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21.
Electrothermal atomic absorption spectrometry methods with Zeeman effect background correction (Z-GFAAS) for determination
of As, Sb, Se, Ag, Cd, Pb, Cu, Fe, Zn, Cr, and Ni in water and sludge samples were developed. The measurements using Z-GFAAS
and variable magnetic field at the three-field dynamic mode permit the sensitivity adaptation for higher analytical concentrations.
Calibration ranges were expanded over two orders of magnitude within one measurement run by the applying three-field dynamic
mode of this correction system. There are presented calibration data, furnace programs, modifiers, and microwave digestion
programs of the obviously monitored elements in the environmental samples. Very low detection limits (3σ criterion) were obtained.
Quality assurance was checked by the suitable CRM. The study brings simultaneous determination of the samples with different
element concentration range and different sample matrixes, as an important application information for an analyst working
in the area of the eco-analytical research. 相似文献
22.
?ehnaz ?ener Erhan Sener Remzi Karag��zel 《Environmental monitoring and assessment》2011,173(1-4):533-554
The appropriate site selection for waste disposal is one of the major problems in waste management. Also, many environmental, economical, and political considerations must be adhered to. In this study, landfill site selection is performed using the Geographic Information System (GIS), the Analytical Hierarchy Process (AHP), and the remote sensing methods for the Senirkent?CUluborlu Basin. The basin is located in the E?irdir Lake catchment area, which is one of the most important fresh water in Turkey. So, waste management must be regulated in the basin. For this aim, ten different criteria (lithology, surface water, aquifer, groundwater depth, land use, lineaments, aspect, elevation, slope, and distance to roads) are examined in relation to landfill site selection. Each criterion was identified and weighted using AHP. Then, each criterion is mapped using the GIS technique, and a suitability map is prepared by overlay analyses. The results indicate that 96.3% of the area in the basin is unsuitable; 1.6%, moderately suitable; and 2.1%, most suitable. Finally, suitable regions in the basin are determined for solid waste landfill disposal and checked in the field. The selected and investigated regions are considered to be suitable for the landfill. 相似文献
23.
Clarisse Mariet Andr�� Gaudry Sophie Ayrault M��lanie Moskura Franck Denayer Nadine Bernard 《Environmental monitoring and assessment》2011,174(1-4):107-118
An active biomonitoring of the heavy metals pollution experiment was undertaken by means of the bryophyte species Scleropodium purum transplanted at three different sites exposed to rural, traffic, or industrial influences. Concentrations of about 40 elements in S. purum were determined by instrumental neutron activation analysis and inductively coupled plasma mass spectrometry. Accumulation rates of heavy metals were determined in the three sites. These accumulation rates in polluted sites were matched together and also to those recorded at the rural site. The changes of the accumulation rate of heavy metals in S. purum versus their concentrations in PM10 particles simultaneously collected above show some different accumulation properties of S. purum according to elements and sites. S. purum has a weak efficiency in the three sites to accumulate elements like V, Cr, Cu, Zn, As, Se, Sb, and Pb originating from atmospheric hot sources generally enriched in particulates matter (PM10), whereas it is particularly high for Br, Th, and Rb. For other elements, Co, La, Ce, and Hf, and rare earth elements, Fe, Sr, Nb, Ti, Al, and Sc, the collection efficiency by S. purum is intermediate. In the industrial site Dunkerque, a magnification of the collection efficiency by S. purum for elements originating from steel and aluminum productions and petroleum refinement suggests that these metals could be enriched in coarse particles with a better accumulation by the bryophyte with respect to PM10. 相似文献
24.
25.
Türk Çulha S Koçbaş F Gündoǧdu A Baki B Culha M Topçuoǧlu S 《Environmental monitoring and assessment》2011,183(1-4):525-529
Concentration of the some heavy metals (Co, Cu, Fe, Ni, Pb and Zn) Mediterranean mussel Mytilus galloprovincialis from Yalova (Marmara Sea) were investigated seasonally. The mean concentrations of Co, Cu, Fe, Ni, Pb and Zn in the soft tissues were 4.08 ± 0.67, 5.54 ± 0.59, 156.72 ± 20.18, 3.71 ± 1.14, 2.92 ± 0.51 and 106.23 ± 5.66 mg kg(?-1) dry weights, respectively. There were no significant differences between the metal concentrations among the seasons (P > 0.05). The mean Pb and Zn concentrations were higher than the acceptable limit proposed by International Turkish standards. 相似文献
26.
