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41.
Jacqueline T. Bangm Jessica L. Reiner Hannes Both Theresa M. Cantu Marco A. Gouws Matthew P. Guillette Jeremy P. Koelmel Wilmien J. Luus-Powell Jan Myburgh Olivia Rynders Joseph R. Sar Willem J. Smit John A. Bowden 《环境科学学报(英文版)》2017,29(11):59-67
This study examined concentrations of 15 perfluoroalkyl acids (PFAAs) in tissues from male Mozambique tilapia (Oreochromis mossambicus) collected at Loskop Dam, Mpumalanga, South Africa in 2014 and 2016. Nine of the 15 PFAAs were detected frequently and were included in statistical analysis and included two of the most commonly known PFAAs, perfluorooctanesulfonic acid (PFOS) (median, 41.6 ng/g) and perfluorooctanoic acid (PFOA) (median, 0.0825 ng/g). Of the tissues measured, plasma (2016 and 2014 median, 22.2 ng/g) contained the highest PFAA burden followed by (in descending order): liver (median, 11.6 ng/g), kidney (median, 9.04 ng/g), spleen (median, 5.92 ng/g), adipose (median, 2.54 ng/g), and muscle (median, 1.11 ng/g). Loskop Dam tilapia have been affected by an inflammatory disease of the adipose tissue known as pansteatitis, so this study also aimed to investigate relationships between PFAA tissue concentrations and incidence of pansteatitis or fish health status. Results revealed that healthy tilapia exhibited an overall higher (p-value < 0.05) PFAA burden than pansteatitis-affected tilapia across all tissues. Further analysis showed that organs previously noted in the literature to contain the highest PFAA concentrations, such as kidney, liver, and plasma, were the organs driving the difference in PFAA burden between the two tilapia groups. Care must be taken in the interpretations we draw from not only the results of our study, but also other PFAA measurements made on populations (human and wildlife alike) under differing health status. 相似文献
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Blood serum concentrations of perfluorinated compounds in men from Greenlandic Inuit and European populations 总被引:3,自引:0,他引:3
Lindh CH Rylander L Toft G Axmon A Rignell-Hydbom A Giwercman A Pedersen HS Góalczyk K Ludwicki JK Zvyezday V Vermeulen R Lenters V Heederik D Bonde JP Jönsson BA 《Chemosphere》2012,88(11):1269-1275
Perfluorinated compounds (PFCs), such as perfluorooctane sulfonate (PFOS) and perfluorooctanoic acid (PFOA), are used in large quantities. They are persistent and found in measurable levels in human serum around the world. They have been associated with developmental, hepatic, and carcinogenic effects in animal studies. The aim of the present study was to describe levels of PFCs in serum among Inuits from Greenland and inhabitants from Warsaw, Poland and Kharkiv, Ukraine. Furthermore, the aim was to define social- and lifestyle related determinants of exposure for these compounds. Serum levels of seven PFCs were analyzed by liquid chromatography/tandem mass spectrometry (LC/MS/MS). The concentrations of PFOS and PFOA were the highest of all PFCs in all three populations with a total amount of almost 90% of the PFCs. The mean levels of PFOS and PFOA were in the Greenlandic Inuits 52 and 4.8 ng mL(-1), in Poland 19 and 5.2 ng mL(-1), and in Ukraine 8.1 and 1.9 ng mL(-1), respectively. Thus, levels of PFCs in the serum of Inuits on Greenland were among the highest described in a general population whereas the levels in Poland were similar to other industrialized countries. The exposure in Ukraine was rather low. In the Greenlandic Inuit population, intake of seafood, tea, age and area of living were significant determinants of PFOS concentrations and explained about 22% of the variation. For the other populations no strong determinants were found. 相似文献
45.
Mårten Bryngelsson Erik G. Lindfeldt Jan Heller 《International Journal of Greenhouse Gas Control》2009,3(3):255-262
This study investigates the possibility of capturing CO2 from flue gas under pressurised conditions, which could prove to be beneficial in comparison to working under atmospheric conditions. Simulations of two hybrid combined cycles with pressurised fluidised bed combustion and CO2 capture are presented. CO2 is captured from pressurised flue gas by means of chemical absorption after the boiler but before expansion. The results show a CO2 capture penalty of approximately 8 percentage points (including 90% CO2 capture rate and compression to 110 bar), which makes the efficiency for the best performing cycle 43.9%. It is 5.2 percentage points higher than the most probable alternative, i.e. using a natural gas fired combined cycle and a pulverised coal fired condensing plant separately with the same fuel split ratio. The largest part of the penalty is associated with the lower mass flow of flue gas after CO2 capture, which leads to a decrease in work output in the expander and potential for feed water heating. The penalty caused by the regeneration of absorbent is quite low, since the high pressure permits the use of potassium carbonate, which requires less regeneration heat than for example the more commonly proposed monoethanolamine. Although the efficiencies of the cycles look promising it will be important to perform a cost estimate to be able to make a fair comparison with other systems. Such a cost estimate has not been done in this study. A significant drawback of these hybrid cycles in that respect is the complex nature of the systems that will have a negative effect on the economy. 相似文献
46.
