全文获取类型
收费全文 | 1318篇 |
免费 | 58篇 |
国内免费 | 480篇 |
专业分类
安全科学 | 76篇 |
废物处理 | 81篇 |
环保管理 | 84篇 |
综合类 | 744篇 |
基础理论 | 225篇 |
污染及防治 | 523篇 |
评价与监测 | 46篇 |
社会与环境 | 45篇 |
灾害及防治 | 32篇 |
出版年
2023年 | 27篇 |
2022年 | 72篇 |
2021年 | 77篇 |
2020年 | 35篇 |
2019年 | 43篇 |
2018年 | 49篇 |
2017年 | 62篇 |
2016年 | 63篇 |
2015年 | 67篇 |
2014年 | 108篇 |
2013年 | 113篇 |
2012年 | 100篇 |
2011年 | 122篇 |
2010年 | 82篇 |
2009年 | 102篇 |
2008年 | 100篇 |
2007年 | 90篇 |
2006年 | 60篇 |
2005年 | 47篇 |
2004年 | 49篇 |
2003年 | 48篇 |
2002年 | 27篇 |
2001年 | 41篇 |
2000年 | 41篇 |
1999年 | 35篇 |
1998年 | 34篇 |
1997年 | 24篇 |
1996年 | 24篇 |
1995年 | 19篇 |
1994年 | 15篇 |
1993年 | 16篇 |
1992年 | 8篇 |
1991年 | 16篇 |
1990年 | 16篇 |
1989年 | 6篇 |
1988年 | 10篇 |
1987年 | 2篇 |
1986年 | 2篇 |
1985年 | 2篇 |
1983年 | 1篇 |
1981年 | 1篇 |
排序方式: 共有1856条查询结果,搜索用时 31 毫秒
11.
Juan Huang Jun Xiao Yang Guo Wenzu Guan Chong Cao Chunni Yan Mingyu Wang 《环境科学学报(英文版)》2020,32(1):319-330
Silver nanoparticles(AgNPs) have been widely used in many fields,which raised concerns about potential threats to biological sewage treatment systems.In this study,the phosphorus removal performance,enzymatic activity and microbial population dynamics in constructed wetlands(CWs) were evaluated under a long-term exposure to Ag NPs(0,50,and 200 μg/L) for 450 days.Results have shown that Ag NPs inhibited the phosphorus removal efficiency in a short-term exposure,whereas caused no obviously negative effects from a long-term perspective.Moreover,in the coexisting CW system of Ag NPs and phosphorus,competition exhibited in the initial exposure phase,however,cooperation between them was observed in later phase.Enzymatic activity of acid-phosphatase at the moderate temperature(10–20°C) was visibly higher than that at the high temperature(20–30℃) and CWs with Ag NPs addition had no appreciable differences compared with the control.High-throughput sequencing results indicated that the microbial richness,diversity and composition of CWs were distinctly affected with the extension of exposure time at different Ag NPs levels.However,the phosphorus removal performance of CWs did not decline with the decrease of polyphosphate accumulating organisms(PAOs),which also confirmed that adsorption precipitation was the main way of phosphorus removal in CWs.The study suggested that Ag NPs and phosphorus could be removed synergistically in the coexistence system.This work has some reference for evaluating the influences of Ag NPs on the phosphorus removal and the interrelation between them in CWs. 相似文献
12.
Dong Cao Ziyu Rao Fanglan Geng Hongyun Niu Yali Shi Yaqi Cai Yuehui Kang 《环境科学学报(英文版)》2020,32(11):67-74
Molecular level characterization of dissolved organic sulfur (DOS) by electrospray ionization-Fourier transform ion cyclotron resonance mass spectrometry (ESI-FTICR MS) is necessary for further understanding of the role of DOS in the environment. Here, ESI spray solvent, a key parameter for ion production during ESI process, was investigated for its effect on the molecular characterization of DOS by ESI-FTICR MS. 100% MeOH as spray solvent was found for the first time to remarkably enhance the ionization efficiency of the majority of CHOS-molecules in NOM, which facilitated a total of 1473 CHOS-molecular formulas with one sulfur atom to be detected. The number of CHOS-molecular formulas obtained using 100%MeOH as spray solvent increased notably over 740 in comparison with those using 50% MeOH aqueous solution (731) or 50% ACN aqueous solution (653). Moreover, due to the enhancement of ionization efficiency of DOS during ESI processes, the tandem mass spectra of the NOM CHOS-molecules could be easily obtained using 100% MeOH as spray solvent, which were hardly obtained using 50% MeOH aqueous solution as spray solvent. The results of the tandem mass spectra suggested the first discovery of organosulfates or sulfonic acids in Suwannee River NOM sample. A simple method based on 100% MeOH as ESI spray solvent for advanced molecular characterization of DOS by ESI-FTICR MS was proposed and applied, and the results revealed more molecular information of DOS in sea DOM samples. 相似文献
13.
