南京大气细粒子中重金属污染特征及来源解析

利用2011年1月、4月、7月和10月在南京市区和北郊采集的气溶胶样品,研究了南京大气细粒子中zn、Ph、Hg、As和cd5种重金属的污染水平,通过元素相关性分析和因子分析方法,对细粒子中这些重金属的污染来源进行了初步解析。结果表明,南京大气细粒子及其重金属污染严重,北郊普遍比市区严重;As严重超标,cd在南京北郊超标约5倍,zn在市区与北郊的质量浓度均高于其他重金属元素。每种重金属的浓度均随季节而变化。市区细粒子中,As和zn可能主要与燃煤、轮胎灰尘和建筑扬尘等有关,Pb、Hg和cd主要来自交通尘、城市垃圾焚烧等。北郊细粒子中,As、Hg和zn主要来源于燃煤、钢铁冶炼等工业,Pb和cd主要与农作物秸秆燃烧、汽车尾气、道路扬尘等影响有关。     

A multi-objective assessment of an air quality monitoring network using environmental,economic, and social indicators and GIS-based models

In the United States, air pollution is primarily measured by Air Quality Monitoring Networks (AQMN). These AQMNs have multiple objectives, including characterizing pollution patterns, protecting the public health, and determining compliance with air quality standards. In 2006, the U.S. Environmental Protection Agency issued a directive that air pollution agencies assess the performance of their AQMNs. Although various methods to design and assess AQMNs exist, here we demonstrate a geographic information system (GIS)-based approach that combines environmental, economic, and social indicators through the assessment of the ozone (O₃) and particulate matter (PM10) networks in Maricopa County, Arizona. The assessment was conducted in three phases: (1) to evaluate the performance of the existing networks, (2) to identify areas that would benefit from the addition of new monitoring stations, and (3) to recommend changes to the AQMN. A comprehensive set of indicators was created for evaluating differing aspects of the AQMNs’ objectives, and weights were applied to emphasize important indicators. Indicators were also classified according to their sustainable development goal. Our results showed that O₃ was well represented in the county with some redundancy in terms of the urban monitors. The addition of weights to the indicators only had a minimal effect on the results. For O₃, urban monitors had greater social scores, while rural monitors had greater environmental scores. The results did not suggest a need for adding more O₃ monitoring sites. For PM10, clustered urban monitors were redundant, and weights also had a minimal effect on the results. The clustered urban monitors had overall low scores; sites near point sources had high environmental scores. Several areas were identified as needing additional PM10 monitors. This study demonstrates the usefulness of a multi-indicator approach to assess AQMNs. Network managers and planners may use this method to assess the performance of air quality monitoring networks in urban regions.

Implications:The U.S. Environmental Protection Agency issued a directive in 2006 that air pollution agencies assess the performance of their AQMNs; as a result, we developed a GIS-based, multi-objective assessment approach that integrates environmental, economic, and social indicators, and demonstrates its use through assessing the O₃ and PM₁₀ monitoring networks in the Phoenix metropolitan area. We exhibit a method of assessing network performance and identifying areas that would benefit from new monitoring stations; also, we demonstrate the effect of adding weights to the indicators. Our study shows that using a multi-indicator approach gave detailed assessment results for the Phoenix AQMN.     

MCM-41介孔分子筛的合成及其对铜离子的吸附性能简

以微硅粉为硅源,CTAB和PEG-6000为模板剂,合成MCM-41介孔分子筛。采用XRD、N₂吸附-脱附曲线、FTIR以及TEM表征了其结构、比表面积、孔径分布及晶体形貌,并且以该样品为吸附剂,对含Cu²⁺的溶液进行了静态吸附实验。结果表明,以微硅粉为硅源成功合成了具有典型六方排列孔道结构的MCM-41,其比表面积为869.5 m²/g,孔容为0.97 cm³/g,平均孔径为3.3 nm;溶液pH为5~6时,MCM-41对Cu²⁺的去除效果最好;MCM-41对Cu²⁺的最大吸附吸附容量36.3 mg/g;MCM-41对Cu²⁺的吸附性能符合Langmuir吸附方程的特征。动力学研究表明,该过程符合准二级动力学模型。     

Toxicity of sediment cores from Yangtze River estuary to zebrafish (<Emphasis Type="Italic">Danio rerio</Emphasis>) embryos

Toxicity evaluation is an important segment in sediment quality monitoring in order to protect aquatic organisms and human health. The purpose of this study is to assess the toxicity of sediments from three sediment cores in Yangtze River Estuary, China, using the zebrafish (Danio rerio) embryo tests. Fertilized zebrafish eggs were exposed to both whole sediments and sediment organic extracts prepared from collected sediments, in order to provide a comprehensive and realistic insight into the bioavailable toxicity potential of the sediments. As end points, development parameters (mortality, hatching rate, and abnormality) in the developing embryos were recorded during the 96-h exposure. The results showed that some samples increased mortality, inhibited the hatching of embryos, and induced morphological abnormalities. The embryonic toxicities presented serrated changes and irregular distribution with depth, which may be related to hydrodynamic effect and unstable environmental input. However, lethal and sub-lethal effects were more significant at the sub-surface sediments (10～40 cm), which indicated that the pollution is more serious in recent decades.     

