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31.
Wilcox J Sasmaz E Kirchofer A Lee SS 《Journal of the Air & Waste Management Association (1995)》2011,61(4):418-426
Experimental and theory-based investigations have been carried out on the oxidation and adsorption mechanism of mercury (Hg) on brominated activated carbon (AC). Air containing parts per billion concentrations of Hg was passed over a packed-bed reactor with varying sorbent materials at 140 and 30 degrees C. Through X-ray photoelectron spectroscopy surface characterization studies it was found that Hg adsorption is primarily associated with bromine (Br) on the surface, but that it may be possible for surface-bound oxygen (O) to play a role in determining the stability of adsorbed Hg. In addition to surface characterization experiments, the interaction of Hg with brominated AC was studied using plane-wave density functional theory. Various configurations of hydrogen, O, Br, and Hg on the zigzag edge sites of graphene were investigated, and although Hg-Br complexes were found to be stable on the surface, the most stable configurations found were those with Hg adjacent to O. The Hg-carbon (C) bond length ranged from 2.26 to 2.34 A and is approximately 0.1 A shorter when O is a nearest-neighbor atom rather than a next-nearest neighbor, resulting in increased stability of the given configuration and overall tighter Hg-C binding. Through a density of states analysis, Hg was found to gain electron density in the six p-states after adsorption and was found to donate electron density from the five s-states, thereby leading to an oxidized surface-bound Hg complex. 相似文献
32.
Municipal solid waste incineration contributes with 20% of the heat supplied to the more than 400 district heating networks in Denmark. In evaluation of the environmental consequences of this heat production, the typical approach has been to assume that other (fossil) fuels could be saved on a 1:1 basis (e.g. 1 GJ of waste heat delivered substitutes for 1 GJ of coal-based heat). This paper investigates consequences of waste-based heat substitution in two specific Danish district heating networks and the energy-associated interactions between the plants connected to these networks. Despite almost equal electricity and heat efficiencies at the waste incinerators connected to the two district heating networks, the energy and CO2 accounts showed significantly different results: waste incineration in one network caused a CO2 saving of 48 kg CO2/GJ energy input while in the other network a load of 43 kg CO2/GJ. This was caused mainly by differences in operation mode and fuel types of the other heat producing plants attached to the networks. The paper clearly indicates that simple evaluations of waste-to-energy efficiencies at the incinerator are insufficient for assessing the consequences of heat substitution in district heating network systems. The paper also shows that using national averages for heat substitution will not provide a correct answer: local conditions need to be addressed thoroughly otherwise we may fail to assess correctly the heat recovery from waste incineration. 相似文献
33.
S. Taku Ide Kristian Jessen Franklin M. Orr Jr. 《International Journal of Greenhouse Gas Control》2007,1(4):481-491
CO2 can be effectively immobilized during CO2 injection into saline aquifers by residual trapping – also known as capillary trapping – a process resulting from capillary snap-off of isolated CO2 bubbles. Simulations of CO2 injection were performed to investigate the interplay of viscous and gravity forces and capillary trapping of CO2. Results of those simulations show that gas injection processes in which gravitational forces are weak compared to viscous forces (low gravity number Ngv) trap significantly more CO2 than do flows with strong gravitational forces relative to the viscous forces (high Ngv). The results also indicate that over a wide range of gravity numbers (Ngv), significant fractions of the trapping of CO2 can occur relatively quickly. The amount of CO2 that is trapped after injection ceases is demonstrated to correlate with Ngv. For some simulated displacements, effects of capillary pressure and aquifer dip angle on the amount and the rate of trapping are reported. Trapping increases when effects of capillary pressure and aquifer inclination are included in the model. Finally we show that injection schemes such as alternating injection of brine and CO2 or brine injection after CO2 injection can also enhance the trapping behavior. 相似文献
34.
Walter F. Dabberdt Hanwant B. Singh 《Journal of the Air & Waste Management Association (1995)》2013,63(9):876-881
Emergency plans for oxidant controls provide the basis for taking preventive action to protect public health. Historic oxidant data (1970 to Sept. 1974) from the South Coast Air Basin (SCAB), were evaluated to assess episode characteristics in an area where emergency strategies are most likely to be enforced. These findings, together with an objective study of a test case episode (June 1974) using a photochemical air quality simulation model, suggest that the currently conceived emergency plans for oxidant control are unlikely to be effective. It is concluded that, because of the chemical and mefeorofogfcal complexities of the episodes, they are extremely difficult both to predict and concurrently to control over their short-lived duration. 相似文献
35.
36.