Yanqin Ren Gehui Wang Jianjun Li Can Wu Cong Cao Jiayuan Wang Lu Zhang Fan Meng Hong Li 《环境科学学报(英文版)》2018,30(9):32-44
Size-resolved biogenic secondary organic aerosols(BSOA) derived from isoprene and monoterpene photooxidation in Qinghai Lake, Tibetan Plateau(a continental background site) and five cities of China were measured using gas chromatography/mass spectrometry(GC/MS). Concentrations of the determined BSOA are higher in the cities than in the background and are also higher in summer than in winter. Moreover, strong positive correlations(R2= 0.44–0.90) between BSOA and sulfate were found at the six sites,suggesting that anthropogenic pollution(i.e., sulfate) could enhance SOA formation,because sulfate provides a surface favorable for acid-catalyzed formation of BSOA. Size distribution measurements showed that most of the determined SOA tracers are enriched in the fine mode( 3.3 μm) except for cis-pinic and cis-pinonic acids, both presented a comparable mass in the fine and coarse( 3.3 μm) modes, respectively. Mass ratio of oxidation products derived from isoprene to those from monoterpene in the five urban regions during summer are much less than those in Qinghai Lake region. In addition, in the five urban regions relative abundances of monoterpene oxidation products to SOA are much higher than those of isoprene. Such phenomena suggest that BSOA derived from monoterpenes are more abundant than those from isoprene in Chinese urban areas. 相似文献
14.
The research, focused on the specific interactions among seven plant secondary compounds and aphids, was carried out and the preliminary results showed: (1) "T-typed tube method" was regarded as the best method compared with others designed to observe the interactions. (2) Cabbage aphid was able to be attracted by laurolene while it was not susceptible to α-pinene, β-pinene and diamylene. (3) Gossypol, a major secondary substance in cotton, was able to be implicated as feeding attractant to cotton aphid. (4) Rutin might be implicated repellent to cotton aphid. 相似文献
15.
盐酸付玫瑰苯胺是三苯甲烷类染料,分子中存在的共轭体系使其具有以下特性:1.本身带色;2.随介质的pH变化产生显著的颜色效应,pH值越高,颜色越深,pH值越低,颜色越浅;3.对光和水洗的坚牢度较差;4.可发生重氮化反应;5.杂质使其颜色加深。 相似文献
16.
OnthedeterminationofnitrousoxideemissionfactorduringbiomassburningCaoMeiqiu;ZhuangYahui(ResearchCenterforEco-EnvironmentalSci... 相似文献
17.
18.
SBR法处理中药材有机废水工艺研究 总被引:2,自引:0,他引:2
应用SBR法对中药材有机废水进行了研究。考察了CODCR、BOD5、SS、NH3-H的处理效果,以及PH、水温、污泥负荷等条件对去除率的影响。运行结果表明,PHO 6.0-9.0、t为15-30℃、污沁荷0.3kgBOD5/kgMLSS.d,运行程序:进水0.5h(限制曝气)、曝气10h、脱氮1.5h,沉降0.5h,排水0.5h、闲置11h,周期时间24h时CODCR去除率88%、BOD594%、 相似文献
19.
SO2 和氟化物对农作物的危害可通过症状、镜检和受害叶片的化学分析来鉴别 ,并从风向、与污染源距离、障碍物和叶片成熟程度几方面与作物病虫等影响因素相区别。排放浓度、接触时和作物本身抗性是影响危害程度的主要因素。应从治理污染、选种抗性强树木、避开作物敏感生育期、合理种植、加强施肥等方面采取措施加以防治 相似文献
20.
此文分析在二辊楔横轧中轧制各类轴肩的过程。在假想工件轴端固定的图上确定楔侧面截面轮廓形状,再通过叠加轴向刚性移动量确定各截面实际位置,比较直观简便地设计出轧制轴肩的辊面上的成形曲面。最后归纳了设计步骤。 相似文献