船舶柴油机选择性催化还原积碳臭氧直接氧化再生

为解决船舶柴油机SCR催化剂积碳再生问题,提出了臭氧直接氧化再生的方法。实验用玻璃纤维无胶滤筒采集PM,然后在管式炉中用臭氧氧化滤筒中的PM,研究了温度和臭氧浓度对PM氧化的影响。实验表明,臭氧的最佳氧化温度窗口为200~240℃,PM氧化速度随臭氧浓度提高明显加快,PM氧化率可以达到92%以上。根据实验结果,提出了船舶柴油机SCR积碳O3低温再生技术方案。     

Comparative quantification of oxygen release by wetland plants: electrode technique and oxygen consumption model

Understanding oxygen release by plants is important to the design of constructed wetlands for wastewater treatment. Lab-scale systems planted with Phragmites australis were studied to evaluate the amount of oxygen release by plants using electrode techniques and oxygen consumption model. Oxygen release rate (0.14 g O₂/m²/day) measured using electrode techniques was much lower than that (3.94–25.20 gO₂/m²/day) calculated using the oxygen consumption model. The results revealed that oxygen release by plants was significantly influenced by the oxygen demand for the degradation of pollutants, and the oxygen release rate increased with the rising of the concentration of degradable materials in the solution. The summary of the methods in qualifying oxygen release by wetland plants demonstrated that variations existed among different measuring methods and even in the same measuring approach. The results would be helpful for understanding the contribution of plants in constructed wetlands toward actual wastewater treatment.     

The influences of pH and ionic strength on the sorption of tylosin on goethite

As one of the widely used antibiotics in the world, the environmental risks of tylosin (TYL) received more and more attention. In order to assess its environmental fate and ecological effects accurately, it is necessary to understand the sorption properties of TYL on the soils/sediments. The sorption of TYL on goethite at different pH and ionic strength conditions were measured through a series of batch experiments and the sorption data of TYL were fitted by Freundlich and dual-mode sorption models. It was obvious that sorption was strongly dependent on pH and ionic strength. Sorption capacity of TYL increased as the pH increased and ionic strength decreased. The pH and ionic strength-dependent trends might be related with complexation between cationic/neutral TYL species and goethite. The sorption affinity of TYL on goethite decreased as ionic strength increased, which only occurred at higher TYL concentrations, suggested that inner complex might have dominated process at low concentrations and outer complex might occur at higher concentrations of TYL. Spectroscopic evidence indicated that tricarbonylamide and hydroxyl functional groups of TYL might be accounted for the sorption on mineral surfaces. The experimental data of TYL sorption could be fitted by surface complexation model (FITEQL), indicating that ≡FeOH with TYL interaction could be reasonably represented as a complex formation of a monoacid with discrete sites on goethite. The sorption mechanism of TYL might be related with surface complexation, electrostatic repulsion, and H-bounding on goethite. It should be noticed that the heterogeneous of sorption affinity of TYL on goethite at various environment to assess its environment risk.     

Positive matrix factorization as source apportionment of soil lead and cadmium around a battery plant (Changxing County,China)

Chemical compositions of soil samples are multivariate in nature and provide datasets suitable for the application of multivariate factor analytical techniques. One of the analytical techniques, the positive matrix factorization (PMF), uses a weighted least square by fitting the data matrix to determine the weights of the sources based on the error estimates of each data point. In this research, PMF was employed to apportion the sources of heavy metals in 104 soil samples taken within a 1-km radius of a lead battery plant contaminated site in Changxing County, Zhejiang Province, China. The site is heavily contaminated with high concentrations of lead (Pb) and cadmium (Cd). PMF successfully partitioned the variances into sources related to soil background, agronomic practices, and the lead battery plants combined with a geostatistical approach. It was estimated that the lead battery plants and the agronomic practices contributed 55.37 and 29.28 %, respectively, for soil Pb of the total source. Soil Cd mainly came from the lead battery plants (65.92 %), followed by the agronomic practices (21.65 %), and soil parent materials (12.43 %). This research indicates that PMF combined with geostatistics is a useful tool for source identification and apportionment.