Accumulation and Depuration Kinetics of Rotavirus in Mussels Experimentally Contaminated

Bivalve mollusks as filter-feeders concentrate in their digestive tissue microorganisms likely present in the harvesting water, thus becoming risky food especially if consumed raw or poorly cooked. To eliminate bacteria and viruses eventually accumulated, they must undergo a depuration process which efficacy on viruses is on debate. To better clarify the worth of the depuration process on virus elimination from mussels, in this study we investigated rotavirus kinetics of accumulation and depuration in Mytilus galloprovincialis experimentally contaminated. Depuration process was monitored for 9 days and virus residual presence and infectivity were evaluated by real time quantitative polymerase chain reaction, cell culture and electron microscopy at days 1, 2, 3, 5, 7, 9 of depuration. Variables like presence of ozone and of microalgae feeding were also analyzed as possible depuration enhancers. Results showed a two-phase virus removal kinetic with a high decrease in the first 24 h of depuration and 5 days necessary to completely remove rotavirus.     

Controlling factors of phytoplankton seasonal succession in oligotrophic Mali Ston Bay (south-eastern Adriatic)

Fine spatial and temporal phytoplankton variability in Mali Ston Bay has been observed for the first time based on physicochemical properties and small herbivorous zooplankton. Extensive year-through research was conducted during 2002 at Usko station which is traditionally an area of intensive shellfish farming. The Neretva River inflow, submarine springs (“vruljas”) and precipitation are additional sources of nutrients in the bay. Temperature and salinity, combined with total inorganic nitrogen (TIN) were observed to be the most important environmental factors driving the succession of phytoplankton communities. Orthophosphate was a potential limiting factor for phytoplankton development. The nanophytoplankton abundances, as well as the microphytoplankton diatoms are controlled by herbivorous zooplankton grazing (‘top-down’ control) more than other groups of microphytoplankton. Nanophytoplankton dominated phytoplankton abundance and its most intensive development was recorded in winter and spring, while increase in microphytoplankton abundance occurred in spring and autumn. Diatoms dominated microphytoplankton abundance mostly in winter and autumn, while dinoflagellates dominated in spring and summer. Considering the number of taxa and abundance, dinoflagellates were the dominant microphytoplankton group during the year and were the main component of the spring blooms. At that time, in conditions of elevated temperature (>16 °C), decreased salinity (34–36) and increased concentrations of TIN, blooms of harmful dinoflagellate Prorocentrum minimum were recorded for the first time in the bay. The results showed a significant difference in environmental conditions, as well as in the annual phytoplankton succession and community structure, as compared with studies carried out more than 20 years ago in this area.     

Xenobiotics removal by adsorption in the context of tertiary treatment: a mini review

Many xenobiotics, including several pharmaceuticals and pesticides, are poorly treated in domestic wastewater treatment plants. Adsorption processes, such as with activated carbons, could be a solution to curb their discharge into the aquatic environment. As adsorbent-like activated carbon is known to be expensive, identifying promising alternative adsorbent materials is a key challenge for efficient yet affordable xenobiotic removal from wastewaters. As part of the effort to address this challenge, we surveyed the literature on pharmaceutical and pesticide xenobiotics and built a database compiling data from 38 scientific publications covering 65 xenobiotics and 58 materials. Special focus was given to the relevance and comparability of the data to the characteristics of the adsorbent materials used and to the operating conditions of the batch tests inventoried. This paper gives an in-depth overview of the adsorption capacities of various adsorbents. The little data on alternative adsorbent materials, especially for the adsorption of pharmaceuticals, makes it difficult to single out any one activated carbon alternative capable of adsorbing pesticides and pharmaceuticals at the tertiary stage of treatment. There is a pressing need for further lab-scale experiments to investigate the tertiary treatment of discharged effluents. We conclude with recommendations on how future data should best be used and interpreted.     

Catalytic activity of NiW electrodeposits

NiW systems are known as one of the best catalysts for various desulfurization processes. In this study, we examined catalytic properties of NiW electrodeposits, produced from two different electrolytes, towards sulfide ion oxidation in alkaline solution. Despite the big difference in morphology and structure of both materials, they exhibit almost the same catalytic activity for the examined reaction. A possible explanation of this experimental fact is that the overall reaction is controlled by the transport of oxygen through the catalyst samples.     

AN ANTIDEGRADATION POLICY FOR PRESERVING SURFACE WATER QUALITY IN FLORIDA1

ABSTRACT: As part of its overall system for protecting aquatic systems from unnecessary degradation, the State of Florida provides special protection for water bodies of unusual importance. Such water bodies are designated as “Outstanding Florida Waters” (OFW5). New discharges to OFWs are possible only if certain stringent criteria are met. A new point source direct discharge to an OFW is usually not allowed if it would cause any lowering of ambient water quality. A new indirect discharge (upstream from an OFW boundary) may be allowed only if it would not significantly degrade the OFW. To date, the advantages of the OFW system have clearly outweighed the disadvantages, and OFW designations are helping to protect Florida's most valuable waters from additional degradation. Florida's system could be a useful model for other jurisdictions wanting to provide special protection to special water bodies.     

A Sensitivity Analysis of Ozone Formation to Ambient Air Composition by Means of Photochemical Models

The prediction of the atmospheric concentration of ozoneand of other photochemical pollutants represents one of themajor scientific challenges in the study of urban airquality. To this aim, photochemical models are widelyapplied as support tools for regulatory purposes, but theirresults are known to be affected by several uncertainties,in boundary conditions, geographical and meteorologicaldata and the chemical composition of emission and ambientair as well. Also the mechanism selected to describe theurban chemistry may lead to large differences in the modelresults. In this work, the influence of ambient air composition onthe results of photochemical model has been studied using a simple Lagrangian trajectory model coupled with different chemical sub-models (CB-IV and a simplified version of EMEP). To this aim a parametric sensitivity study of ozone with respect to its precursors' concentration was performed withreference to the same meteorological conditions and by simulatingdifferent scenarios characterized by specific emitted pollutantsconcentration. Rather than analyzing sensitivity by changing initial composition, an analytical local sensitivity concept has been applied; this allowed evaluation the influence of initial concentration on the predicted ozone concentration andto discriminate between VOC-sensitive and NOx-sensitive kineticregimes. Finally, these results have been successfully comparedwith those obtained applying the concept of photochemical indicators (i.e. O₃/NOy and H₂O₂/HNO₃ ratios).