Extraction,chemical compositions,and cytotoxic activities of essential oils of Thevetia peruviana

Abstract

In this study, The essential oil of flowers, fruits, and leaves of Thevetia peruviana, which were collected in Vietnam, were being reported for the first time. The essential oil of flowers was extracted by different methods: n-hexane extraction, distillation water, and supercritical CO₂ extraction. The compositions of essential oil of different parts of Thevetia peruviana were analyzed by GC-FID and GC/MS systems. Major chemical compositions of essential oil were identified as monoterpenes, sesquiterpenes, terpenoids, and sterol. The activities of total essential oil extracts of the Thevetia peruviana exhibit inhibitory activities against five cancer cell lines.     

An intergrated waste survey and environmental effects of COGIDO, a bleached pulp and paper mill in Vietnam, on the receiving waterbody

An integrated investigation on wastewater characterization and the environmental effects from the COGIDO pulp and paper mill in Bien Hoa Industrial Estate, Vietnam, a chlorine bleached soda integrated pulp and paper mill operating without a chemical recovery system, on the receiving water body was conducted during the rainy and dry seasons in 1993 and 1995. The pollution load from the mill was very high in terms of BOD, COD and SS (COD_m: 58.7 t/d; BOD: 33.3 t/d and SS: 25.1 t/d). The effluent toxicity was determined using four toxicity tests: the green micro-alga, Selenastrum capricornutum, Microtox (marine bacteria: Photobacterium phosphoreum), the duckweed, Lemna aequinoctialis, and fish (silver barb: Puntius gonionotus, and Tilapia: Tilapia nilotica). Selenastrum capricornutum was the most sensitive among the tested organisms. The mill toxicity emission rate (TER) was as high as 338 610 (Selenastrum test). The bleaching-pulp and semi-chemical pulp plants which contributed the largest pollution load to the total COGIDO effluent, therefore, were targeted for abatement measures. Physico-chemical parameters as well as qualitative and quantitative aquatic organism composition for the river water were established. The BOD₅ and COD values exceeded the potable surface water standard by a factor of 2 to 4. The species diversity and abundance of the phytoplankton, zooplankton and zoobenthos were found to be lower (20–40%) than that of unpolluted rivers in Vietnam, whereas pollution-indicator species increased up to four times during the dry season 1995.     

Influencing factors on sustainable development: a case study in Quang Tri province,Vietnam

Background Sustainable development (SD) is a common concept. Knowledge and attitudes are essential in the SD process. This study assesses the knowledge, attitudes, and practices (KAP) of local people about SD. Aim To study the factors that influence the understanding of the concept, contents, and indicators of different aspects affecting the health and environmental issues. Methods A cross-sectional study was carried out from June to July 2007 among 546 households in the Quang Tri province. Data were gathered on basis of socio-demographic variables, namely age, gender, education, occupation, income, and region. Chi square tests and multivariate analysis were performed on the obtained data. The data were cleaned and analysed using SPSS 15.0 for windows. Results Occupation is related to knowledge, attitude, or practice. Income is related to knowledge or practice. Gender related to only attitude. Lastly, region is related to attitude or practice. The proportion of wrong understanding about SD is 2.0 times (95% CI: 1.3; 3.1, p < 0.001) higher than that of the people who have good understanding about it. The rate of willingness to do any related SD programmes of the people who understanding is 2.1 times (95% CI: 1.4; 3.2, p < 0.001) higher than that of the people who have bad one. Conclusions This study shows that knowledge on sustainability of the local communities is low. Occupation and income influence understanding of SD more than region, age, gender, and education. Most of the local people who do not understand SD in general, do not want to participate or act in SD programmes.     

Integrating data-driven ecological models in an expert-based decision support system for water management in the Du river basin (Vietnam)

In this study, classification trees were combined with the Water Framework Directive (WFD)-Explorer, a modular toolbox that supports integrated water management in a river basin to evaluate the impact of different restoration measures on river ecology. First, the WFD-Explorer toolbox analysed the effect of different restoration options on the abiotic river characteristics based on the water and substance balance embedded in the simulation environment. Based on these abiotic characteristics, the biological index Biological Monitoring Working Party for Vietnam was then predicted by classification trees that were trained on biological and abiotic data collected in the Du river basin in northern Vietnam. The ecological status of streams in the basin ranged from nearly pristine headwaters to severely impacted river stretches. Elimination of point sources from ore extraction and decentralised domestic wastewater treatment proved to be the most effective measures to improve the ecological condition of the Du river basin. The combination of the WFD-Explorer results with data-driven models enabled model application in a situation where expert knowledge was lacking. Consequently, this approach appeared promising for decision support in the context of river restoration and conservation management.     