Viatcheslav Moutavtchi Jan Stenis William Hogland Antonina Shepeleva 《Journal of Material Cycles and Waste Management》2010,12(2):169-183
This article aims to develop a general model for the evaluation of ecological-economic efficiency that will serve as an information
support tool for decision making at the corporate, municipal, and regional levels. It encompasses cost-benefit analysis in
solid waste management by applying a sustainability promoting approach that is explicitly related to monetary measures. A
waste managements’ efficient decision (WAMED) model based on cost-benefit analysis is proposed and developed to evaluate the
ecological-economic efficiency of solid waste management schemes. The employment of common business administration methodology
tools is featured. A classification of competing waste management models is introduced to facilitate evaluation of the relevance
of the previously introduced WAMED model. Suggestions are made for how to combine the previously introduced EUROPE model,
based on the equality principle, with the WAMED model to create economic incentives to reduce solid waste management-related
emissions. A fictive case study presents the practical application of the proposed cost-benefit analysis-based theory to the
landfilling concept. It is concluded that the presented methodology reflects an integrated approach to decreasing negative
impacts on the environment and on the health of the population, while increasing economic benefits through the implementation
of solid waste management projects. 相似文献
47.
Flow injection spectrophotometric determination of methamidophos using online hydrolysis 总被引:1,自引:0,他引:1
Mohammad Rasul Jan Jasmin Shah Nadia Bashir M. Salman 《Environmental monitoring and assessment》2010,167(1-4):685-689
A new protocol for the online spectrophotometric determination of methamidophos has been developed. The method is based on online hydrolysis of methamidophos, and the resulting hydrolyzed product is reacted with sodium nitroproside to form a colored complex. The calibration curve is linear over the concentration range of 0.5–20 μgml?–?1, with a molar absorptivity of 2.5×104 L mol?1 cm?1. The method is fast and reproducible with a sample throughput of 90 samples/h. The method is successfully applied to formulations and real samples. 相似文献
48.
Bioaccumulation models take various elimination and uptake processes into account, estimating rates from chemical lipophilicity, expressed as the octanol-water partition ratio (Kow). Here, we focussed on metabolism, which transforms parent compounds into usually more polar metabolites, thus enhancing elimination. The aim of this study was to quantify the change in lipophilicity of relevant organic pollutants undergoing various biotransformation reactions in mammals. We considered oxidation reactions catalyzed by three enzyme groups: cytochrome P450 (CYP), alcohol dehydrogenase (ADH), and aldehyde dehydrogenase (ALDH). Estimated log Kow values of a selected dataset of parent compounds were compared with the log Kow of their first metabolites. The log Kow decreased by a factor that varies between 0 and −2, depending on the metabolic pathway. For reactions mediated by CYP, the decrease in Kow was one order of magnitude for hydroxylated and epoxidated compounds and two orders of magnitude for dihydroxylated and sulphoxidated xenobiotics. On the other hand, no significant change in lipophilicity was observed for compounds N-hydroxylated by CYP and for alcohols and aldehydes metabolized by ADH and ALDH. These trends could be anticipated by the calculus method of log Kow. Yet, they were validated using experimental log Kow values, when available. These relationships estimate the extent to which the elimination of pollutants is increased by biotransformation. Thus, the quantification of the Kow reduction can be considered as a first necessary step in an alternative approach to anticipate biotransformation rates, which are hard to estimate with existing methods. 相似文献
49.
A sensitive spectrophotometric method has been developed for determination of ametryn in agricultural samples. The proposed
method was based on reaction with pyridine and further coupling with sulfanilic acid to form a colored product. The absorbance
was measured at 400 nm with a molar absorptivity of 2.1 × 105 L mol−1 cm−1. The method shows a linear range from 0.2–20 μg mL−1 with limit of detection and limit of quantification 0.16 and 0.54 μg mL−1, respectively. The method has been successfully applied to the determination of ametryn in sugarcane juice and commercial
formulations after separation of ametryn from triazine herbicides based on solvent extraction. Recovery values were found
to be in the range of 96.0 ± 0.2% to 98.4 ± 0.1%. 相似文献
50.
Jan Deckers 《Journal of Agricultural and Environmental Ethics》2009,22(6):573-597
In this paper, I provide some evidence for the view that a common charge against those who adopt vegetarianism is that they
would be sentimental. I argue that this charge is pressed frequently by those who adopt moral absolutism, a position that
I reject, before exploring the question if vegetarianism might make sense. I discuss three concerns that might motivate those
who adopt vegetarian diets, including a concern with the human health and environmental costs of some alternative diets, a
concern about inflicting pain on animals, and a concern with the killing of animals. While I argue that vegetarianism does
not make sense in some situations, I hope that this paper shows that there are many good reasons why the adoption of vegetarian,
and—even more so—vegan diets might be appropriate in some situations. In carving out this position, I focus primarily on the
question whether a morally relevant distinction between the killing of plants and the killing of animals should be made. I
engage primarily with the views of two of the most prominent authors on this issue, arguing that neither Peter Singer nor
Tom Regan provide a satisfactory account on the ethics of killing nonhuman organisms. Two views are challenged in particular,
the view that relatively simple animals such as molluscs, as well as plants, lack awareness, and the view that animals without
a preference to continue living stand to lose little or nothing by being killed. I provide some evidence to support the claim
that many share my view that it is more problematic to kill animals than to kill plants, before analyzing why some suppress
the negative feelings they associate with killing animals. By exploring these issues I hope to shed some light on the issue
of whether the feelings of those who adopt vegetarianism are sentimental or make sense, and to stimulate reflection amongst
those with an interest in food ethics. 相似文献