out in a RF anechoic chamber
using standard horn antennas and a calibrated measuring system. Absolute radiation patterns of the antenna gain were obtained
in the three principal planes. Significant reduction of the absorbed power could be achieved just by moving the phone 1 cm
away from the head. 相似文献
48.
49.
František Vožeh Antonín Doněk Jan Cendelín Ivana Korelusová Jan Vrba 《The Environmentalist》2007,27(4):501-504
The effect of long-term exposure to high frequency electromagnetic field (HF EMF) on some somatic and neural characteristics
was studied in neurodefective Lurcher mutant (+/Lc) and normal wild type mice (+/+). Both newborn and young adult (3 months)
animals derived from two strains (C3H, B6CBA) were exposed to HF EMF (870 MHz) from 1st to 21st day or from 91st to 120th
day respectively. In animals of both groups and controls we observed the development of body weight. Moreover, in the HF EMF
exposed adult B6CBA animals we studied spatial learning ability, motor functions and the CNS excitability. To investigate
specific energy absorption rate (SAR) in experimental animals we have done the basic 3D calculations of the electromagnetic
energy distribution in the simplified model of the mouse. The HF EMF exposed animals exhibited mild differences of body weight
between them and unexposed controls. The long-term exposure to HF EMF did not significantly influence the ability to learn
in the Morris water maze. However, significant lower swimming speed was found in the irradiated +/Lc as well as lower motor
activity of +/+ in the open field when compared to controls. No significant differences were found between HF EMF irradiated
animals and controls in examination of the CNS excitability and motor functions. 相似文献
50.
Irena Ciglenečki Srđan Pichler Esad Prohić Božena Ćosović 《Water, Air, & Soil Pollution: Focus》2006,6(5-6):537-545
Geochemical, mineralogical and sedimentological analyses were carried out to contrast two different sites (respectively characterized
by permanently oxic and anoxic conditions) in a small, meromictic, seawater lake. In fact, due to relatively high organic
matter content, and reduced water exchange, the Rogoznica Lake has almost permanent anoxic conditions below the depth of 12 m,
where sediment can be considered an anoxic–sulphidic sedimentary environment. Different water column and sediments redox conditions
affect the distribution and speciation of major redox-sensitive metals (Fe, Mn, Mo), reduced sulphur species (RSS) and dissolved
organic C (DOC). Trace metals, especially those that accumulate in anoxic–sulphidic environments (Fe, Mo) showed a marked
enrichment in the solid phase, whereas the low solubility of sulphides leads to low porewater concentrations. The relatively
high sedimentary enrichment of Mo (up to 81 mg/kg) also confirms highly anoxic conditions within the Rogoznica Lake sediments.
Results clearly show that chemical species within the sediments will tend towards equilibrium between porewater and solid
phase according the prevailing environment conditions such as redox, pH, salinity, DOC. 相似文献