Arsenic and other trace elements contamination in groundwater and a risk assessment study for the residents in the Kandal Province of Cambodia

Concentrations of arsenic and other trace elements in groundwater were examined at three villages (PT, POT and CHL) in the Kandal Province of Cambodia. Concentrations of arsenic in the groundwater ranged from 6.64 (in POT village) to 1543 microg/L (in PT village), with average and median concentrations of 552 and 353 microg/L, respectively. About 86% out of fifteen samples contained arsenic concentrations exceeding the WHO drinking water guidelines of 10 microg/L. Concentrations of arsenic (III) varied from 4 (in POT village) to 1334 microg/L (in PT village), with an average concentration of 470 microg/L. In addition, about 67%, 80% and 86% of the groundwater samples had higher concentrations for, respectively, barium, manganese and lead than the WHO drinking water guidelines. These results reveal that groundwater in Kandal Province is not only considerably contaminated with arsenic but also with barium, manganese and lead. A risk assessment study found that one sample (PT25) had a cumulative arsenic concentration (6758 mg) slightly higher than the threshold level (6750 mg) that could cause internal cancer in smelter workers with chronic exposure to arsenic from groundwater. High cumulative arsenic ingestion poses a health threat to the residents of Kandal Province.     

Complex hydrochemical characteristics of the Middle–Upper Pleistocene aquifer in Soc Trang Province,Southern Vietnam

Environmental Geochemistry and Health - Environmental isotope techniques were applied to study the hydrochemical characteristics of groundwater in Soc Trang Province, Southern Vietnam, in frame of...     

Iron-doped copper 1,4-benzenedicarboxylate as photo-Fenton catalyst for degradation of methylene blue

Abstract

A metal-organic framework of iron-doped copper 1,4-benzenedicarboxylate was synthesized and, for the first time, utilized as a heterogeneous photo-Fenton catalyst for degradation of methylene blue dye in aqueous solution under visible light irradiation. The synthesized materials were characterized by scanning electron microscopy, Fourier-transform infrared spectroscopy, X-ray diffraction and energy-dispersive X-ray spectroscopy. The influence factors, kinetics, and stability of the synthesized catalysts were investigated in detail. Iron-doped copper 1,4-benzenedicarboxylate showed higher degradation efficiency than pure copper 1,4-benzenedicarboxylate. An almost complete degradation was achieved within 70?min under visible light irradiation at a solution pH of 6, a catalyst loading of 1?g?L^?1, a H₂O₂ dosage of 0.05?mol L^?1 and methylene blue concentration of 50?mg?L^?1. Recycling studies demonstrated that the iron-doped copper 1,4-benzenedicarboxylate is a promising heterogeneous photo-Fenton catalyst for long-term removal of methylene blue dye from industrial wastewater.     

Modeling of partial nitrification and denitrification in an SBR for leachate treatment without carbon addition

A process of partial nitrification and denitrification in a sequencing batch reactor (SBR) treating leachate was simulated by applying a modified version of activated sludge model no. 3 (ASM3), named ASM3_2step. This model modifies the ASM3 model by separating nitrification and denitrification into two steps with nitrite as an intermediate substrate. Three periods, including long term period, steady state and cycle evolution, were used for calibration. Three main processes were observed, including biomass production, nitrification (focusing on nitrite accumulation) and denitrification. The kinetic and stoichiometric parameters ( m_{\textA_NH} \mu_{{{\text{A\_NH}}}} , Y_{\textA_NH} Y_{{{\text{A\_NH}}}} , Y_{\textA_\textNO2} Y_{{{\text{A}}\_{\text{NO}}_{2} }} , Y_{\textH_\textO2} Y_{{{\text{H}}\_{\text{O}}_{2} }} , b _A, K_{\textA_NH} K_{{{\text{A\_NH}}}} ), were determined from biokinetic and respirometry tests. Some of the default values of kinetic and stoichiometric parameters available in the ASM3 model and in the literature were kept constant, while some others were adjusted step by step until observed state variables fit with experimental data. The maximum specific growth rate of nitrite oxidizing bacteria (0.108 day⁻¹) (simulated by the model) and that of ammonium oxidizing bacteria (0.61 day⁻¹) (from biokinetic tests) are the parameters which have the highest influence on the nitrite accumulation, even more than oxygen supply intensity or Kla value. Other important parameters were K_{\textAO_NH} K_{{{\text{AO\_NH}}}} and K_{\textAO_\textNO2} K_{{{\text{AO}}\_{\text{NO}}_{2} }} , calibrated at the values of 1.37 and 1.59 mg O₂/L, respectively. The modified model and values of the kinetic and stoichiometric parameters obtained from the modeling process will be used for optimization of the partial nitrification in the next study.     

Industrial transformation and shrimp aquaculture in Thailand and Vietnam: pathways to ecological,social, and economic sustainability?

Shrimp aquaculture in Vietnam is in the process of being transformed into a major industry around the intensification of the production system. The experiences of other countries in the region, especially in Thailand where high input production systems dominate, suggests that now is a critical time for intervention to redirect industry into pathways that are more sustainable ecologically, socially, and economically. In Thailand, years of experience with intensified systems and a complex industrial organization has not led to sustainable solutions. The challenge here is for society to regain control and then to redirect the transformation along more efficient and benign pathways. Our analyses suggest that current pathways in both countries are unlikely to lead to a sustainable industry. A complete transformation of the way shrimp are grown, fed, processed, distributed, and regulated is needed.