Heavy metal accumulation and distribution in Phragmites australis seedlings tissues originating from natural and urban catchment

The retention of heavy metal (HM) was studied in root and rhizomes (BLG), stems (ST), and leaves (LF) of Phragmites australis (common reed) seedlings collected from different locations, differing in the scale of anthropogenic interference. The analysis includes the reference samples of sediments in uncontaminated lake Garczonki and contaminated roadside ditch in Cieplewo. The concentrations of Zn, Cu, Pb, Cd, Ni, and Cr were analyzed in plant tissues and sediments using the atomic absorption spectrometry and inductively coupled plasma mass spectrometry. The general assessment of sediments collected in the Garczonki lake showed a good environmental status; while in the roadside ditch in Cieplewo, the sediments were considerably polluted with HM. In the first stage of plant growth, all of the analyzed HMs are mainly inhibited by BLG system. The decreasing trend of elements was as follows: BLG > ST > LF. The organs followed different decreasing trends of HM concentration; the trend Zn > Cu > Ni > Cr > Pb > Cd was found in ST and LF for the Garczonki lake seedlings and for BLG and LF for the roadside ditch in Cieplewo seedlings. Zn showed the highest concentration, while Cd the lowest concentration in each of the examined organs. The bioaccumulation factor indicated the higher mobility of HM in seedlings in the Garczonki lake than in the roadside ditch in Cieplewo. The morphological studies suggest the good state and health of seedling from both sites; however, the reduction of root hair surface was observed for the roadside ditch seedlings. The anatomical studies present changes in the size of the nucleus and count of chloroplasts in LF. No reaction on HM contamination sediments in the seedlings from the roadside ditch in Cieplewo in the aerenchyma was noted. Potentially, both types of seedlings can be used to decontaminate environments rich in HM. However, the level of HM absorbed by seedlings (in the first stage of growth) should be considered due to the behavior in the target phytoremediation site.

     

A review of municipal solid waste composition and quantities in Poland

A review of results of the research involving the quantitative and composition analyses of household waste conducted in Poland in recent years is presented in this paper. For these analyses various methodologies have been employed, as there is not one obligatory methodology how to characterise municipal solid waste. The results of the research in large Polish cities indicate great variability, which is difficult to be reasonably explained. This situation is affected by a number of factors, such as various methods and places for sample collection, various methods for tests, fractional character of most of the studies (studies carried out only in some periods during a year). Consequently, it is neither possible to measurably compare their results, nor to generalise them. Hence, within this article only individual data for large cities is provided. It is therefore necessary to standardise methodology for such analyses in Europe, taking into account local variability (such as different housing patterns, climate and waste collection schemes) to allow comparison of results.Reported yearly household waste generation in Polish cities varies from 238 to 309 kg per inhabitant. Biodegradable waste is a strongly dominated fraction in household waste from Polish cities, followed by paper/cardboard and plastics. Historical data shows that waste composition has undergone profound changes, the most significant being an increase of the share of plastics and decrease of fine fraction. The presented data indicates that waste composition strongly depends on the type of housing and its heating system. In the new multi-family buildings with central heating the share of paper and plastics is higher than in old houses with individual heating. In the latter ones the share of fine fraction is higher.     

Factors determining the fluctuation of fluoride concentrations in PM10 aerosols in the urbanized coastal area of the Baltic Sea (Gdynia, Poland)

Fluoride concentrations were determined in PM10 samples collected in the urbanized coastal area of the Baltic Sea (Gdynia) in the period between 1 August 2008 and 8 January 2010. F^? concentrations remained within the range of 0.4–36.6 ng?·?m^?3. The economic transformations which have taken place in Poland increasing ecological awareness have had an excellent effect on the levels of fluoride pollution in the air of the studied region. In our measurements, fluoride concentrations increased in wintertime, when air temperature dropped, at low wind speeds (<1 m?·?s^?1) and with low dispersion of pollutants originating from local sources (traffic, industry, domestic heating). At times when wind speed grew to >10 m?·?s^?1, fluorides were related to marine aerosols or else brought from distant sources. Apart from wind speed and air temperature, other significant meteorological parameters which determined the variability of F^? turned out to be air humidity and precipitation volume. Aerosols were washed out effectively, even with small precipitation (h?=?4 mm), and if a dry period lasted for several days, their concentrations grew rapidly to over 30.0 ng?·?m^?3.     

