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101.
Polyaniline (PANI) nanofibers were electrochemically synthesized on gold electrode using ethanol as soft template by the cyclic voltammetry technique. The PANI nanofibers were characterized by Fourier transform infrared spectroscopy, UV-visible spectroscopy, and scanning electron microscopy. Linear sweep voltammetry was used to investigate electrocatalytic activity of the PANI nanofibers modified electrode toward the reduction of nitrate ions. Results showed that the electroreduction process strongly depends on the applied potential. At the potential value of about -0.8 V vs Ag/AgCl, the electroreduction of nitrate anions to nitrite anions was identified as the rate-determining step of the electroreduction process. In the potential range of -0.8 to -1.0 V, reduction of nitrite to hydroxylamine occurs, followed by the reduction to ammonia. At potentials more negative than -1.0 V, nitrite is directly reduced to ammonia. This study demonstrates the effectiveness of PANI nanofibers modified electrode in the electroreduction of nitrate ions compared to traditional reduction methods. 相似文献
102.
Siddiq Akbar Fariha Hasan Akhtar Nadhman Samiullah Khan Aamer Ali Shah 《Journal of Polymers and the Environment》2013,21(4):1109-1116
A poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) degrading bacterial strain designated as AF-111 was isolated from sewage sludge sample. The bacterium was identified by 16S rRNA gene sequencing. The results revealed that strain AF-111 showed 99 % similarity with Streptomyces althioticus strain NRRL B-3981 and designated as Streptomyces sp. strain AF-111. An extracellular PHBV depolymerase enzyme was produced under optimized conditions and purified through ammonium sulphate fractionation and column chromatography. The enzyme was purified to homogeneity, indicated by sodium dodecyl sulfate–polyacrylamide gel electrophoresis and molecular weight was found to be approximately 51 kDa. Effect of temperature, pH, metal ions and inhibitors on the PHBV depolymerase activity was determined. The enzyme was stable at wide range of temperature (35–55 °C) and pH (6–8). PHBV depolymerase was stable in the presence of different metal ions except iron and zinc which had inhibitory effect on depolymerase activity. Both ethylenediamine teteracetic acid and phenylmethyl sulphonyl fluoride strongly inhibited enzyme activity which indicates that this enzyme belongs to the serine hydrolase family like other polyhydroxyalkanoate depolymerases. The results show that a depolymerase from strain AF-111 can effectively degrade PHBV, therefore, it can be applied in the process of biochemical monomer recycling. 相似文献
103.
Nevzat Damla Ugur Cevik Ali Ihsan Kobya Berna Ataksor Umit Isık 《Environmental monitoring and assessment》2010,160(1-4):401-412
The province of Batman, located in southern Anatolia, has a population of approximately 500,000. To our knowledge, there exists no information regarding the environmental radioactivity in this province. Therefore, gamma activity measurements in soil, building materials and water samples and an indoor radon survey have been carried out in the Batman province. The mean activity concentrations of the natural radionuclides (226Ra, 232Th and 40K) and a fission product (137Cs) were 35 ± 8, 25 ± 10, 274 ± 167 and 12 ± 7 Bq kg???1, respectively, in the soil samples. The concentrations of 226Ra, 232Th and 40K in the selected building materials ranged from 18 to 48 Bq kg???1, 8 to 49 Bq kg???1 and 68 to 477 Bq kg???1, respectively. All the calculated radium equivalent (Raeq) activity values of the building material samples are lower than the limit of 370 Bq kg???1, equivalent to a γ-dose of 1.5 mSv year???1. The activity concentrations of 226Ra, 232Th and 40K in tap waters collected from the study area were determined with mean specific activity concentrations of 42 ± 15, 35 ± 9 and 524 ± 190 mBq L???1, respectively. Indoor radon measurements were made at 95 dwellings in Batman using a CR-39 detector. The radon concentration levels were found to vary from 23 to 145 Bq m???3. The arithmetic mean of the measured radon concentration levels was found to be 84 Bq m???3 with a standard deviation value of 23 Bq m???3. The measurement results obtained in this study did not significantly differ from those taken in other parts of the country. The data generated in this study can be used to determine whether the Batman province is in a normal or high background radiation area and provides a valuable database for future estimations of the impact of radioactive pollution. 相似文献
104.
