Effects of flooding and drought on water quality in Gulf Coastal Plain streams in Georgia

Since 1994, water-quality constituents have been measured monthly in three adjacent Coastal Plain watersheds in southwestern Georgia. During 1994, rainfall was 650 mm above annual average and the highest flows on record were observed. From November 1998 through November 2000, 19 months had below average rainfall. Lowest flows on record were observed during the summer of 2000. The watersheds are human-dominated with row-crop agriculture and managed forestlands being the major land uses. However, one watershed (Chickasawhatchee Creek) had 10 to 13% less agriculture and greater wetland area, especially along the stream. Suspended particles, dissolved organic carbon, NH4-N, and soluble reactive phosphorus concentrations were greater during wet and flood periods compared with dry and drought periods for each stream. Regional hydrologic conditions had little effect on NO3-N or dissolved inorganic carbon. Chickasawhatchee Creek had significantly lower suspended sediment and NO3-N concentrations and greater organic and inorganic carbon concentrations, reflecting greater wetland area and stronger connection to a regional aquifer system. Even though substantial human land use occurred within all watersheds, water quality was generally good and can be attributed to low stream drainage density and relatively intact floodplain forests. Low drainage density minimizes surface run-off into streams. Floodplain forests reduce nonpoint-source pollutants through biological and physical absorption. In addition to preserving water quality, floodplain forests provide important ecological functions through the export of nutrients and organic carbon to streams. Extreme low flows may be disruptive to aquatic life due to both the lack of water and to the scarcity of biologically important materials originating from floodplain forests.     

Synthesis of polychlorinated biphenyls (PCBs) using the Suzuki-coupling

An improved synthesis of polychlorinated biphenyls (PCBs) utilizing a palladium-catalyzed cross-coupling reaction (Suzuki-coupling) is described. The coupling of (chlorinated) aryl boronic acids 1-3 with bromochlorobenzenes 4 using the standard conditions of the Suzuki-coupling gave the desired PCB congeners 5-7 in good to excellent yields. The self-coupling product of the aryl boronic acids is the major impurity of this reaction. 3,4,5-trichlorophenyl derivatives such as 10 can be synthesized by coupling of an aryl boronic acid with the corresponding bromochloroaniline 8. The approach offers the advantage of high selectivity and good yields compared to conventional methods such as the Cadogan reaction and allows the use of less toxic starting materials.     

Seasonal aerosol sulfate trends for selected regions of the United States

Site and regional trends in seasonally averaged particle SO4(2-) concentrations were examined for a large portion of the United States using data collected by the CASTNet air monitoring network. Trends were analyzed for overlapping periods of 1988-1999 and 1992-1999. The largest absolute SO4(2-) decreases--approximately -0.4 microg/m3/yr--between 1988 and 1999 occurred in summer for sites in the Ohio River Valley and areas to the east. Generally, the largest SO4(2-) reductions were found for summer, but larger relative reductions often occurred for spring and autumn. Sulfate changes during 1992-1999 were quite different from those found for 1988-1999 and were not entirely consistent with changes in SO2 emissions. In some locations, the 1992-1999 period saw smaller declines in SO4(2-), while in other places seasonal SO4(2-) actually increased. Increases were mostly confined to summer and autumn across the southern and southwestern states. Multivariate analysis of ambient sulfur levels, by region, versus SO2 emissions reveals that annual emissions are associated with more than 80% of the variance in seasonal sulfur (SO2 and SO4(2-)) in more than three-quarters of the cases examined. The weakest associations were found for the southeastern United States.     

Principles and issues in radiological ecological risk assessment

This paper provides a bridge between the fields of ecological risk assessment (ERA) and radioecology by presenting key biota dose assessment issues identified in the US Department of Energy's Graded Approach for Evaluating Radiation Doses to Aquatic and Terrestrial Biota in a manner consistent with the US Environmental Protection Agency's framework for ERA. Current radiological ERA methods and data are intended for use in protecting natural populations of biota, rather than individual members of a population. Potentially susceptible receptors include vertebrates and terrestrial plants. One must ensure that all media, radionuclides (including short-lived radioactive decay products), types of radiations (i.e., alpha particles, electrons, and photons), and pathways (i.e., internal and external contamination) are combined in each exposure scenario. The relative biological effectiveness of alpha particles with respect to deterministic effects must also be considered. Expected safe levels of exposure are available for the protection of natural populations of aquatic biota (10 mGy d(-1)) and terrestrial plants (10 mGy d(-1)) and animals (1 mGy d(-1)) and are appropriate for use in all radiological ERA tiers, provided that appropriate exposure assumptions are used. Caution must be exercised (and a thorough justification provided) if more restrictive limits are selected, to ensure that the supporting data are of high quality, reproducible, and clearly relevant to the protection of natural populations.     

A quantitative succession model for nine montana forest communities

A quantitative succession model was developed both to meet resource management needs in Montana's Lewis and Clark National Forest and to develop a modeling methodology. It builds upon previous concepts and incudes three new features: quantitative prediction of all tree species and seedlings; quantitative predictions of important understory species; and successional pathways determined by fire intensity and scorch height. The method is described and demonstrated for selected Montana habitat (community) types. It is also available in managerial guidelines and has been programmed as a new module in theforplan simulator. Weaknesses of this and other models are discussed. Conclusions relate succession modeling to resource management needs.     

FEASIBILITY OF INTERBASIN WATER TRANSFER1

ABSTRACT: Interbasin water transfer is one of the most controversial water-resources-planning topics. Local communities, particularly those from which the water is to be taken (donor regions), generate enough opposition to doom many projects to failure. The opposition often arises because planners have traditionally considered excess water a free commodity rather than a marketable resource. To make transfer schemes mutually acceptable to donor and recipient regions, visible benefits must be offered. Agreement must be made on an acceptable purchase price and/or on other benefits such as a substantial amount of low flow augmentation or possibly some degree of flood control on the donor source stream. The hydrologic and economic feasibility of water transfer from the East Susquehanna River basin to the Delaware Reservoir System for supplemental supply to the New York City area was investigated. Nine alternative schemes for diversions up to 400 cfs and compensations in the form of low flow augmentation and/or flood control were considered resulting in unit costs to the recipient region between $90 and $380/mg. If only the minimum state-mandated flow is released to the Susquehanna River, the savings to the water recipients would be sufficient to pay a purchase price of about $21/mg, which would be equivalent to a total amount of $420,000/year for an average export of 100 cfs.     

FARMERS’ATTITUDES TOWARD GOVERNMENT INVOLVEMENT IN PREVENTING AGRICULTURAL NONPOINT SOURCE WATER POLLUTION1

ABSTRACT: Concern over the pollution of our lakes and streams has become a major issue in the United States. Sedimentation from sigricultural lands has been identified as a significant factor in water pollution. Some citizens suggest that government should force compliance with soil loss standards, while others suggest that we ask farmers to voluntarily comply. Related questions are “DO farmers think government should be involved in controlling erosion and protecting water quality?”“To what extent should government be involved?” What level of government should be involved? Federal? State? Local?“Why should pay for water quality projects?” Farmers from a small watershed in northeastern Indiana were interviewed before and after a major demonstration project. Their responses suggest that farmers feel that individual landowners should be responsible for controlling erosion and agricultural nonpoint source water pollution. However, over 60 percent of the study fanners indicated that the federal government should play an important role, in terms of both technical and financial assistance.