Modeling of n-butane ignition, combustion, and preflame oxidation in the 20-l vessel

The objective of the study reported herein is to simulate various physical and chemical phenomena accompanying fuel-rich n-butane–oxygen mixture preparation, ignition, preflame oxidation, and combustion in the standard 20-l explosion vessel, by applying mathematical models. Based on the computational fluid dynamics (CFD) simulations of the mixing process and natural convection of the ignition kernel, as well as on the analysis of the detailed reaction mechanism of n-butane oxidation, laminar flame propagation, and self-ignition, possible explanations for the phenomena observed experimentally have been suggested. The results of the study indicate that seemingly inflammable mixtures can become hazardous depending on the mixture preparation procedure and forced ignition timing.     

Review of ozone and temperature lidar validations performed within the framework of the Network for the Detection of Stratospheric Change

The use of assimilation tools for satellite validation requires true estimates of the accuracy of the reference data. Since its inception, the Network for Detection of Stratospheric Change (NDSC) has provided systematic lidar measurements of ozone and temperature at several places around the world that are well adapted for satellite validations. Regular exercises have been organised to ensure the data quality at each individual site. These exercises can be separated into three categories: large scale intercomparisons using multiple instruments, including a mobile lidar; using satellite observations as a geographic transfer standards to compare measurements at different sites; and comparative investigations of the analysis software. NDSC is a research network, so each system has its own history, design, and analysis, and has participated differently in validation campaigns. There are still some technological differences that may explain different accuracies. However, the comparison campaigns performed over the last decade have always proved to be very helpful in improving the measurements. To date, more efforts have been devoted to characterising ozone measurements than to temperature observations. The synthesis of the published works shows that the network can potentially be considered as homogeneous within +/-2% between 20-35 km for ozone and +/-1 K between 35-60 km for temperature. Outside this altitude range, larger biases are reported and more efforts are required. In the lower stratosphere, Raman channels seem to improve comparisons but such capabilities were not systematically compared. At the top of the profiles, more investigations on analysis methodologies are still probably needed. SAGE II and GOMOS appear to be excellent tools for future ozone lidar validations but need to be better coordinated and take more advantage of assimilation tools. Also, temperature validations face major difficulties caused by atmospheric tides and therefore require intercomparisons with the mobile systems, at all sites.     

Outlier identification and visualization for Pb concentrations in urban soils and its implications for identification of potential contaminated land

Outliers in urban soil geochemical databases may imply potential contaminated land. Different methodologies which can be easily implemented for the identification of global and spatial outliers were applied for Pb concentrations in urban soils of Galway City in Ireland. Due to its strongly skewed probability feature, a Box–Cox transformation was performed prior to further analyses. The graphic methods of histogram and box-and-whisker plot were effective in identification of global outliers at the original scale of the dataset. Spatial outliers could be identified by a local indicator of spatial association of local Moran's I, cross-validation of kriging, and a geographically weighted regression. The spatial locations of outliers were visualised using a geographical information system. Different methods showed generally consistent results, but differences existed. It is suggested that outliers identified by statistical methods should be confirmed and justified using scientific knowledge before they are properly dealt with.     

The European whitefish, Coregonus lavaretus (L.), under conditions of technogenic pollution in the Kostomuksha tailing pond

The population structure and biological parameters of the European whitefish, Coregonus lavaretus (L.), have been analyzed in a technogenically polluted water body. The biochemical state of the whitefish and the fauna and morphology of helminths parasitizing them have been assessed. It is shown that the species composition of the fish, plankton, benthos, and parasite faunas of this water body are depleted and the morphological parameters of common fish parasites are altered. It is noted that, in addition to adaptive rearrangements in biochemical metabolism, the whitefish from the transformed water body are characterized by a reduction in the level of protein synthesis in muscles and the rate of aerobic energy metabolism in the liver and muscles.     