Ali Naderi Beni Michael Kühn Robert Meyer Christoph Clauser 《Environmental Modeling and Assessment》2012,17(4):337-351
We study opportunities for CO2 sequestration in geological formations of the state North Rhine Westphalia in Germany. Simulations are performed for evaluating a potential site within the Bunter sandstone formation near the town of Minden in a depth?of around 3,000 m using the numerical simulator TOUGHREACT. Our focus is on three CO2 storage mechanisms: (1) hydrodynamic trapping, (2) dissolution trapping, and (3) mineral trapping. The results show that due to buoyancy the injected CO2 phase initially migrates towards the top of the reservoir and is hydrodynamically trapped beneath the confining layer of the cap rock. Then, the CO2 spreads laterally and dissolves partially in the formation water. The dissolution of CO2 results in an increase of the density of the brine causing a downward migration until it settles after 10,000 years at the bottom of the reservoir. The simulations indicate that after 10,000 years, 15% (17 Mt) from a total of 114 Mt injected CO2 are trapped hydrodynamically, 20% (23 Mt) are trapped by dissolution, and 65% (74 Mt) are fixed in newly formed carbonates such as dawsonite, ankerite, and siderite. Within our study pressure increases near the injection well by a factor of 1.1 which is lower than the upper limit usually accepted in gas storage operations. The mineral reactions cause a net decrease of porosity and in turn a decrease of permeability down to 9% of the initial value in parts of the reservoir. 相似文献
105.
Monavari SM Omrani GA Karbassi A Raof FF 《Environmental monitoring and assessment》2012,184(4):1841-1846
Environment problems associated with the generation of waste are part of societal changes where households play an important
role. These societal changes influence the size, structure and characteristic of given households. For the effective planning
of solid-waste handling infrastructure, it is essential to know the quantity of waste generation and its composition. This
paper presents the findings of a study carried out in an urban municipal area in Iran to determine the household solid-waste
generation rate and waste composition based on field surveys and to determine the related socioeconomic parameters. The dependent
variables were waste generation and composition, and independent variables were family size, family employment, age, number
of room and education. Over 400 sample households were selected for the study using a stratified random sampling methodology
and from five different socioeconomic groups. Waste collected from all groups of households were segregated and weighted.
Waste generation rate was 5.4 kg/household/day. Household solid waste comprised of ten categories of wastes and with the largest
component (76.9%). The generation and composition of household solid waste were correlated with family size, education level
and households income. This paper adequately suggests new insights concerning the role of socioeconomic parameters in affecting
the generation of household waste. 相似文献
106.
Tabrez Alam Khan Saif Ali Chaudhry Imran Ali 《Environmental science and pollution research international》2013,20(8):5425-5440
Arsenic contamination of groundwater is a major threat to human beings globally. Among various methods available for arsenic removal, adsorption is fast, inexpensive, selective, accurate, reproducible and eco-friendly in nature. The present paper describes removal of arsenate from water on zirconium oxide-coated sand (novel adsorbent). In the present work, zirconium oxide-coated sand was prepared and characterised by infrared and X-ray diffraction techniques. Batch experiments were performed to optimise different adsorption parameters such as initial arsenate concentration (100–1,000 μg/L), dose (1–8 g/L), pH of the solution (2–14), contact time (15–150 min.), and temperature (20, 30, 35 and 40 °C). The experimental data were analysed by Langmuir, Freundlich, Temkin and Dubinin–Radushkevich isotherm models. Furthermore, thermodynamic and kinetic parameters were evaluated to know the mode of adsorption between ZrOCMS and As(V). The maximum removal of arsenic, 97 %, was achieved at initial arsenic concentration of 200 μg/L, after 75 min at dosage of 5.0 g/L, pH?7.0 and 27?±?2 °C. For 600 μg/L concentration, the maximum Langmuir monolayer adsorption capacity was found to be 270 μg/g at 35 °C. Kinetic modelling data indicated that adsorption process followed pseudo-second-order kinetics. The mechanism is controlled by liquid film diffusion model. Thermodynamic parameter, ΔH°, was ?57.782, while the values of ΔG° were ?9.460, ?12.183, ?13.343 and ?13.905 kJ/mol at 20, 30, 35 and 40 °C, respectively, suggesting exothermic and spontaneous nature of the process. The change in entropy, ΔS°?=??0.23 kJ/mol indicated that the entropy decreased due to adsorption of arsenate ion onto the solid adsorbent. The results indicated that the reported zirconium oxide-coated marine sand (ZrOCMS) was good adsorbent with 97 % removal capacity at 200 μg/L concentration. It is interesting to note that the permissible limit of arsenic as per World Health Organization is 10 μg/L, and in real situation, this low concentration can be achieved through this adsorbent. Besides, the adsorption capacity showed that this adsorbent may be used for the removal of arsenic from any natural water resource. 相似文献
107.