Control of upland bank erosion through tidal marsh construction on restored shores: Application in the maryland portion of Chesapeake Bay

During the period of 1972 through 1993, Environmental Concern Inc. (EC) and its recent (1989) affiliate Environmental Construction Company (ECC) have completed 216 marsh construction projects to control upland bank erosion in tributaries of the Maryland portion of Chesapeake Bay. Of these projects, 26 have involved marsh construction on unaltered existing shores and 190 have utilized marsh construction on shores that have been restored to former increased elevations through shoreline filling and grading. This paper describes the latter restoration technique. Throughout the 21-year period of applying the technique for long-term upland bank erosion control, refinements to the design standards and criteria for site suitability have been made so as to optimize its successful application. As a result of this experience, a reliable bioengineering restoration technique has evolved to control upland bank erosion. This paper describes the details of this successful technique through a review of: (1) its objectives and benefits, (2) suitability of sites for its application, (3) the design of its shore restoration, (4) its construction, (5) its maintenance, and (6) comparison of its cost with those of structural techniques for bank erosion control. Although the technique has only been applied in the Maryland portions of Chesapeake Bay, its applicability should, with modifications, be broadly applicable to all water bodies.     

Genotoxicological effects of some phenoxyherbicides and their metabolites on Bacillus subtilis M45 Rec- and H17 Rec+ strains

Because they are used in a number of commercial preparations phenoxyacetic acids and their salts can occur in wastewater. During their degradation genotoxic substances may be created. The results of investigations of biodegradability and genotoxicity of some phenoxyherbicides are presented. Commercial formulations of 2,4-D (Aminopielik 720) and MCPA (Chwastox Extra) were the substrates studied. Biodegradation tests were conducted according to OECD guidelines for testing of chemicals--confirmatory test (OECD Method 303 A). Genotoxicity tests were conducted with Bacillus subtilis strains according to the method of [Chemical Mutagens, vol. 6, Plenum Press. New York, 1980, p. 149]. Genotoxicity of biodegradation products was also studied. Both commercial formulations were biodegradable. Aminopielik 720 was potentially genotoxic but only at great concentrations while Chwastox Extra was not genotoxic. Biodegradation products of neither compound were genotoxic.     

Compliance and Emissions Trading under the Kyoto Protocol: Rules for Uncertain Inventories

A solution is proposed for proving compliance with emission targets and for emissions trading in the event of uncertainties in reported emission inventories. The solution is based on the undershooting concept, from which the mathematical conditions for both proving compliance with a risk α and calculating effective emissions for trading are derived. Based on the reported emission units, the number of permits granted is reduced in proportion to the uncertainty in the inventory. A country whose inventory has higher uncertainty is thereby allotted fewer permits than a country with the same inventory but smaller uncertainty.     

A framework for analysis of contamination on human and ecological receptors at DOE hazardous waste site buffer lands

This article discusses a framework and tools for evaluating ecological resources and the effects of cleanup on hazardous waste sites, particularly those with ecological buffer lands. Environmental professionals are faced with assessing the risks of contamination to humans and ecological receptors (organisms and ecosystems) at hazardous waste sites. While exposure assessment has focused largely on human receptors, environmental managers have recently taken a broader view, recognizing the intrinsic value and aesthetic importance of ecological resources and services, and of including a range of stakeholders in remediation decisions. The assessment process involves understanding exposure pathways from source to receptor, and determining how best to interdict these pathways. Environmental characterization and exposure assessment, indicator and biomarker identification, and biomonitoring and surveillance are the major components of ecological assessments. Using the Department of Energy as a case study, this article offers a framework for ecological exposure assessment, recognizing that humans are important components of ecosystems and, like other biota, are exposed to contaminants that move through environmental media. © 2007 Wiley Periodicals, Inc.     

Efficiency of energy delivery systems: I. An economic and energy analysis

Energy-return-on-investment (ERI) analysis is a variation of more traditional cost-benefit analyses, a variation that is particularly important in times of diminishing fuel resources. We present a simple set of procedures for ERI analysis and apply those procedures to central New York State, where there is a proposal for a new 870 MW_e coal-fired generating station. We compared the energy and dollar costs of building that facility with the costs of an alternative comprehensive regional program of insulation. The analysis showed that regional insulation was more efficient in conserving energy than the plant was in providing it by at least a factor of 4 in economic terms and by a factor of more than 15 when viewed as energy returned on energy invested.     

Method of Testing the Penetration of Acid Solutions Through Safety Gloves

Because they cause burns that are difficult to heal, acids are dangerous, and steps should be taken to ensure that the human skin does not come into contact with them. For this purpose safety gloves are generally used by workers who have to handle acids. Such gloves need to be tested to ensure that they are acid resistant. Standard EN 374 (European Committee for Standardization [CEN], 1993c) specifies a method of testing the permeation of liquid chemicals, on a molecular level, through glove material, but it may be difficult to ensure the fitness of the joints of a two-compartment cell, when gloves are lined with jersey. To deal with this a simple pH-meter method to test the permeation of acid and alkali solutions through safety gloves has been developed. The permeation of H₂S0₄, HCI, HN0₃, and CH₃COOH through gloves made from neoprene, nitrile, and PVC was tested. This method seems to be simple and economical.