环境管理、规划管理与项目管理

文章从深入分析环境管理的内涵出发，进而提出树立项目管理意识，强化项目管理的概念，说明项目管理在环境管理中的地位和作用，从这个意义上讨论环境管理与项目管理的关系，简述环境保护项目管理的主要环节，达到提高环境管理效能的途径的目的。     

Supported Pd/Sn bimetallic nanoparticles for reductive dechlorination of aqueous trichloroethylene

A Pd/Sn bimetallic nanoparticles resin (nano-Pd/Sn/resin) was successfully synthesized for reductive transformation of aqueous trichloroethylene (TCE). The physicochemical properties of the prepared resin were characterized using scanning electron microscopy, energy dispersive X-ray spectroscopy, N(2) isothermal sorption at and X-ray photospectroscopy. The surface-area-normalized rate constants (k(SA)) of Sn particles in the nanoscale range (50-100 nm) were 4.5 times larger than the k(SA) for powdered Sn (0.04 mm). After depositing 1 wt% Pd onto nano-Sn surface, k(SA) was further enhanced by about a factor of 2. Groundwater constituents such as sulfide nitrate and dissolved oxygen had significant negative effects on the rate of TCE degradation by the nano-Pd/Sn/resin. A wet-chemical method regeneration method was observed to effectively restore the reactivity of the poisoned nano-Pd/Sn/resin after dipping in sulfide solution for 2d. In all cases, less than 0.5% of the degraded TCE appeared as chlorinated byproducts including the three dichloroethene isomers. The nano-Pd/Sn/resin technique performs well in transforming TCE into nontoxic hydrocarbons, as compared with other published methods.     

汉江上游郧县曲远河河口段全新世古洪水水文状态研究

对汉江上游河谷郧县曲远河河口剖面进行了沉积学、粒度、磁化率和烧失量的研究。结果表明：夹在古土壤中的灰白色沉积层是典型的古洪水滞流沉积物，记录了一次特大洪水事件，用地层对比法和OSL方法确定其发生时间为4 950~5 450 a B.P.。用古洪水SWD尖灭点法确定古洪水行洪水位高程为169 m，采用比降法恢复其洪峰流量为60 577 m3/s。根据2011年汉江上游洪水洪痕，用相同的方法对洪峰流量进行了反演，误差为-411％，说明用比降法恢复的古洪水洪峰流量是可靠的     

Effective removal of coordinated copper from wastewater using a new dithiocarbamate-type supramolecular heavy metal precipitant

A new dithiocarbamate-type heavy metal precipitant, sodium 1,3,5-hexahydrotriazinedithiocarbamate (HTDC), was prepared and used to remove coordinated copper from wastewater. In the reported dithiocarbamate-type precipitants, HTDC possesses the highest percentage of the effective functional groups. It could effectively precipitate copper to less than 0.5 mg l⁻¹ from both synthetic and actual industrial wastewater containing CuEDTA in the range of pH 3–9. UV–vis spectral investigation and elemental analysis suggested that the precipitate was a kind of coordination supramolecular compound, [Cu₃(HTDC)₂]_n. The toxicity characteristic leaching procedure (TCLP) and semi-dynamic leaching test (SDLT) indicated that the supramolecular precipitate was non-hazardous and stable in weak acid and alkaline conditions. Tests of an anion exchange resin D231 provided a clue to simultaneously remove excess HTDC and residual CuEDTA in practical process of wastewater treatment.     

冶炼烟气中砷的监测方法改进

金属冶炼烟气中的砷大都以颗粒物的形式存在,对环境造成污染.2010年,国家颁布了《铜、镍、钴工业污染物排放标准》( GB 25467-2010),对于废气中砷的监测,该标准中规定使用《空气和废气砷的测定 二乙基二硫代氨基甲酸银分光光度法(暂行)》( HJ 540-2009).然而该方法中对于烟气中砷的监测方法存在一定问题,高氯酸在高温消解过程中易爆炸,比较危险,另外采用在锥形瓶内加热至产生白烟的排酸方式不能有效地排净硝酸,会导致反应无法进行.为此,就该方法中有组织排放废气中砷的前处理部分提出了改进意见.     

Distribution of radionuclides among the main components of Lake Chervyanoe in the Eastern Ural Radioactive Trace

Radioecological conditions have been estimated in Lake Chervyanoe located on the central axis of the Eastern Ural Radioactive Trace (EURT) about 100–110 km northeast of the Mayak Production Association. Data on the ⁹⁰Sr and ¹³⁷Cs contents in the main components of the lake, the distribution of these radionuclides over the profile of bottom sediments, and their amounts in the lake are presented. The experimental data have been used to construct mathematical models for estimating changes in the radionuclide concentrations and amounts in the water and bottom sediments of the lake over a long period after the nuclear accident, as well as the tritium content of the lake water in different periods of time.