Bari ME Zietsman J Quadrifoglio L Farzaneh M 《Journal of the Air & Waste Management Association (1995)》2011,61(6):611-630
The objective of this research was to develop a multiobjective optimization model to deploy emissions reduction technologies for nonroad construction equipment to reduce emissions in a cost-effective and optimal manner. Given a fleet of construction equipment emitting different pollutants in the nonattainment (NA) and near -nonattainment (NNA) counties of a state and a set of emissions reduction technologies available for installation on equipment to control pollution/emissions, the model assists in determining the mix of technologies to be deployed so that maximum emissions reduction and fuel savings are achieved within a given budget. Three technologies considered for emissions reduction were designated as X, Y, and Z to keep the model formulation general so that it can be applied for any other set of technologies. Two alternative methods of deploying these technologies on a fleet of equipment were investigated with the methods differing in the technology deployment preference in the NA and NNA counties. The model having a weighted objective function containing emissions reduction benefits and fuel-saving benefits was programmed with C++ and ILOG-CPLEX. For demonstration purposes, the model was applied for a selected construction equipment fleet owned by the Texas Department of Transportation, located in NA and NNA counties of Texas, assuming the three emissions reduction technologies X, Y, and Z to represent, respectively, hydrogen enrichment, selective catalytic reduction, and fuel additive technologies. Model solutions were obtained for varying budget amounts to test the sensitivity of emissions reductions and fuel-savings benefits with increasing the budget. Different mixes of technologies producing maximum oxides of nitrogen (NO(x)) reductions and total combined benefits (emissions reductions plus fuel savings) were indicated at different budget ranges. The initial steep portion of the plots for NO(x) reductions and total combined benefits against budgets for different combinations of emissions reduction technologies indicated a high benefit-cost ratio at lower budget amounts. The rate of NO(x) reductions and the increase of combined benefits decreased with increasing the budget, and with the budget exceeding certain limits neither further NO(x) reductions nor increased combined benefits were observed. Finally, the Pareto front obtained would enable the decision-maker to achieve a noninferior optimal combination of total NO(x) reductions and fuel-savings benefits for a given budget. 相似文献
108.
Kaleem Muhammad Mumtaz Abdul Samad Hashmi Muhammad Zaffar Saeed Aamer Inam Farooq Waqar Rooma Jabeen Amber 《Environmental science and pollution research international》2023,30(6):13994-14007
Environmental Science and Pollution Research - Polychlorinated biphenyls (PCBs) are toxic organic compounds and pose serious threats to environment and public health. PCBs still exist in different... 相似文献
109.
Nevzat Damla Uğur Cevik Ali Ihsan Kobya Ahmet Celik Necati Celik 《Environmental monitoring and assessment》2010,170(1-4):457-466
The activity concentrations of 226Ra, 232Th, and 40K in lime and gypsum samples used as building materials in Turkey were measured using gamma spectrometry. The mean activity concentrations of 226Ra, 232Th, and 40K were found to be 38 ± 16, 20 ± 9, and 156 ± 54 Bq kg???1 for lime and found to be 17 ± 6, 13 ± 5, and 429 ± 24 Bq kg???1 for gypsum, respectively. The radiological hazards due to the natural radioactivity in the samples were inferred from calculations of radium equivalent activities (Raeq), indoor absorbed dose rate in the air, the annual effective dose, and gamma and alpha indices. These radiological parameters were evaluated and compared with the internationally recommended limits. The experimental mass attenuation coefficients (μ/ρ) of the samples were determined in the energy range 81–1,332 keV. The experimental mass attenuation coefficients were compared with theoretical values obtained using XCOM. It is found that the calculated values and the experimental results are in good agreement. 相似文献
110.
Shadi Dayyani Chandra A. Madramootoo Peter Enright Guillaume Simard Apurva Gullamudi Shiv O. Prasher Ali Madani 《Journal of the American Water Resources Association》2009,45(3):779-792
Abstract: The hydrologic performance of DRAINMOD 5.1 was assessed for the southern Quebec region considering freezing/thawing conditions. A tile drained agricultural field in the Pike River watershed was instrumented to measure tile drainage volumes. The model was calibrated using water table depth and subsurface flow data over a two‐year period, while another two‐year dataset served to validate the model. DRAINMOD 5.1 accurately simulated the timing and magnitude of subsurface drainage events. The model also simulated the pattern of water table fluctuations with a good degree of accuracy. The R2 between the observed and simulated daily WTD for calibration was >0.78, and that for validation was 0.93. The corresponding coefficients of efficiency (E) were >0.74 and 0.31. The R2 and E values for calibration/validation of subsurface flow were 0.73/0.48 and 0.72/0.40, respectively. DRAINMOD simulated monthly subsurface flow quite accurately (E > 0.82 and R2 > 0.84). The model precisely simulated daily/monthly drain flow over the entire year, including the winter months. Thus DRAINMOD 5.1 performed well in simulating the hydrology of a cold region. 相似文献