Real-time measurement of outdoor tobacco smoke particles 总被引:1,自引:0,他引:1
Klepeis NE Ott WR Switzer P 《Journal of the Air & Waste Management Association (1995)》2007,57(5):522-534
The current lack of empirical data on outdoor tobacco smoke (OTS) levels impedes OTS exposure and risk assessments. We sought to measure peak and time-averaged OTS concentrations in common outdoor settings near smokers and to explore the determinants of time-varying OTS levels, including the effects of source proximity and wind. Using five types of real-time airborne particle monitoring devices, we obtained more than 8000 min worth of continuous monitoring data, during which there were measurable OTS levels. Measurement intervals ranged from 2 sec to 1 min for the different instruments. We monitored OTS levels during 15 on-site visits to 10 outdoor public places where active cigar and cigarette smokers were present, including parks, sidewalk cafés, and restaurant and pub patios. For three of the visits and during 4 additional days of monitoring outdoors and indoors at a private residence, we controlled smoking activity at precise distances from monitored positions. The overall average OTS respirable particle concentration for the surveys of public places during smoking was approximately 30 microg m(-3). OTS exhibited sharp spikes in particle mass concentration during smoking that sometimes exceeded 1000 microg m(-3) at distances within 0.5 m of the source. Some average concentrations over the duration of a cigarette and within 0.5 m exceeded 200 microg m(-3), with some average downwind levels exceeding 500 microg m(-3). OTS levels in a constant upwind direction from an active cigarette source were nearly zero. OTS levels also approached zero at distances greater than approximately 2 m from a single cigarette. During periods of active smoking, peak and average OTS levels near smokers rivaled indoor tobacco smoke concentrations. However, OTS levels dropped almost instantly after smoking activity ceased. Based on our results, it is possible for OTS to present a nuisance or hazard under certain conditions of wind and smoker proximity. 相似文献
37.
Coastal fisheries provide staple food and sources of livelihood in Pacific Island countries, and securing a sustainable supply is recognised as a critical priority for nutrition security. This study sought to better understand the role of fish for Pacific Island communities during disasters and in disaster recovery. To evaluate community impacts and responses after natural disasters, focus group discussions were held with men and women groups at ten sites across Shefa, Tafea, Malampa and Sanma provinces in Vanuatu. The combined impacts of category 5 Tropical Cyclone Pam (TC-Pam) in March 2015 and prolonged El-Niño induced drought have had a profound impact across much of Vanuatu. Terrestrial systems had been disproportionately impacted with substantial shortages in drinking water, garden crops, cash crops and damage to infrastructure. Localized impacts were noted on marine environments from TC-Pam and the drought, along with an earthquake that uplifted reef and destroyed fishing grounds in Malampa province. Communities in Malampa and Shefa provinces also noted a crown-of-thorns outbreak that caused coral mortality. The significant reduction in terrestrial-based food and income generation capacity generally led to increased reliance on marine resources to cope and a shift in diets from local garden food to rice. However, limited market access, lack of fishing skills and technology in many sectors of the community reduced the capacity for marine resources to support recovery. A flexible management approach allowed protected areas and species to be utilized as reservoirs of food and income when temporarily opened to assist recovery. These findings illustrate that fish and fisheries management is at the center of disaster preparedness and relief strategies in remote Pacific Island communities. High physical capital (e.g. infrastructure, water tanks and strong dwellings) is key for disaster preparedness, but supporting community social capital for the purpose of natural resource management and human capital for diverse adaptation skills can also improve community resilience. Recognizing the humanitarian value that well managed fisheries resources and skilled fishers can play to disaster relief adds another dimension to the imperative of improving management of coastal fisheries and aligning policies across sectors. 相似文献
38.
The relationship between out-migration of labor in the Qinling mountain area and households' firewood consumption is explored. Migration and remittances reduce households' firewood consumption due to i... 相似文献
39.
40.
P. Bogaert G. Christakos M. Jerrett H.-L. Yu 《Atmospheric environment (Oxford, England : 1994)》2009,43(15):2471-2480
This paper is concerned with the spatiotemporal mapping of monthly 8-h average ozone (O3) concentrations over California during a 15-years period. The basic methodology of our analysis is based on the spatiotemporal random field (S/TRF) theory. We use a S/TRF decomposition model with a dominant seasonal O3 component that may change significantly from site to site. O3 seasonal patterns are estimated and separated from stochastic fluctuations. By means of Bayesian Maximum Entropy (BME) analysis, physically meaningful and sufficiently detailed space–time maps of the seasonal O3 patterns are generated across space and time. During the summer and winter months the seasonal O3 concentration maps exhibit clear and progressively changing geographical patterns over time, suggesting the existence of relationships in accordance with the typical physiographic and climatologic features of California. BME mapping accuracy can be superior to that of other techniques commonly used by EPA; its framework can rigorously assimilate useful data sources that were previously unaccounted for; the generated maps offer valuable assessments of the spatiotemporal O3 patterns that can be helpful in the identification of physical mechanisms and their interrelations, the design of human exposure and population health models, and in risk assessment. As they focus on the seasonal patterns, the maps are not contingent on short-time and locally prevalent weather conditions, which are of no interest in a global and non-forecasting framework. Moreover, the maps offer valuable insight about the space–time O3 concentration patterns and are, thus, helpful for disentangling the influence of explanatory factors or even for identifying some influential ones that could have been otherwise overlooked. 相似文献