Marion Valeix Hervé Fritz Andrew J. Loveridge Zeke Davidson Jane E. Hunt Felix Murindagomo David W. Macdonald 《Behavioral ecology and sociobiology》2009,63(10):1483-1494
A central question in the study of predator–prey relationships is to what extent prey behaviour is determined by avoidance
of predators. Here, we test whether the long-term risk of encountering lions and the presence of lions in the vicinity influence
the behaviour of large African herbivores at waterholes through avoidance of high-risk areas, increases in group size, changes
in temporal niche or changes in the time spent in waterhole areas. In Hwange National Park, Zimbabwe, we monitored waterholes
to study the behaviour of nine herbivore species under different risks of encountering lions. We radio-collared 26 lions in
the study area which provided the opportunity to monitor whether lions were present during observation sessions and to map
longer-term seasonal landscapes of risk of encountering lions. Our results show that the preferred prey species for lions
(buffalo, kudu and giraffe) avoided risky waterholes. Group size increased as encounter risk increased for only two species
(wildebeest and zebra), but this effect was not strong. Interestingly, buffalo avoided the hours of the day which are dangerous
when the long-term and short-term risks of encountering lions were high, and all species showed avoidance of waterhole use
at night times when lions were in the vicinity. This illustrates well how prey can make temporal adjustments to avoid dangerous
periods coinciding with predator hunting. Additionally, many herbivores spent more time accessing water to drink when the
long- and short-term risks of encountering lions were high, and they showed longer potential drinking time when the long-term
risk of encountering lions was high, suggesting higher levels of vigilance. This study illustrates the diversity of behavioural
adjustments to the risk of encountering a predator and how prey respond differently to temporal variations in this risk. 相似文献
27.
28.
Jofré MB Antón RI Caviedes-Vidal E 《Environmental science and pollution research international》2011,19(7):2889-2897
Purpose
Heavy metals have been detected in water and sediments from the Embalse La Florida, an artificial lake in the arid region of San Luis province, Argentina, representing one of the few sources of permanent water for reproduction of native anuran species. This study assesses lead (Pb) and cadmium (Cd) concentrations in the anuran species found in this water reservoir as well as differences between compounds, species and sites of collection.Methods
Adult anuran amphibians were collected on the north and south shores of the Embalse La Florida and Pb and Cd concentrations were measured in whole body homogenates digested using wet ashing techniques.Results
All individuals of the six species assayed had detectable levels of Pb and Cd that ranged from 1.19 to 5.57 ??g/g dry mass and from 1.09 to 6.86 ??g/g dry mass, respectively. Anuran amphibians collected in the more contaminated south shore accumulated 21% more Cd and 40% more Pb than individuals from the less altered north shore. Cd and Pb accumulation was not significantly correlated with the concentration in water at the site of collection.Conclusions
Amphibians of the Embalse La Florida accumulate Cd and Pb. Between and within species, differences were detected in Cd and Pb concentrations. Differences in metal concentrations between species, metals, and individuals collected on shores of the Embalse La Florida with different contamination, were detected. Therefore, it is crucial to implement adequate policies to protect amphibians from the accelerated urban development experienced in this location. 相似文献29.
Pérez IA Sánchez ML García MA Pardo N 《Environmental science and pollution research international》2011,19(7):3015-3027
Purpose
The impact of CO2 urban plume in a rural area was investigated by concentrations recorded near surface.Methods
CO2 dry concentrations at three levels near surface were recorded for about 8 months at a rural site. Daily cycles were obtained and directional analysis was made with percentiles. Several functions were used to fit background and plume concentrations and the goodness of fit was evaluated with different statistics, which were also compared.Results
Daily cycle showed a difference of around 2 ppm during the night between the lowest (1.8 m) and the highest (8.3 m) levels. Weighting functions of the directional analysis revealed the influence of the Valladolid urban plume. Two regions were established, with local factors prevailing below 3 m?s?1 and transport dominating above 6 m?s?1. The best fit was achieved with a quadratic function for the background and a cubic function for the plume due to the lack of symmetry observed. Gamma and Weibull distributions were also successfully used. Some statistics, such as the root mean square error (RMSE), stood out when evaluating the goodness of fit, whilst others were discarded due to their extremely low values and the lack of sensitivity against the functions used. Finally, a comprehensive metric merging several statistics was also tested with slight differences against RMSE. 相似文献30.
Rodica Chiriac Jean Carré Yves Perrodin Hervé Vaillant Santiago Gasso Philippe Miele 《Atmospheric environment (Oxford, England : 1994)》2009,43(11):1926-1931
The dispersion of VOCs emitted by a municipal solid waste landfill was studied for a period of over one year. Sixteen VOCs were monitored: linear alkanes from C7 to C11, BTEX, trimethylbenzene, trichlorethylene, tetrachlorethylene, α and β-pinenes, limonene. The analytical procedure was first comprised of static long-term sampling of about 2 months using radial diffusion Radiello tubes containing activated carbon, followed by extraction by solvent (i.e. CS2) and GC/MS analysis. The results were initially analysed on the basis of the total concentration of the quantified VOCs, then by examining the concentrations of certain selected compounds. The influence of different parameters such as operating conditions, meteorological conditions and site morphology was highlighted on the basis of total VOC concentrations. In order to study the VOC's dispersion more closely, 5 compounds were chosen: toluene, benzene, limonene, and the sum trichlorethylene + tetrachlorethylene, as a “marker”, to verify the origin of the VOCs emitted. The results showed that the main source of VOCs is the open cell and lead to different hypotheses on interferences from neighbouring sources and to the proposal of solutions to limit the emission of VOCs and their dispersion. To our knowledge, this type of study has not been accomplished until this day. 相似文献